γ,γ-Bis--valeriansaeure-butylester | 16501-16-9

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: γ,γ-Bis--valeriansaeure-butylester
• 英文别名: 4,4-Di(tert.-amylperoxy)-valeriansaeure-butylester；n-butyl-4,4-bis(t-amylperoxy)valerate；Butyl 4,4-bis[(2-methylbutan-2-yl)peroxy]pentanoate；butyl 4,4-bis(2-methylbutan-2-ylperoxy)pentanoate
• CAS: 16501-16-9
• 化学式: C₁₉H₃₈O₆
• 分子量: 362.507
• InChiKey: PAKRLBFYNABWNT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.8
• 重原子数：
  25
• 可旋转键数：
  15
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.95
• 拓扑面积：
  63.2
• 氢给体数：
  0
• 氢受体数：
  6

文献信息

• PRIMER MIXTURE OF CROSSLINKING INITIATOR AND PROMOTER
  申请人：ARKEMA FRANCE

  公开号：US20150239997A1

  公开（公告）日：2015-08-27

  A primer mixture intended for crosslinking polyethylene, including at least an initiator of free radicals chosen from organic peroxides, azo compounds or mixtures thereof, wherein the mixture has said free-radical initiator and at least one crosslinking promoter chosen from the cycloalkanes having 5 to 7 carbon atoms, substituted by 1 to 3 vinyl, allyl or isopropenyl groups, the aromatic compounds substituted by 1 to 3 vinyl, allyl or isopropenyl groups, the methacrylate, acrylate and maleimide monomers being multi-substituted, and in that the weight ratio of free-radical initiator to the crosslinking promoter is greater than or equal to 1, and preferably between 1.5 and 4. Also, a method and to a use related to this primer mixture.

  一种用于交联聚乙烯的底漆混合物，包括至少一种自由基引发剂，所述自由基引发剂选择自有机过氧化物、偶氮化合物或其混合物中的一种，其中混合物具有所述自由基引发剂和至少一种选择自于环戊烷、环己烷、环庚烷的交联促进剂，所述交联促进剂被1至3个乙烯基、丙烯基或异丙烯基取代的，被1至3个乙烯基、丙烯基或异丙烯基取代的芳香族化合物，以及多取代的甲基丙烯酸酯、丙烯酸酯和马来酰亚胺单体，其中自由基引发剂与交联促进剂的重量比大于或等于1，且优选在1.5至4之间。此外，还涉及一种与该底漆混合物相关的方法和用途。
• CO-CROSSLINKER SYSTEMS FOR ENCAPSULATION FILMS COMPRISING UREA COMPOUNDS
  申请人：ULBRICHT Daniel

  公开号：US20160177013A1

  公开（公告）日：2016-06-23

  A first composition (A) contains (i) at least one compound (I) selected from the group consisting of triallyl isocyanurate, and triallyl cyanurate, wherein the compound (I) is preferably triallyl isocyanurate; and (ii) at least one urea compound. A second composition (B) contains the first composition (A) and at least one polyolefin copolymer. Composition (B) is used for producing a film for encapsulating an electronic device, in particular a solar cell.

  第一种组合物（A）包含（i）至少一种从三烯基异氰酸酯和三烯基氰酸酯组成的化合物（I），其中化合物（I）最好是三烯基异氰酸酯；和（ii）至少一种脲化合物。第二种组合物（B）包含第一种组合物（A）和至少一种聚烯烃共聚物。组合物（B）用于生产用于封装电子设备的薄膜，特别是太阳能电池。
• CO-CROSSLINKER SYSTEMS FOR ENCAPSULATION FILMS COMPRISING BIS(ALKENYLAMIDE) COMPOUNDS
  申请人：ULBRICHT Daniel

  公开号：US20160177007A1

  公开（公告）日：2016-06-23

  A first composition (A) contains (i) at least one compound (I) selected from the group consisting of triallyl isocyanurate, and triallyl cyanurate, wherein the compound (I) is preferably triallyl isocyanurate, and (ii) at least one bis(alkenylamide) compound. A second composition (B) contains the first composition (A) and at least one polyolefin copolymer. The composition (B) is used for the production of a film for encapsulation of an electronic device, especially a solar cell.

  第一种组合物（A）包含（i）至少一种从三烯基异氰酸酯和三烯基氰酸酯组成的群体中选择的化合物（I），其中化合物（I）最好是三烯基异氰酸酯，以及（ii）至少一种双（烯基酰胺）化合物。第二种组合物（B）包含第一种组合物（A）和至少一种聚烯烃共聚物。组合物（B）用于生产用于封装电子设备，特别是太阳能电池的膜。
• Novel unsaturated peroxides, polymeric derived therefrom and their uses
  申请人：ELF ATOCHEM NORTH AMERICA, INC.

  公开号：EP0667339A1

  公开（公告）日：1995-08-16

  Novel unsaturated peroxide compositions of Structure A, are disclosed where the R-Q- grouping contains a polymerizable carbon-carbon double bound, i.e. R is, inter alia, alkyl of 1 to 18 carbons; Q is, inter alia, where -(X-Ri) shows the point of attachment of the X-R1 group and (R)- shows the point of attachment of the R group to the Q diradical and R2 and R3 include hydrogen; -X- includes a direct bond and -R1 is a peroxide-containing radical, e.g., wherein R6, R7, R8 and R9 are, inter alia, alkyl of 1 to 4 carbons and R10 includes t-alkyl of 4 to 12 carbons. Further, polymeric peroxide compositions derived from them and their uses are disclosed.

  公开了结构 A.的新型不饱和过氧化物组合物、 公开了结构 A 的新型不饱和过氧化物组合物，其中 R-Q-基团含有可聚合的碳碳双键，即 R 除其他外为 1 至 18 碳原子的烷基；Q 除其他外为 1 至 18 碳原子的烷基、 其中 -(X-Ri) 表示 X-R1 基团的连接点，(R)- 表示 R 基团与 Q 二叉基团的连接点，R2 和 R3 包括氢；-X- 包括直接键，-R1 是含过氧化物的基团，如 其中 R6、R7、R8 和 R9 除其他外为 1 至 4 个碳原子的烷基，R10 包括 4 至 12 个碳原子的 t-烷基。此外，还公开了由它们衍生的聚合物过氧化物组合物及其用途。
• Initiator compositions
  申请人：Arkema Inc.

  公开号：EP1614698A1

  公开（公告）日：2006-01-11

  Peroxide/diluent initiator compositions are provided which reduce the formation of VOCs during the manufacture of ethylenically unsaturated monomer, oligomer and polymer resins.

  过氧化物/稀释剂引发剂组合物可减少乙烯基不饱和单体、低聚物和聚合物树脂生产过程中挥发性有机化合物的形成。