2,2-Diethoxyethyl 2-methylprop-2-enoate | 95983-99-6

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: 2,2-Diethoxyethyl 2-methylprop-2-enoate
• CAS: 95983-99-6
• 化学式: C₁₀H₁₈O₄
• 分子量: 202.25
• InChiKey: MRORRLLLFWTVKW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.8
• 重原子数：
  14
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.7
• 拓扑面积：
  44.8
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  甲基丙烯酸乙酯 、 2-溴-1,1-二乙氧基乙烷 生成 2,2 Diethoxy-ethyl-methacrylate 、 2,2-Diethoxyethyl 2-methylprop-2-enoate
  参考文献：
  名称：

  Polyaldehyde/polyacetal compositions

  摘要：

  本发明揭示了水溶性单体和由其衍生的水溶性聚合物。这些材料可以与其他乙烯基单体一起使用，形成与纤维素基底反应的水溶性聚合物，特别是在造纸生产中应用时，可以获得显著提高的强度。聚合物含有至少2摩尔％的单体，该单体由化学结构表示：##STR1##其中R为H，CH.sub.3或C.sub.2H.sub.5；A为O或N（R.sub.1）；B为CH.sub.2，CH.sub.2CH.sub.2O，##STR2##而D为##STR3##其中R.sub.1为H，CH.sub.3，C.sub.2H.sub.5，（CH.sub.2CH.sub.2O）.sub.nH或（B）.sub.qD，其中q为1-6，除非B含有氮，在这种情况下q始终为1；R.sub.2为H，CH.sub.3，C.sub.2H.sub.5或（CH.sub.2CH.sub.2O）.sub.nH；R.sub.4和R.sub.5可以相同也可以不同，对于每个单独的出现，它们为H，CH.sub.3，C.sub.2H.sub.5；Z来自于群Cl，Br，I，NO.sub.3，SO.sub.4等；m范围从0-6；n范围从1-6。

  公开号：

  US04605718A1

文献信息

• POLY(ORGANOPHOSPHAZENE) COMPOSITION FOR BIOMATERIALS
  申请人：SONG Soo-Chang

  公开号：US20130004455A1

  公开（公告）日：2013-01-03

  Provided are a use of chemically-crosslinkable, poly(organophosphazene)s for biomaterials, chemically-crosslinkable poly(organophosphazene)s with a physiologically active substance covalently-bonded thereto, a use thereof for biomaterials, and a process for preparing the same. The chemical crosslinkings can be made by UV irradiation, and/or a crosslinker, and/or an additive, and/or an enzyme, and/or a mixing of at least one polymer.

  提供了一种用于生物材料的化学交联可用的聚（有机磷氮烷）的用途，与生理活性物质共价结合的化学交联聚（有机磷氮烷），以及其用于生物材料的用途，以及制备这些材料的过程。这种化学交联可以通过紫外辐射、交联剂、添加剂、酶、至少一种聚合物的混合等方法实现。
• Cross-Linkable Monomers and Polymers and the Use Thereof
  申请人：Jakob Martin

  公开号：US20110190462A1

  公开（公告）日：2011-08-04

  The invention relates to novel cross-linkable monomers that may be polymerized with ethylenically unsaturated comonomers to form cross-linkable copolymers. Said copolymers may particularly be used in the form of aqueous dispersions as formaldehyde-free adhesives or as coatings with good water resistance. The cross-linkable monomer is a compound in acid or salt form comprising an anion of the formula (I) and one or more cations for producing electrical neutrality, where R 1 and R 2 represent, independently of one another, hydrogen alkyl, cycloalkyl, aryl, aralkyl, —COOR 5 , —COO − cat + or —CON(R 6 R 7 ), R 6 and R 7 represent, independently of one another, hydrogen, alkyl, or aryl, cat 4 represents a monovalent cation, and one of the groups R 1 or R 2 may also represent a group —X—R 4 —CR 5 (OH)SO 3 − ), wherein X, R 4 , and R 5 assume one of the meanings listed below, R 3 represents hydrogen, alkyl, or aryl, X is selected from the group of direct C—C bond, —O—, —CH 2 —O—, —CH 2 —NR 8 —, —COO— or —CONR 8 —, R 8 represents hydrogen, alkyl, or aryl, R 4 represents alkylene, polyoxyalkylene, cycloalkylene, or arylene, and R 5 represents hydrogen, alkyl, cycloalkyl, or aryl.

  本发明涉及新型交联单体，可以与乙烯基不饱和共聚单体聚合形成交联共聚物。所述共聚物可以作为无甲醛粘合剂的水性分散液或具有良好耐水性的涂料使用。所述交联单体是一种酸或盐形式的化合物，包括公式（I）的阴离子和一个或多个阳离子以产生电中性，其中R1和R2分别独立地表示氢，烷基，环烷基，芳基，芳基烷基，-COOR5，-COO-cat+或-CON（R6R7），R6和R7分别独立地表示氢，烷基或芳基，cat4表示一价阳离子，R1或R2中的一个也可以表示一个基团-X-R4-CR5（OH）SO3-，其中X，R4和R5分别取下面列出的含义之一，R3表示氢，烷基或芳基，X从直接C-C键，-O-，-CH2-O-，-CH2-NR8-，-COO-或-CONR8-的群中选择，R8表示氢，烷基或芳基，R4表示烷基，聚氧烷基，环烷基或芳基，R5表示氢，烷基，环烷基或芳基。
• Pretreated plastic dental appliances and methods
  申请人：MINNESOTA MINING AND MANUFACTURING COMPANY

  公开号：EP0706785A1

  公开（公告）日：1996-04-17

  A method for pretreating a plastic dental appliance having a surface to be bonded to a tooth comprising applying a pretreatment composition comprising i) a polymerizable component, ii) a solvent capable of at least partially solubilizing the plastic dental appliance, and iii) a photoinitiator system to the surface of the dental appliance. Components i) and ii) may be the same or different materials. The polymerizable component of the pretreatment composition is then polymerized by exposure to actinic radiation. The present invention also provides pretreated plastic dental appliances prepared by this method. Optionally, the plastic dental appliance may additionally be precoated with an orthodontic adhesive and packaged accordingly.

  一种预处理塑料牙科器械的方法，该器械表面要与牙齿粘合，该方法包括在牙科器械表面涂抹预处理组合物，该组合物包括 i) 可聚合成分；ii) 至少能部分溶解塑料牙科器械的溶剂；iii) 光引发剂系统。成分 i) 和 ii) 可以是相同或不同的材料。然后将预处理组合物中的可聚合成分暴露在光辐射下进行聚合。本发明还提供了通过该方法制备的预处理塑料牙科器械。可选地，塑料牙科器械可额外预涂正畸粘合剂并进行相应包装。
• Poly(organophosphazene) composition for biomaterials
  申请人：Korea Institute of Science and Technology

  公开号：EP2540764A2

  公开（公告）日：2013-01-02

  Provided are a use of chemically-crosslinkable, poly(organophosphazene)s for biomaterials, chemically-crosslinkable poly(organophosphazene)s with a physiologically active substance covalently-bonded thereto, a use thereof for biomaterials, and a process for preparing the same. The chemical crosslinkings can be made by UV irradiation, and/or a crosslinker, and/or an additive, and/or an enzyme, and/or a mixing of at least one polymer.

  本发明提供了可化学交联聚（有机膦）烯在生物材料中的用途、与生理活性物质共价结合的可化学交联聚（有机膦）烯、其在生物材料中的用途以及制备方法。化学交联可以通过紫外线照射、和/或交联剂、和/或添加剂、和/或酶和/或至少一种聚合物的混合来实现。
• US4508594A
  申请人：——

  公开号：US4508594A

  公开（公告）日：1985-04-02