申请人:SOLVAY (Société Anonyme)
公开号:EP1811219A1
公开(公告)日:2007-07-25
The invention relates to a multilayer polymer structure [structure (S)] comprising a layer (α) comprising at least one polyamide [polymer (A)], said layer (α) being linked to a layer (γ) comprising at least one melt-processible fluoropolymer substantially free from recurring units derived from functional monomers [polymer (F)] via a layer (β), said layer (β) comprising a polymer composition (C-1), said polymer composition (C-1) comprising from 100% to 3% by weight of at least one functional fluoropolymer [polymer (I)], with respect to the total weight of the composition, and from 0 to 97 % by weight of at least one melt-processible fluoropolymer substantially free from recurring units derived from functional monomers [polymer (F)], with respect to the total weigh of the composition.
The multilayer structures of the invention enables obtaining structures with excellent adhesion between fluoropolymers and polyamides, whose components can withstand high processing temperature, such as those required for instance for aromatic polyamide processing and extremely harsh environment.
本发明涉及一种多层聚合物结构[结构(S)],包括一层(α),该层由至少一种聚酰胺[聚合物(A)]组成,所述层(α)通过层(β)与一层(γ)相连,所述层(γ)由至少一种可熔融加工的含氟聚合物组成,该含氟聚合物基本上不含源自功能单体[聚合物(F)]的递归单元,所述层(β)由聚合物组合物(C-1)组成、所述聚合物组合物(C-1)包括至少一种功能性含氟聚合物[聚合物(I)](占组合物总重量的 100%至 3%)和至少一种可熔融加工的含氟聚合物(占组合物总重量的 0%至 97%)(基本上不含源自功能性单体的递归单元[聚合物(F)])。
本发明的多层结构可以使含氟聚合物和聚酰胺之间产生极佳的粘合力,其组分可以承受较高的加工温度,例如芳香族聚酰胺加工所需的温度和极端恶劣的环境。