4,4'-bis(4''-(4'''-chlorobenzenesulfonyl)phenoxy)diphenylsulfone | 121464-64-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4,4'-bis(4''-(4'''-chlorobenzenesulfonyl)phenoxy)diphenylsulfone
• 英文别名: 1,1'-{Sulfonylbis[(4,1-phenylene)oxy]}bis[4-(4-chlorobenzene-1-sulfonyl)benzene]；1-[4-(4-chlorophenyl)sulfonylphenoxy]-4-[4-[4-(4-chlorophenyl)sulfonylphenoxy]phenyl]sulfonylbenzene
• CAS: 121464-64-0
• 化学式: C₃₆H₂₄Cl₂O₈S₃
• 分子量: 751.686
• InChiKey: AMXOAKAUPNFPPA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.6
• 重原子数：
  49
• 可旋转键数：
  10
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  146
• 氢给体数：
  0
• 氢受体数：
  8

反应信息

• 作为反应物：
  描述：

  4,4'-bis(4''-(4'''-chlorobenzenesulfonyl)phenoxy)diphenylsulfone 在 {Ni(pyridine)4}Cl2 四丁基碘化铵 、 三苯基膦 、 锌 作用下， 以 N,N-二甲基乙酰胺 为溶剂， 反应 0.5h， 以8%的产率得到
  参考文献：
  名称：

  Synthesis of Strained Macrocyclic Biaryls for Enthalpy-Driven Ring-Opening Polymerization

  摘要：

  Polymerizable macrocyclic biarylene-ether-ketones and biarylene-ether-sulfones are accessible from linear, bis(chloro)-terminated oligomers via nickel-catalyzed, intramolecular coupling under pseudo-high-dilution conditions. Single-crystal X-ray analyses of the resulting cyclo-oligomers reveal extremely distorted and highly strained geometries, with 4,4 '-biphenylene units showing deviations of up to 70 degrees from linearity.

  DOI：

  10.1021/ma0517796
• 作为产物：
  描述：

  4,4-二苯氧基二苯砜 、 4-氯苯磺酰氯 在 三氯化铁 作用下， 以 various solvent(s) 为溶剂， 以66.9%的产率得到4,4'-bis(4''-(4'''-chlorobenzenesulfonyl)phenoxy)diphenylsulfone
  参考文献：
  名称：

  Synthesis of Strained Macrocyclic Biaryls for Enthalpy-Driven Ring-Opening Polymerization

  摘要：

  Polymerizable macrocyclic biarylene-ether-ketones and biarylene-ether-sulfones are accessible from linear, bis(chloro)-terminated oligomers via nickel-catalyzed, intramolecular coupling under pseudo-high-dilution conditions. Single-crystal X-ray analyses of the resulting cyclo-oligomers reveal extremely distorted and highly strained geometries, with 4,4 '-biphenylene units showing deviations of up to 70 degrees from linearity.

  DOI：

  10.1021/ma0517796

文献信息

• Polyarylene, Process For Producing The Same, Solid Polyelectrolyte, And Proton-Conductive Film
  申请人：Yamakawa Yoshitaka

  公开号：US20080015389A1

  公开（公告）日：2008-01-17

  A polyarylene having a structural unit shown by the following formula (1) is disclosed. wherein X and Y indicate a divalent organic group or a single bond, Z shows an oxygen atom or a sulfur atom, R represents at least one atom or group selected from the group consisting of a hydrogen atom, a fluorine atom, an alkyl group, and a fluorine-substituted alkyl group, a is an integer of 1 to 20, n is an integer of 1 to 5, and p is an integer of 1 to 10.

  披氏芳烃具有以下公式（1）所示的结构单元，其中X和Y表示二价有机基团或单键，Z表示氧原子或硫原子，R代表至少选择自氢原子、氟原子、烷基团和氟代烷基团组成的一种原子或基团，a为1至20之间的整数，n为1至5之间的整数，p为1至10之间的整数。
• ELECTROLYTE MEMBRANE, MEMBRANE-ELECTRODE ASSEMBLY, AND SOLID POLYMER FUEL CELL
  申请人：JSP CORPORATION

  公开号：US20160149250A1

  公开（公告）日：2016-05-26

  The present invention relates to an electrolyte membrane, a membrane-electrode assembly and a polymer electrolyte fuel cell. The electrolyte membrane contains a polymer (1) including a hydrophobic structural unit and a structural unit having a proton-conducting group and a polymer (2) including a hydrophobic structural unit having no sulfonic group which is different from the hydrophobic structural unit of the polymer (1).

  本发明涉及一种电解质膜、膜电极组件和聚合物电解质燃料电池。该电解质膜包含聚合物（1），其中包括一个疏水结构单元和一个具有质子导电基团的结构单元，以及聚合物（2），其中包括一个疏水结构单元，没有磺酸基团，其与聚合物（1）的疏水结构单元不同。
• Halogenated aromatic compound, polymer thereof, and proton-conductive membrane comprising same
  申请人：JSR Corporation

  公开号：EP1245555B1

  公开（公告）日：2009-08-19
• POLYARYLENE-BASED POLYMER, PREPARATION METHOD FOR THE SAME, AND POLYMER ELECTROLYTE MEMBRANE FOR FUEL CELL USING THE POLYMER
  申请人：Hwang Inchul

  公开号：US20120309857A1

  公开（公告）日：2012-12-06

  Disclosed herein is a polyarylene-based polymer, a preparation method for the same, and a polymer electrolyte membrane for fuel cell using the polymer. The polyarylene-based polymer, which is designed to have long side chains of a hydrophilic moiety and dense sulfonic acid groups, may improve the formation of ion channels when fabricating a polymer membrane and also ensures good chemical stability of the hydrophilic moiety and good dimensional stability against water. Further, the preparation method of the present invention simplifies production of the polymer, and polymer electrolyte membranes using the polymer exhibits improved properties as a polymer electrolyte membrane for a fuel cell, such as high proton conductivity, even under an atmosphere of low water uptake, and good dimensional stability against a long-term exposure to water.
• US7163988B2
  申请人：——

  公开号：US7163988B2

  公开（公告）日：2007-01-16