di(4'-methyl-4-biphenylyl)amine | 587023-36-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: di(4'-methyl-4-biphenylyl)amine
• 英文别名: bis(4'-methyl-biphenyl-4-yl)amine；4-(4-methylphenyl)-N-[4-(4-methylphenyl)phenyl]aniline
• CAS: 587023-36-7
• 化学式: C₂₆H₂₃N
• 分子量: 349.475
• InChiKey: ZDTPCDRWXNSCQQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.4
• 重原子数：
  27
• 可旋转键数：
  4
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  12
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  di(4'-methyl-4-biphenylyl)amine 、 N,N-双(联苯-4-基)-4'-溴联苯-4-胺 在 bis-triphenylphosphine-palladium(II) chloride sodium t-butanolate 作用下， 以 xylene 为溶剂， 反应 24.0h， 生成 N,N-diphenyl-4-amino-N',N'-di(4'-methyl-4-biphenylyl)-4'-amino-1,1'-biphenyl
  参考文献：
  名称：

  EP1584614

  摘要：

  公开号：
• 作为产物：
  描述：

  N,N-di(4'-methyl-4-biphenyl)benzylamine 在 palladium 10% on activated carbon 氢气 作用下， 以 乙醇 、 氯仿 为溶剂， 反应 30.0h， 生成 di(4'-methyl-4-biphenylyl)amine
  参考文献：
  名称：

  EP1584614

  摘要：

  公开号：

文献信息

• COMPOUND
  申请人：CAMBRIDGE DISPLAY TECHNOLOGY LIMITED

  公开号：US20170040556A1

  公开（公告）日：2017-02-09

  The present invention relates to a compound of general formula (I) which can transport holes in an organic optoelectronic device, and to blends and solutions comprising the compound of general formula (I): wherein X is C, Si or Ge; A is a group of formula (II) wherein Z is N, P, NH, O or S; E is C 1-10 alkyl or H; W is substituted or unsubstituted C 5-14 aryl or substituted or unsubstituted C 6-16 alkyl; e is an integer from 1 to 4; and z is 1 or 2; B, C and D are each independently A, H, C 1 -C 12 alkyl, C 5-14 aryl or OH; and a, b, c and d are each independently an integer from 1 to 5.

  本发明涉及一种通式（I）的化合物，该化合物可在有机光电器件中传输空穴，以及包含通式（I）的混合物和溶液：其中X为C，Si或Ge；A为式（II）的基团：其中Z为N，P，NH，O或S；E为C1-10烷基或H；W为取代或未取代的C5-14芳基或取代或未取代的C6-16烷基；e为1至4的整数；z为1或2；B、C和D各自独立地为A、H、C1-C12烷基、C5-14芳基或OH；a、b、c和d各自独立地为1至5的整数。
• Crystalline oxotitanylphthalocyanine and electrophotographic photoreceptor using the same
  申请人：SHARP KABUSHIKI KAISHA

  公开号：EP0997783A2

  公开（公告）日：2000-05-03

  An object of the invention is to improve the photosensitivity characteristics, characteristics on repeated use and stability of a photoreceptor. A photosensitive layer (4a, 4b) formed on a conductive support (1) of a photoreceptor (8a-8d) contains crystalline oxotitanylphthalocyanine having major peaks in an X-ray diffraction spectrum at Bragg angles (2θ ± 0.2°) of 7.3°, 9.4°, 9.6°, 11.6°, 13.3°, 17,9°, 24.1° and 27.2°, wherein a peak bundle formed by overlapping the peaks at 9.4° and 9.6° is the largest peak, and the peak at 27.2° is the secondary largest peak as a charge generating substance (2). Furthermore, it contains a bisamine compound, an N,N'-bisenamine compound, a styryl compound, an amine-hydrazone compound, a benzofuran-bishydrazone compound, a bisenamine compound, a benzofuran-bishydrazone compound or a benzofuran-bis-cyclic hydrazone compound represented by the particular structural formulae as a charge transporting substance (3).

  本发明的目的是改善感光器的光敏特性、重复使用特性和稳定性。在光感受器（8a-8d）的导电支架（1）上形成的光敏层（4a、4b）含有结晶的氧代酞菁，其 X 射线衍射谱中布拉格角（2θ ± 0.2°）的主要峰值为 7.3°、9.4°、9.6°、11.6°、13.3°、17.9°、24.1°和 27.2°，其中由 9.4°和 9.6°处的峰重叠形成的峰束是最大峰，而 27.2°处的峰是作为电荷生成物质的次大峰 (2)。此外，它还含有双胺化合物、N,N'-联苯胺化合物、苯乙烯基化合物、胺腙化合物、苯并呋喃双腙化合物、双烯胺化合物、苯并呋喃双腙化合物或苯并呋喃双环腙化合物作为电荷传输物质（3）。
• AROMATIC AMINE DERIVATIVE AND ORGANIC ELECTROLUMINESCENCE ELEMENT
  申请人：IDEMITSU KOSAN CO., LTD.

  公开号：EP1584614A1

  公开（公告）日：2005-10-12

  A novel aromatic amine derivative having an asymmetric structure; and an organic electroluminescence device comprising a cathode, an anode and an organic thin film layer which is disposed between the cathode and the anode and comprises at least one layer comprising a light emitting layer, wherein at least one layer in the organic thin film layer comprises the above aromatic amine derivative singly or as a component of a mixture. Crystallization of the molecules is suppressed, and the yield in the production of the organic electroluminescence device can be increased.

  一种具有不对称结构的新型芳香胺衍生物；以及一种有机电致发光器件，该器件包括一个阴极、一个阳极和一个有机薄膜层，该有机薄膜层设置在阴极和阳极之间，并包括至少一层发光层，其中有机薄膜层中的至少一层由上述芳香胺衍生物单独或作为混合物的组分组成。分子的结晶被抑制，有机电致发光器件的生产率可以提高。
• Compound
  申请人：CAMBRIDGE DISPLAY TECHNOLOGY LIMITED

  公开号：US10205108B2

  公开（公告）日：2019-02-12

  The present invention relates to a compound of general formula (I) which can transport holes in an organic optoelectronic device, and to blends and solutions comprising the compound of general formula (I): wherein X is C, Si or Ge; A is a group of formula (II) wherein Z is N, P, NH, O or S; E is C1-10 alkyl or H; W is substituted or unsubstituted C5-14 aryl or substituted or unsubstituted C6-16 alkyl; e is an integer from 1 to 4; and z is 1 or 2; B, C and D are each independently A, H, C1-C12 alkyl, C5-14 aryl or OH; and a, b, c and d are each independently an integer from 1 to 5.

  本发明涉及一种可在有机光电器件中传输空穴的通式（I）化合物，以及包含通式（I）化合物的混合物和溶液： 其中 X 是 C、Si 或 Ge； A 是式 (II) 的基团 其中 Z 是 N、P、NH、O 或 S； E 是 C1-10 烷基或 H W 是取代或未取代的 C5-14 芳基或取代或未取代的 C6-16 烷基； e 是 1 至 4 的整数；以及 z 是 1 或 2； B、C 和 D 各自独立地为 A、H、C1-C12 烷基、C5-14 芳基或 OH；以及 A、B、C 和 D 各自独立地为 1 至 5 的整数。
• Aromatic amine derivative and organic electroluminescence element
  申请人：Kawamura Hisayuki

  公开号：US20060134458A1

  公开（公告）日：2006-06-22

  A novel aromatic amine derivative having an asymmetric structure; and an organic electroluminescence device comprising a cathode, an anode and an organic thin film layer which is disposed between the cathode and the anode and comprises at least one layer comprising a light emitting layer, wherein at least one layer in the organic thin film layer comprises the above aromatic amine derivative singly or as a component of a mixture. Crystallization of the molecules is suppressed, and the yield in the production of the organic electroluminescence device can be increased.

  一种具有不对称结构的新型芳香胺衍生物；以及一种有机电致发光器件，该器件包括一个阴极、一个阳极和一个有机薄膜层，该有机薄膜层设置在阴极和阳极之间，并包括至少一层发光层，其中有机薄膜层中的至少一层由上述芳香胺衍生物单独或作为混合物的组分组成。分子的结晶被抑制，有机电致发光器件的生产率可以提高。