IONIZING RADIATION-RESISTANT THERMOPLASTIC RESIN COMPOSITION, AND MOLDED PRODUCT COMPRISING SAME
申请人:Lotte Advanced Materials Co., Ltd.
公开号:EP3521361A1
公开(公告)日:2019-08-07
A thermoplastic resin composition of the present invention comprises a rubber-modified vinyl-based graft copolymer, a first aromatic vinyl-based copolymer, a second aromatic vinyl-based copolymer, and a polyalkylene glycol, wherein the first aromatic vinyl-based copolymer is a copolymer of methyl methacrylate, methyl acrylate, an aromatic vinyl-based monomer, and a monomer copolymerizable with the aromatic vinyl-based monomer, the second aromatic vinyl-based copolymer is a copolymer of an aromatic vinyl-based monomer and a monomer copolymerizable with the aromatic vinyl-based monomer, and the weight ratio of methyl methacrylate to methyl acrylate, in the first aromatic vinyl-based copolymer, is approximately 1:0.01 to approximately 1:0.2. The thermoplastic resin composition has excellent discoloration resistance, color, transparency, and the like even after irradiation with ionizing radiation.
本发明的一种热塑性树脂组合物包括橡胶改性乙烯基接枝共聚物、第一芳香族乙烯基共聚物、第二芳香族乙烯基共聚物和聚亚烷基二醇,其中第一芳香族乙烯基共聚物是甲基丙烯酸甲酯、丙烯酸甲酯、芳香族乙烯基单体和可与芳香族乙烯基单体共聚的单体的共聚物,第二芳香族乙烯基共聚物是芳香族乙烯基单体和可与芳香族乙烯基单体共聚的单体的共聚物、第二芳香族乙烯基共聚物是芳香族乙烯基单体和可与芳香族乙烯基单体共聚的单体的共聚物,甲基丙烯酸甲酯与丙烯酸甲酯在第一芳香族乙烯基共聚物中的重量比约为 1:0.01 至约 1:0.2。该热塑性树脂组合物即使在电离辐射照射后也具有优异的抗变色性、颜色和透明度等。