申请人:MOBAY CORPORATION
公开号:EP0450460A2
公开(公告)日:1991-10-09
The present invention is directed to a process for the production of optionally cellular, polyurea elastomer moldings by reacting a reaction mixture containing
I) a polyisocyanate,
II) a polyether having at least two isocyanate-reactive groups and a molecular weight of 1800 to 12,000 in which at least 50% of the isocyanate-reactive groups are primary and/or secondary amino groups,
III) about 5 to 50% by weight, based on the weight of component (II) of a chain extender comprising a sterically hindered aromatic diamine and
IV) about 0.5 to 20% by weight, based on the weight of components (II) and (III) of a zinc carboxylate containing from 10 to 14 carbon atoms per carboxylate group,
and the reaction mixture is processed as a one-shot system by the RIM process at an isocyanate index of about 70 to 130.
The present invention is also directed to an isocyanate-reactive component for use in a RIM process based on components (II), (III) and (IV).
本发明涉及一种生产可选蜂窝状聚脲弹性体模塑件的工艺,其反应混合物中含有
I) 一种多异氰酸酯、
具有至少两个异氰酸酯反应基团且分子量在 1800 至 12000 之间的聚醚,其中至少 50%的异氰酸酯反应基团为伯氨基和/或仲氨基、
III) 以组分(II)的重量为基准,约 5%至 50%的扩链剂,包括受立体阻碍的芳香族二胺和
IV) 以组分(II)和(III)的重量计,约 0.5%至 20%的羧酸锌,每个羧酸基含有 10 至 14 个碳原子、
反应混合物作为一次性系统,在异氰酸酯指数约为 70 至 130 的条件下,用 RIM 工艺进行处理。
本发明还涉及一种异氰酸酯反应组分,用于基于组分(II)、(III)和(IV)的 RIM 工艺。