Providing hydrophobic surfaces on hydrophilic inorganic materials with metal glycolates
申请人:ADEKA ARGUS CHEMICAL CO., Ltd.
公开号:EP0133702A2
公开(公告)日:1985-03-06
Hydrophilic inorganic materials are provided with a hydrophobic surface by treatment with a metal glycolate compound having the formula:
wherein:
Me is Sn, Ti, Zr or Al;
when Me is Sn, Ti or Zr, m is 1, and when Me is Al, m is 0;
R is alkyl having from about eight to about fifty carbon atoms;
X, and X2 are independently selected from the group consisting of -R,. -OR,, -OCOR1, -SR,, -S(CH2)nCOOR1,
X1 and X2 can be combined to form
R1 is selected from the group consisting of alkyl having from one to about eighteen carbon atoms; alkenyl having from three to about eighteen carbon atoms; cycloalkyl having from five to about eight carbon atoms; and aryl and alkaryl having from six to about eighteen carbon atoms;
R2 is alkylene having from one to about fifty carbon atoms;
R3 is selected from the group consisting of hydrogen, alkyl having from one to about eighteen carbon atoms; alkenyl having from three to about eighteen carbon atoms; cycloalkyl having from five to about eight carbon atoms; and aryl and alkaryl having from six to about eighteen carbon atoms;
r is 0 or 1.
亲水性无机材料通过使用具有以下式子的羟基乙酸金属化合物进行处理而具有疏水性表面:
其中
Me 是 Sn、Ti、Zr 或 Al;
当 Me 为 Sn、Ti 或 Zr 时,m 为 1,当 Me 为 Al 时,m 为 0;
R 是具有约 8 至约 50 个碳原子的烷基;
X和X2独立地选自由-R、-OR、-OCOR、-OCOR、-OCOR、-OCOR、-OCOR、-OCOR、-OCOR、-OCOR、-OCOR、-OCOR、-OCOR-OR,,-OCOR1,-SR,,-S(CH2)nCOOR1、
X1 和 X2 可以组合形成
R1 选自具有 1 至约 18 个碳原子的烷基;具有 3 至约 18 个碳原子的烯基;具有 5 至约 8 个碳原子的环烷基;以及具有 6 至约 18 个碳原子的芳基和烷芳基;
R2 是具有 1 至约 50 个碳原子的亚烷基;
R3 选自由氢、具有 1 至约 18 个碳原子的烷基、具有 3 至约 18 个碳原子的烯基、具有 5 至约 8 个碳原子的环烷基以及具有 6 至约 18 个碳原子的芳基和烷芳基组成的组;
r 为 0 或 1。