1-ethyl-5-cyano-6-hydroxy-4-methyl-2(1H)-pyridinone | 28141-13-1

• 物质功能分类: 医药中间体 - 杂环化合物 - 吡啶类化合物
• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: 1-ethyl-5-cyano-6-hydroxy-4-methyl-2(1H)-pyridinone
• 英文别名: 1-ethyl-6-hydroxy-4-methyl-2-oxo-1,2-dihydroypyridine-3-carbonitrile；1-Ethyl-6-hydroxy-4-methyl-2-oxo-1,2-dihydropyridine-3-carbonitrile；1-ethyl-2-hydroxy-4-methyl-6-oxopyridine-3-carbonitrile
• CAS: 28141-13-1
• 化学式: C₉H₁₀N₂O₂
• 分子量: 178.191
• InChiKey: YSNMMQRIPFUHAO-UHFFFAOYSA-N

物化性质

• 熔点：
  244-247 °C(lit.)
• 沸点：
  316.8±42.0 °C(Predicted)
• 密度：
  1.27±0.1 g/cm3(Predicted)
• 溶解度：
  溶于二甲基甲酰胺

计算性质

• 辛醇/水分配系数(LogP)：
  0.5
• 重原子数：
  13
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  64.3
• 氢给体数：
  1
• 氢受体数：
  3

安全信息

• 危险等级：
  6.1
• 危险品标志：
  Xn
• 安全说明：
  S26,S36
• 危险类别码：
  R20/21/22,R36/37/38
• WGK Germany：
  3
• 海关编码：
  2926909090

文献信息

• Cationic pyridone azo dyestuffs, certain novel coupling components from which they are derived and processes for the manufacture of the dyestuffs and the coupling components
  申请人：IMPERIAL CHEMICAL INDUSTRIES PLC

  公开号：EP0023770A1

  公开（公告）日：1981-02-11

  The dyestuffs are prepared by diazotation of an amine, reaction with a pyridone coupling component carrying in the 3-position a 5- or 6-membered heterocyclic ring containing an o-nitrogen and an o-sulphur or second nitrogen atom and quaternisation. A further carbocyclic or heterocyclic ring may be fused to the first. The novel pyridone coupling components carry a 3-benzimidazole or a 3-benzthiazole substituent and are made by reacting a 3-cyano pyridone with an o-phenylene diamine or o-aminothiophenol in the presence of anhydrous aluminium trichloride. The dyestuffs colour acrylic materials bright yellow shades of high tinctorial strength. They have good fastness properties and compatibility values.

  染料的制备方法是：重氮化胺，与在 3 位上含有一个 5 或 6 元杂环的吡啶酮偶联组分反应，该杂环含有一个邻氮和一个邻硫或第二个氮原子，然后进行季铵化反应。另一个碳环或杂环可与第一个碳环或杂环融合。新型吡啶酮偶联组分带有 3-苯并咪唑或 3-苯并噻唑取代基，是通过 3-氰基吡啶酮与邻苯基二胺或邻氨基苯硫酚在无水三氯化铝存在下反应制成的。 这些染料能使丙烯酸材料染上明亮的黄色，具有很高的锡宽容度。它们具有良好的牢度特性和相容性。
• Thermal transfer sheet
  申请人：ZENECA LIMITED

  公开号：EP0333337A2

  公开（公告）日：1989-09-20

  Coloured condensation polymers useful as replacements for waxes in a thermal wax transfer process, said polymers being obtained by reacting a polymerisable lactone or a hydroxyalkanoic acid with a dye containing at least one active hydrogen atom.

  在热蜡传递工艺中可替代蜡的彩色缩合聚合物，所述聚合物是通过可聚合内酯或羟基烷酸与含有至少一个活性氢原子的染料反应而获得的。
• Ink-jet printing
  申请人：ZENECA LIMITED

  公开号：EP0371627A2

  公开（公告）日：1990-06-06

  A method of printing in which a solid ink composition is melted and ejected from a small orifice in the form of small drops directed towards a substrate on which an image is to be formed, characterised in that the solid ink composition comprises either a solution or a dispersion of a dye or a finely divided pigment in a halogenated hydrocarbon having a melting point of at least 50°C ("Ink A"), or a coloured condensation polymer obtained by reacting a polymerisable lactone or a hydroxyalkanoic acid with a dye containing at least one active hydrogen atom ("Ink B).

  一种印刷方法，在这种方法中，固体油墨组合物被熔化，并以小液滴的形式从一个小孔中喷出，射向要在其上形成图像的承印物、其特征在于，固体油墨组合物包括染料或精细颜料在熔点至少为 50°C 的卤代烃中的溶液或分散体（"油墨 A"），或通过可聚合内酯或羟基烷酸与含有至少一个活性氢原子的染料反应而得到的彩色缩合聚合物（"油墨 B"）。
• Reactive dyes
  申请人：ZENECA LIMITED

  公开号：EP0514001A1

  公开（公告）日：1992-11-19

  A water soluble dye having a reactive group of the formula: wherein: Tis a labile atom or group; and R² and R³are each independently a non-chromophoric optionally substituted aryl or alkyl group.

  具有式中活性基团的水溶性染料： 其中 T 是易变原子或基团；以及 R² 和 R³ 各自独立地为非变色的任选取代芳基或烷基。
• US4424155A
  申请人：——

  公开号：US4424155A

  公开（公告）日：1984-01-03