High vinylidene chloride content interpolymer coating resins and method of preparation
申请人:THE DOW CHEMICAL COMPANY
公开号:EP0068461A1
公开(公告)日:1983-01-05
A process for preparing in aqueous emulsion an interpolymer composition have polymerized therein 86 to 92 mole percent vinylidene chloride, 14 to 8 mole percent of a comonomer mixture of methyl methacrylate and a comonomer selected from the group consisting of acrylonitrile, methacrylic acid and methacrylonitrile in a ratio of the comonomer to methyl methacrylate of from 0.5 : 1 to 2 : 1, and 0.5 to 1.0 weight percent itaconic acid, based on weight of vinylidene chloride plus comonomer mixture. The interpolymers are prepared in a three step process wherein the monomer feeding is step-wise reduced for a portion of Step III and a polymerization initiator is added at the same constant rate as in Steps I an II. The process reduces the amount of unreacted mixed monomers remaining after monomer addition is completed and the detrimental results of a large variation in polymer composition particularly from high vinylidene chloride fractions.
一种在水乳液中制备互聚物组合物的工艺,其中聚合有 86 至 92 摩尔%的偏二氯乙烯、14 至 8 摩尔%的甲基丙烯酸甲酯和选自丙烯腈、甲基丙烯酸和甲基丙烯腈组的共聚单体混合物,共聚单体与甲基丙烯酸甲酯的比例为 0.5 : 1 至 2 : 1,以及 0.5 至 1.0 重量百分比的衣康酸(以偏二氯乙烯加共聚单体混合物的重量为基准)。通过三步法制备互聚物,其中步骤 III 的部分单体进料量逐步减少,聚合引发剂以与步骤 I 和 II 相同的恒定速率加入。该工艺减少了单体添加完成后剩余的未反应混合单体的量,也减少了聚合物成分变化较大的不利影响,特别是高偏氯乙烯馏分。