Methyl 2,5-dichlorobenzenesulfinate | 1364683-79-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Methyl 2,5-dichlorobenzenesulfinate
• CAS: 1364683-79-3
• 化学式: C₇H₆Cl₂O₂S
• 分子量: 225.095
• InChiKey: JBNUQUPOMABESL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.7
• 重原子数：
  12
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  45.5
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  Methyl 2,5-dichlorobenzenesulfinate 在 一水合肼 作用下， 以 二甲基亚砜 为溶剂， 反应 1.0h， 以95%的产率得到di(2,5-dichlorophenyl)disulfide
  参考文献：
  名称：

  Synthesis of Diaryl Disulfides via Mild Reduction of Arylsulfinates with Hydrazine Monohydrate in DMSO

  摘要：

  Arylsulfinates were reduced with hydrazine monohydrate at room temperature in dimethylsulfoxide (DMSO) to afford diaryl disulfides in good yields. A dramatic solvent effect was observed, and DMSO was found to be the best solvent for the reaction.

  DOI：

  10.1080/00397911.2010.535947

文献信息

• Synthesis of Diaryl Disulfides via Mild Reduction of Arylsulfinates with Hydrazine Monohydrate in DMSO
  作者：Rui-Heng Zhu、Xiao-Xin Shi

  DOI：10.1080/00397911.2010.535947

  日期：2012.4.15

  Arylsulfinates were reduced with hydrazine monohydrate at room temperature in dimethylsulfoxide (DMSO) to afford diaryl disulfides in good yields. A dramatic solvent effect was observed, and DMSO was found to be the best solvent for the reaction.