2-methyl-1,3-hexanediol | 66072-21-7

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: 2-methyl-1,3-hexanediol
• 英文别名: 1,3-Hexanediol, 2-methyl-；2-methylhexane-1,3-diol
• CAS: 66072-21-7
• 化学式: C₇H₁₆O₂
• 分子量: 132.203
• InChiKey: XGGVPUCMUQQFJM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1
• 重原子数：
  9
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  40.5
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  2-methyl-1,3-hexanediol 在 sodium hypochlorite 、 potassium bromide 作用下， 以 二氯甲烷 、 水 为溶剂， 反应 0.17h， 生成 2-methyl-3-hydroxyhexanaldehyde 、 1-hydroxy-2-methyl-3-ketohexane
  参考文献：
  名称：

  TEMPO radical polymer grafted silicas as solid state catalysts for the oxidation of alcohols

  摘要：

  通过RAFT聚合的“自嫁接”和“相互嫁接”方法，合成了TEMPO接枝硅胶，并展示了它们作为一类新型固态催化剂在醇氧化反应中的催化活性。

  DOI：

  10.1039/c3ra41823e
• 作为产物：
  描述：

  1-(benzyloxy)-2-methylhex-5-en-3-ol 以88%的产率得到
  参考文献：
  名称：

  HEATHCOCK, C. H.;KIYOOKA, SYUN-ICHI;BLUMENKOPF, T. A., J. ORG. CHEM., 1984, 49, N 22, 4214-4223

  摘要：

  DOI：

文献信息

• Transparent desiccating agent
  申请人：Uchibori Teruo

  公开号：US20090030220A1

  公开（公告）日：2009-01-29

  The present invention provides a transparent desiccant with a high moisture absorption capacity which is suitable for use as a desiccant for organic EL devices (especially top-emitting organic EL devices). More particularly, the invention provides a transparent desiccant comprising an organometallic compound obtained by reacting a metal alkoxide with a polyol.

  本发明提供了一种具有高吸湿能力的透明脱湿剂，适用于作为有机EL器件（特别是顶部发射有机EL器件）的脱湿剂使用。更具体地，该发明提供了一种透明脱湿剂，包括通过将金属烷氧基化合物与多元醇反应获得的有机金属化合物。
• Halogen substituted carbamate compounds from 2-phenyl-1,2-ethanediol
  申请人：——

  公开号：US20010034365A1

  公开（公告）日：2001-10-25

  Enantiomeric forms of monocarbamates of halogenated 2-pheny-1,2 -ethanediol and dicarbamates of halogenated 2-pheny-1,2-ethanediol have been found to be effective in the treatment of disorders of the central nervous system, especially as anti-convulsive or anti-epileptic agents.

  卤代2-苯基-1,2-乙二醇的单羰基酸酯对映体和卤代2-苯基-1,2-乙二醇的双羰基酸酯被发现在治疗中枢神经系统疾病方面具有有效性，特别是作为抗惊厥或抗癫痫剂。
• Carbamates of 2-heterocyclic-1,2-ethanediols
  申请人：——

  公开号：US20030078235A1

  公开（公告）日：2003-04-24

  Carbamate compounds of 2-heteroaryl-1,2-ethanediol are described. The compounds are effective in the treatment of disorders of the central nervous system, especially as anti-convulsive or anti-epileptic agents.

  本文描述了2-杂环基-1,2-乙二醇的氨基甲酸酯化合物。这些化合物在治疗中枢神经系统疾病方面具有有效性，特别是作为抗惊厥或抗癫痫药物。
• Switchable window based on electrochromic polymers
  申请人：Liu Lu

  公开号：US20050200935A1

  公开（公告）日：2005-09-15

  Syntheses of a new blue EC monomer (ProDOT-MePro), and a new red EC monomer (ProDOP-Et2) are described. Two additional new types of EC monomers based on 3,4-alkylenedioxythiophene include fluorinated EC monomers and an EC monomer including silicon. EC polymer devices having more than one different color EC polymer to enable additional colors to be provided using subtractive color mixing are also described, as well as EC polymer devices incorporating a logo, image, or text, are generally obscured when the device is colored, but become visible when the device is not colored. Also described are EC polymer devices that include a cathodic EC polymer layer, a gel electrolyte, a counter electrode, and a reference electrode. Working prototypes of such devices exhibit significant increases in the speed of transition of the EC device from a colored state to a transparent state.

  本文介绍了一种新的蓝色EC单体（ProDOT-MePro）和一种新的红色EC单体（ProDOP-Et2）的合成方法。还介绍了基于3,4-二亚甲基二氧基噻吩的两种新型EC单体，包括含氟EC单体和含硅EC单体。还介绍了EC聚合物器件，其中包含多种不同颜色的EC聚合物，以实现减色混合提供额外的颜色，并且该器件在着色时可以遮盖标志、图像或文本，但在不着色时变得可见。还介绍了包括阴极EC聚合物层、凝胶电解质、计数电极和参考电极的EC聚合物器件。这种器件的工作原型表现出EC器件从着色状态到透明状态的转换速度显著提高。
• SWITCHABLE WINDOW BASED ON ELECTROCHROMIC POLYMERS
  申请人：Liu Lu

  公开号：US20080055701A1

  公开（公告）日：2008-03-06

  Syntheses of a new blue EC monomer (ProDOT-MePro), and a new red EC monomer (ProDOP-Et2) are described. Two additional new types of EC monomers based on 3,4-alkylenedioxythiophene include fluorinated EC monomers and an EC monomer including silicon. EC polymer devices having more than one different color EC polymer to enable additional colors to be provided using subtractive color mixing are also described, as well as EC polymer devices incorporating a logo, image, or text, are generally obscured when the device is colored, but become visible when the device is not colored. Also described are EC polymer devices that include a cathodic EC polymer layer, a gel electrolyte, a counter electrode, and a reference electrode. Working prototypes of such devices exhibit significant increases in the speed of transition of the EC device from a colored state to a transparent state.

  本文介绍了一种新的蓝色EC单体（ProDOT-MePro）和一种新的红色EC单体（ProDOP-Et2）的合成方法。基于3,4-alkylenedioxythiophene的两种附加的新型EC单体包括氟化EC单体和包括硅的EC单体也被描述。本文还描述了具有多种不同颜色EC聚合物的EC聚合物器件，以实现通过减色混合提供额外的颜色，以及EC聚合物器件，包括一个标志、图像或文本，通常在设备着色时被遮盖，但在设备未着色时变得可见。本文还描述了包括阴极EC聚合物层、凝胶电解质、计数电极和参考电极的EC聚合物器件。这些设备的工作样品表现出EC设备从有色状态到透明状态的转换速度显著增加的特点。