[1-(Hydroxymethyl)cyclohexyl]methyl 2-methylprop-2-enoate | 850715-51-4

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: [1-(Hydroxymethyl)cyclohexyl]methyl 2-methylprop-2-enoate
• CAS: 850715-51-4
• 化学式: C₁₂H₂₀O₃
• 分子量: 212.28
• InChiKey: AFSQFGXTYWXFPP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.6
• 重原子数：
  15
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.75
• 拓扑面积：
  46.5
• 氢给体数：
  1
• 氢受体数：
  3

文献信息

• DIENE-BASED CARBOXYLATE ANION AND SALT THEREOF, AND POLYMERIZABLE OR CURABLE COMPOSITION THEREOF
  申请人：Kaneko Tomomasa

  公开号：US20130197123A1

  公开（公告）日：2013-08-01

  The claimed invention provides a novel compound not having been studied before, that is, a diene carboxylate anion that contains a specific structure, and a salt thereof. The claimed invention further provides a diene carboxylate anion and a salt thereof, especially a metal salt thereof, which are easily soluble in general organic solvents, reactive diluents, and resins, may be in a liquid state at normal temperature depending on the structure, and have high polymerizability. Polymerization/curing of these produces a resin to which many ionic bonds and a metal are introduced, providing various properties such as hardness, scratch resistance, anti-fingerprint property, gas-barrier property, water vapor barrier property, oxygen absorption property, ultraviolet protection, infrared protection, color development and coloring, high refractive index, adhesion, various catalytic abilities, fluorescence ability and light-emitting ability, optical amplification, dispersibility, and antistatic properties. In addition, the anion and the salt can be used for raw materials for functional fine particles and for metal nanoparticle composites, and also for MOD materials. The claimed invention also provides an advantageous method for producing the diene carboxylate anion and the salt thereof.

  所述发明提供了一种新颖的化合物，此化合物以前未被研究过，即一种含有特定结构的二烯二酸盐阴离子及其盐。所述发明进一步提供了一种二烯二酸盐阴离子及其盐，特别是其金属盐，这些盐在一般有机溶剂、反应性稀释剂和树脂中易溶解，在常温下可能处于液态，具有高聚合性。这些的聚合/固化产生的树脂引入了许多离子键和金属，提供了硬度、抗刮擦性、防指纹性、气体屏障性、阻水汽性、氧气吸收性、紫外线保护、红外线保护、颜色开发和着色、高折射率、粘附性、各种催化能力、荧光能力和发光能力、光学放大、分散性和抗静电性等各种性能。此外，该阴离子和盐可用作功能性细颗粒和金属纳米粒子复合材料的原材料，也可用于MOD材料。所述发明还提供了一种生产二烯二酸盐阴离子及其盐的优势方法。
• Materials leading to improved dental composites and dental composites made therefrom
  申请人：Anton Robert Douglas

  公开号：US20060258770A1

  公开（公告）日：2006-11-16

  This invention relates to composite materials for restorative dentistry. More particularly, it relates to new components for dental composites, which impart an attractive combination of good mechanical properties and low shrinkage.

  本发明涉及修复牙科的复合材料。更具体地说，它涉及用于牙科复合材料的新组分，这些组分赋予了良好的机械性能和低收缩率的有吸引力的组合。
• Radiation-curable resin composition for adhesives
  申请人：Yoshizawa Junji

  公开号：US20050244752A1

  公开（公告）日：2005-11-03

  A radiation-curable resin composition for adhesives comprising (A) a bisphenol-type epoxy (meth)acrylate having a hydroxyl group, (B) a polyfunctional (meth)acrylate having an aliphatic cyclic structure or an aromatic cyclic structure other than the component (A), and (C) a photoinitiator, wherein the content of the component (A) and the content of the component (B) in the composition are respectively 30 wt % or more. The radiation-curable resin composition for adhesives of the present invention exhibits excellent adhesion to silver, silicon compound, and aluminum, superior moisture-heat resistance, and fast curability, especially at the edge of the disk, and therefore is very useful in the manufacture of optical disks in comparison with conventional adhesives.

  一种辐射固化树脂黏合剂组合物，包括（A）具有羟基的双酚型环氧（甲基）丙烯酸酯，（B）具有脂肪环结构或除组分（A）以外的芳香环结构的多官能团（甲基）丙烯酸酯，以及（C）光引发剂，其中组合物中组分（A）的含量和组分（B）的含量分别为30重量％或更高。本发明的辐射固化树脂黏合剂组合物对银、硅化合物和铝具有优异的粘附性能，具有优异的耐潮热性和快速固化性能，特别是在光盘边缘处，与传统黏合剂相比，在光盘制造中非常有用。
• Plastic lens
  申请人：——

  公开号：US20030055200A1

  公开（公告）日：2003-03-20

  A plastic lens, an optical molded article, a film or a sheet formed of a copolycarbonate resin comprising a structural unit (I) of the following general formula (I), 1 and a structural unit (II) of the following formula (II), 2 the structural unit (I) having a molar amount percentage of 15 to 85% on the basis of the total amount of the structural units (I) and (II). According to the present invention, there are provided a plastic lens, an optical molded article, and the like, which are excellent in physical properties such as transparency, thermal stability and impact resistance and are excellent in optical properties such as a balance between a refractive index and an Abbe's number and a photoelasticity constant.

  本发明提供了一种塑料镜片、光学模制品、膜或片，其由包括下列通式（I）的结构单元（I）和下列通式（II）的结构单元（II）组成的共聚碳酸酯树脂形成，其中结构单元（I）在结构单元（I）和结构单元（II）的总量的基础上具有15至85％的摩尔量百分比。根据本发明，提供了一种塑料镜片、光学模制品等，其在物理性质（如透明度、热稳定性和抗冲击性）和光学性质（如折射率和阿贝数之间的平衡以及光弹常数）方面均表现出优异的特性。
• CURABLE COMPOSITION, CURED ARTICLE OBTAINED THEREFROM AND PROCESS FOR PREPARATION OF THE SAME
  申请人：Miyamoto Masahiro

  公开号：US20110269894A1

  公开（公告）日：2011-11-03

  Fine polymer particles are dispersed as primary particles in a vinyl monomer to provide a high quality composition in which the dispersed state and stability of the particles are regulated to a high degree and to provide a curable composition being excellent in handleability and using fine polymer particles as a toughness-imparting agent. For the above, the curable composition of the present invention comprises 100 parts by weight of a vinyl monomer (A) and 0.1 to 100 parts by weight of fine polymer particles (B) having a volume average particle size of 0.05 to 1 m, in which the fine polymer particles (B) are dispersed in the form of primary particles in the vinyl monomer (A).

  细聚合物粒子被分散为主要粒子在乙烯单体中，以提供高品质的组合物，其中粒子的分散状态和稳定性得到高度调节，并使用细聚合物粒子作为增加韧性的剂，提供可固化的组合物，其操作性能优异。为此，本发明的可固化组合物包括100重量份的乙烯单体（A）和0.1至100重量份的细聚合物粒子（B），其体积平均粒径为0.05至1μm，其中细聚合物粒子（B）以主要粒子的形式分散在乙烯单体（A）中。