1-Chloro-2-(2-phenoxyethoxy)benzene | 105658-36-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: 1-Chloro-2-(2-phenoxyethoxy)benzene
• CAS: 105658-36-4
• 化学式: C₁₄H₁₃ClO₂
• mdl: MFCD20538226
• 分子量: 248.7
• InChiKey: OJRKKJZDTZSQJN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.2
• 重原子数：
  17
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.142
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

文献信息

• HEAT-SENSITIVE RECORDING MATERIAL
  申请人：Fuji Photo Film Co., Ltd.

  公开号：EP1466751A1

  公开（公告）日：2004-10-13

  (A) The invention discloses a thermosensitive recording material comprising: a support; and a thermosensitive recording layer formed on the support, the thermosensitive recording layer containing an electron-donating colorless dye and an electron-accepting compound which develops color upon a reaction with the electron-donating colorless dye, wherein the thermosensitive recording material satisfies at least one of the following conditions (1) to (3). (1) an image density when thermal printing is performed from a side, of the support, having the thermosensitive recording layer with printing energy of 15.2 mJ/mm2 is 1.20 or more, and the thermosensitive recording material is used for a recording device having a printing speed of 10 cm/sec or more; (2) the thermosensitive recording material contains a sensitizer comprising at least one compound selected from the group consisting of 2-benzyloxynaphthalene, dimethylbenzyloxalate, m-terphenyl, ethyleneglycol tolyl ether, p-benzyl biphenyl, 1,2-diphenoxymethyl benzene, diphenyl sulfone and 1,2-diphenoxy ethane, and the image density after the thermosensitive recording material is brought into contact with a heat source of 70°C for 5 seconds is 0.15 or less; (3) the electron-accepting compound is a compound represented by the following Formula (1) Formula (1)R1-Ph-SO2R2   wherein R1 represents a hydroxyl group or an alkyl group, R2 represents -Ph, -NH-Ph, -Ph-OR3 or -NH-CO-NH-Ph, R3 represents an alkyl group, Ph represents a phenyl group and may be substituted with a substituent containing -SO2R2, and a volume-averaged grain size of the electron-donating colorless dye and electron-accepting compound is in a range of 0.5 to 1.0 µm. (B) A thermosensitive recording material comprises a thermosensitive recording layer containing an electron-donating colorless dye, an electron-accepting compound which develops color upon a reaction with the electron-donating colorless dye and a sensitizer, wherein the thermosensitive recording material satisfies at least one of the following conditions (1) to (3). (1) An image density when thermal printing is performed with a printing energy is 1.20 or more, and the thermosensitive recording material is used for a recording device having a printing speed of 10 cm/sec or more. (2) An image density after the thermosensitive recording material is brought into contact with a heat source of 70°C for 5 seconds is 0.15 or less, and the sensitizer is 2-benzyloxynaphthalene or the like. (3) the electron-accepting compound is a compound represented by R1-Ph-SO2R2 wherein R1 represents a hydroxyl group or an alkyl group, R2 represents -Ph, -NH-Ph, -Ph-OR3 or -NH-CO-NH-Ph, R3 represents an alkyl group, Ph represents a phenyl group and may be substituted with a substituent containing SO2R2, and a volume-averaged grain size is in a range of 0.5 to 1.0 µm.

  (A) 本发明公开了一种热敏记录材料，包括：支撑物；和形成在支撑物上的热敏记录层，该热敏记录层含有电子捐赠无色染料和电子接受化合物，该电子接受化合物与电子捐赠无色染料反应后显色，其中热敏记录材料至少满足以下条件（1）至（3）中的一个。 (1) 当从具有热敏记录层的支撑物的一侧进行热打印时，打印能量为 15.2 mJ/mm2 的图像密度为 1.20 或以上，且热敏记录材料用于打印速度为 10 厘米/秒或以上的记录设备； (2) 热敏记录材料含有敏化剂，该敏化剂包含至少一种选自以下组别的化合物：2-苄氧基萘、二甲基苄氧基萘、间三联苯、乙二醇对二甲苯醚、对苄基联苯、1,2-二苯氧基甲基苯、二苯砜和 1,2-二苯氧基乙烷，且热敏记录材料与 70°C 的热源接触 5 秒钟后的图像密度为 0.15 或更低； (3) 电子接受化合物是由下式表示的化合物 式(1) 式(1)R1-Ph-SO2R2 其中 R1 代表羟基或烷基，R2 代表-Ph、-NH-Ph、-Ph-OR3 或-NH-CO-NH-Ph，R3 代表烷基，Ph 代表苯基并可被含有-SO2R2 的取代基取代，且电子氖型无色染料和电子接受化合物的体积平均粒度在 0.5至1.0微米。 (B) 一种热敏记录材料，它包括一个热敏记录层，该层含有一种电子致性无色染料、一种电子受体化合物，该化合物在与电子致性无色染料和敏化剂反应后显色，其中热敏记录材料至少满足下列条件(1)至(3)之一。 (1) 当使用打印能量进行热打印时，图像密度为 1.20 或以上，且热敏记录材料用于打印速度为 10 厘米/秒或以上的记录设备。 (2) 热敏记录材料与 70°C 的热源接触 5 秒后的图像密度为 0.15 或更低，且敏化剂为 2-苄氧基萘或类似物。 (3) 电子接受化合物是由 R1-Ph-SO2R2 所代表的化合物，其中 R1 代表羟基或烷基，R2 代表-Ph、-NH-Ph、-Ph-OR3 或-NH-CO-NH-Ph，R3 代表烷基，Ph 代表苯基并可被含有 SO2R2 的取代基取代，且体积平均粒度在 0.5 至 1.0 微米范围内。
• Heat-sensitive recording material
  申请人：FUJI PHOTO FILM CO., LTD.

  公开号：US20030114307A1

  公开（公告）日：2003-06-19

  A heat-sensitive recording material includes a support having disposed thereon a heat-sensitive color-forming layer that includes an electron-donating leuco-dye, an electron-receiving compound and an UV absorbent, wherein the layer contains 4-hydroxybenzenesulfonanilide as the electron-receiving compound. Because the layer includes 4-hydroxybenzenesulfonanilide, the heat-sensitive recording material has high sensitivity and improved image preservability, chemical resistance and sticking resistance.

  一种热敏记录材料包括一个支撑物，支撑物上有一个热敏成色层，该层包括一个电子供体白基染料、一个电子接收化合物和一个紫外线吸收剂，其中该层含有作为电子接收化合物的 4-羟基苯磺酰苯胺。由于层中含有 4-羟基苯磺酰苯胺，热敏记录材料具有高灵敏度、更好的图像保存性、耐化学性和抗粘连性。
• REVEALABLE SUBSTRATES AND METHODS OF PRODUCING AND USING SAID SUBSTRATES
  申请人：Virtual Graphics, LLC

  公开号：EP4031607A1

  公开（公告）日：2022-07-27
• US6818592B2
  申请人：——

  公开号：US6818592B2

  公开（公告）日：2004-11-16
• US7098168B2
  申请人：——

  公开号：US7098168B2

  公开（公告）日：2006-08-29