Diamine adipate

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: Diamine adipate
• 英文别名: azane;hexanedioic acid
• 化学式: C6H16N2O4
• 分子量: 180.2
• InChiKey: ZRSKSQHEOZFGLJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -1.2
• 重原子数：
  12
• 可旋转键数：
  3
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  82.3
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  Diamine adipate 以4%的产率得到
  参考文献：
  名称：

  ZHAROV, A. A.;CHISTOTINA, N. P., DOKL. AN CCCP, 306,(1989) N, S. 650-654

  摘要：

  DOI：
• 作为产物：
  描述：

  己二酸 、 氨 生成 Diamine adipate
  参考文献：
  名称：

  High temperature electrolytic capacitor

  摘要：

  高温铝电解电容器包含一种电解质，其为叔丁胺盐和己二酸的1.3至2.0摩尔比，还包含磷酸盐和水，这些溶解在乙二醇中，以提供至少在200 VDC和130°C下工作的电容器。

  公开号：

  US04479166A1

文献信息

• METHOD FOR PRODUCING HEXAMETHYLENEDIAMINE
  申请人：BASF SE

  公开号：US20160326092A1

  公开（公告）日：2016-11-10

  The invention relates to a method for producing hexamethylenediamine, wherein a) a muconic acid starting material is provided, which is selected from among muconic acid, esters of muconic acid, lactones of muconic acid, and mixtures thereof, b) the muconic acid starting material is subjected to a reaction with hydrogen in the presence of at least one hydrogenation catalyst in order to form 1,6-hexanediol, and c) the 1,6-hexanediol obtained in step b) is subjected to amination in the presence of an amination catalyst in order to obtain hexamethylenediamine. The invention further relates to hexamethylenediamine which can be produced by means of said method.

  该发明涉及一种生产己二胺的方法，其中a)提供一种顺丁二酸起始原料，所述顺丁二酸起始原料被选自顺丁二酸、顺丁二酸酯、顺丁二酸内酯及其混合物之一，b)在至少一种加氢催化剂的存在下，将所述顺丁二酸起始原料与氢气反应，以形成1,6-己二醇，c)将步骤b)中获得的1,6-己二醇在氨化催化剂的存在下进行氨化，以获得己二胺。该发明还涉及通过该方法生产的己二胺。
• METHOD OF PRODUCING ADIPIC ACID OR AT LEAST A RESULTANT PRODUCT THEREOF
  申请人：BASF SE

  公开号：US20160311746A1

  公开（公告）日：2016-10-27

  The present invention relates to a process for preparing adipic acid or at least one conversion product thereof, in which muconic acid is hydrogenated with hydrogen in the presence of at least one transition metal catalyst C and of an aqueous liquid A in a reaction zone, wherein the muconic acid is at least partly insoluble in the liquid A under the hydrogenation conditions.

  本发明涉及一种制备己二酸或其至少一个转化产物的方法，其中在反应区中，以至少一种过渡金属催化剂C和水性液体A的存在下，将须二烯二酸与氢气在氢化条件下加氢，其中在氢化条件下，须二烯二酸至少在液体A中部分不溶解。
• [EN] PROCESSES FOR PRODUCING MONOAMMONIUM ADIPATE FROM FERMENTATION BROTHS CONTAINING DIAMMONIUM ADIPATE, MONOAMMONIUM ADIPATE AND/OR ADIPIC ACID, AND CONVERSION OF MONOAMMONIUM ADIPATE TO ADIPIC ACID<br/>[FR] PROCÉDÉS DE FABRICATION D'ADIPATE DE MONOAMMONIUM À PARTIR DE BOUILLONS DE FERMENTATION CONTENANT DE L'ADIPATE DE DIAMMONIUM, UN ADIPATE DE MONOAMMONIUM ET/OU DE L'ACIDE ADIPIQUE, ET DE CONVERSION DE L'ADIPATE DE MONOAMMONIUM EN ACIDE ADIPIQUE
  申请人：BIOAMBER SAS

  公开号：WO2011136941A1

  公开（公告）日：2011-11-03

  A process for making MAA from a clarified DAA-containmg fefme.ntation broth includes (a) distilling: the broth to form an overhead thai includes water and ammonia, and a liquid bottoms, that includes MAA, at least some DAA, and at least about 20 wt% water; (fa) cooling "the bottoms to a temperature sufficient to cause the bottoms to separate into a DAA-containing liquid portion in contact with a MAA-contaraing solid portion that is substantially free of DAA; (c) separating the solid portion from the liquid portion: and (d) recovering the solid portion.

  从含有澄清DAA的发酵液中制备MAA的过程包括(a)蒸馏：将发酵液蒸馏成一个包括水和氨的顶部，以及一个包括MAA、至少一些DAA和至少约20wt％水的液体底部；(b)将底部冷却至足以使底部分离成与MAA含量固体部分接触的含有DAA的液体部分，该固体部分基本上不含DAA；(c)分离固体部分和液体部分；和(d)回收固体部分。
• Processes for producing monoammonium adipate from fermentation broths containing diammonium adipate, monoammonium adipate and/or adipic acid, and conversion of monoammonium adipate to adipic acid
  申请人：BioAmber S.A.S.

  公开号：EP2383250A1

  公开（公告）日：2011-11-02

  A process for making MAA from a clarified DAA-containing fermentation broth includes (a) distilling the broth to form an overhead that includes water and ammonia, and a liquid bottoms that includes MAA, at least some DAA, and at least about 20 wt% water; (b) cooling the bottoms to a temperature sufficient to cause the bottoms to separate into a DAA-containing liquid portion in contact with a MAA-containing solid portion that is substantially free of DAA; (c) separating the solid portion from the liquid portion; and (d) recovering the solid portion.

  从含有澄清DAA的发酵液中制备MAA的过程包括：(a)蒸馏发酵液，形成包括水和氨的顶部，以及包括MAA、至少一些DAA和至少约20 wt%水的液体底部；(b)将底部冷却至足以使底部分离为与含有DAA的液体部分接触的MAA含有的几乎不含DAA的固体部分；(c)将固体部分与液体部分分离；和(d)回收固体部分。
• [EN] PROCESSES FOR THE PRODUCTION OF HYDROGENATED PRODUCTS AND DERIVATIVES THEREOF<br/>[FR] PROCÉDÉS POUR LA PRODUCTION DE PRODUITS HYDROGÉNÉS ET DÉRIVÉS DE CEUX-CI
  申请人：BIOAMBER SAS

  公开号：WO2011159551A1

  公开（公告）日：2011-12-22

  Processes for making hydrogenated products including caprolactame (CL) caprolactone (CLO) or 1,6-hexanediol (HDO) and derivative thereof from monoammonium adipate (MAA) and/or adipic acid (AA) obtained from a clarified diammonium adipate-containing (DAA-containing) fermentation broth or monoammonium adipate-containing (MAA-containing) fermentation broth.

  从澄清的含二铵脂肪二酸盐（DAA含盐）发酵液或含单铵脂肪二酸盐（MAA含盐）发酵液中获得的单铵脂肪二酸盐（MAA）和/或脂肪二酸（AA）制备氢化产品，包括己内酰胺（CL）、己内酯（CLO）或1,6-己二醇（HDO）及其衍生物的工艺。