申请人:Herlihy L Shaun
公开号:US20050165126A1
公开(公告)日:2005-07-28
Photoinitiator compounds of formula (I):
where: A represents a direct bond or a group of formula —[O(CHR
7
CHR
6)
a
]
y
—, —[O(CH
2
)
b
CO]
y
—, or —[O(CH
2
)
b
CO]
(y-1)
—[O(CHR
7
CHR
6
)
a
]—, where one of R
6
and R
7
is hydrogen and the other is hydrogen or methyl; a is a number from 1 to 2; b is a number from 4 to 5; Q is a residue of a polyhydroxy compound having 2 to 6 hydroxy groups; x is a number greater than 1 but no greater than the number of available hydroxyl groups in Q; y is a number from 1 to 10; R
1
, R
2
, R
3
and R
4
are individually the same or different and each is hydrogen, hydroxy, or alkyl; or R
1
and R
3
are joined to form a fused ring system with the benzene rings to which they are attached; and R
5
represents a direct bond, an oxygen atom or a methylene group} are useful as cationic photoinitiators, especially for use in surface coating applications, such as printing inks and varnishes, and which are intended to be cured by polymerisation initiated by radiation.
公式(I)的光引发剂化合物:其中:A代表直接键或式—[O(CHR7CHR6)a]y—、—[O(CH2)bCO]y—或—[O(CH2)bCO](y-1)—[O(CHR7CHR6)a]—的基团,其中R6和R7中的一个是氢,另一个是氢或甲基;a是1到2的数字;b是4到5的数字;Q是具有2到6个羟基的多羟基化合物的残基;x是大于1但不大于Q中可用羟基数的数字;y是1到10的数字;R1、R2、R3和R4分别相同或不同,且每个都是氢、羟基或烷基;或R1和R3连接成与它们附着的苯环形成的融合环系统;R5代表直接键、氧原子或亚甲基基团},可用作离子型光引发剂,特别是用于表面涂层应用,例如印刷油墨和清漆,并且旨在通过辐射引发的聚合反应进行固化。