2-Propenoic acid, 4-phenoxybutyl ester | 103969-85-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: 2-Propenoic acid, 4-phenoxybutyl ester
• 英文别名: 4-phenoxybutyl prop-2-enoate
• CAS: 103969-85-3
• 化学式: C₁₃H₁₆O₃
• 分子量: 220.26
• InChiKey: RGLHEMZXTOODQW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.1
• 重原子数：
  16
• 可旋转键数：
  8
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.31
• 拓扑面积：
  35.5
• 氢给体数：
  0
• 氢受体数：
  3

文献信息

• POLYMERIZABLE COMPOUND, COMPOSITION, POLYMER, OPTICALLY ANISOTROPIC BODY, LIQUID CRYSTAL DISPLAY ELEMENT, AND ORGANIC EL DEVICE
  申请人：DIC Corporation

  公开号：US20170260150A1

  公开（公告）日：2017-09-14

  It is an object of the present invention to provide a polymerizable compound having a good liquid crystal property, a good alignment property, sufficient solubility in solvents, high preservation stability in a solution state, and high optical stability; a composition including the polymerizable compound; a polymer produced by polymerizing the polymerizable compound, such as a resin produced using the polymerizable compound; an optically anisotropic body including the polymer; and a liquid crystal display element and an organic EL device that include the optically anisotropic body. As a result of conducting intensive studies in order to achieve the above object, the compound represented by General Formula (I) is developed.

  本发明的目的是提供一种具有良好液晶性能、良好对准性能、在溶剂中具有足够溶解性、在溶液状态下具有高保持稳定性和高光学稳定性的可聚合化合物；包括该可聚合化合物的组合物；通过聚合该可聚合化合物而产生的聚合物，如使用该可聚合化合物生产的树脂；包括聚合物的光学各向异性体；以及包括光学各向异性体的液晶显示元件和有机EL器件。为了实现上述目标，进行了深入研究，开发了由一般式（I）表示的化合物。
• Rate controlled release of a pharmaceutical agent in a biodegradable device
  申请人：Kunzler Jay

  公开号：US20070218103A1

  公开（公告）日：2007-09-20

  Matrix controlled diffusion drug delivery systems comprising a therapeutically effective amount of one or more pharmaceutically active agents entrapped in a copolymer which is a reaction product of a monomeric mixture comprising one or more acrylate ester and/or methacrylate ester-containing monomers and one or more acrylamido-containing monomers are disclosed. Also disclosed are processes for their preparations and methods for their use.

  本发明揭示了矩阵控制扩散药物传递系统，其中包括一种或多种药物活性剂的治疗有效量，这些活性剂被困在共聚物中，该共聚物是由单体混合物反应生成的，该单体混合物包括一种或多种丙烯酸酯和/或甲基丙烯酸酯含有单体和一种或多种丙烯酰胺含有单体。还揭示了其制备过程和使用方法。
• (METH)ACRYLOYL-TERMINATED POLYISOBUTYLENE POLYMER, METHOD FOR PRODUCING THE SAME, AND ACTIVE ENERGY RAY-CURABLE COMPOSITION
  申请人：KANEKA CORPORATION

  公开号：US20140243444A1

  公开（公告）日：2014-08-28

  The purpose of the present invention is to provide a polymer having a low halogen atom content remaining in the polymer, a simple production method thereof, an active energy ray-curable composition that can be rapidly cured by an irradiation of a small amount of light, and a cured product thereof. These purpose can be achieved by an active energy ray-curable composition, including a polyisobutylene polymer (A) represented by the following general formula (1) (wherein R 1 represents a monovalent or polyvalent aromatic hydrocarbon group, or a monovalent or a polyvalent aliphatic hydrocarbon group; A represents a polyisobutylene polymer; R 2 represents a divalent saturated hydrocarbon group having 2-6 carbon atoms, which contains no hetero atoms; R 3 and R 4 each represent hydrogen, a monovalent hydrocarbon group having 1-20 carbon atoms, or an alkoxy group having 1-20 carbon atoms; R 5 represents hydrogen or a methyl group; and n denotes a natural number), and an active energy ray polymerization initiator (B).

  本发明的目的是提供一种聚合物，其聚合物中保留有较低的卤素原子含量，以及其简单的生产方法，一种能够通过少量光辐照快速固化的活性能量射线固化组合物以及其固化产物。这些目的可以通过一种活性能量射线固化组合物来实现，包括以下通式（1）所表示的聚异丁烯聚合物（A）（其中R1表示单价或多价芳香烃基或单价或多价脂肪烃基；A表示聚异丁烯聚合物；R2表示含有2-6个碳原子的二价饱和碳氢基团，不含杂原子；R3和R4分别表示氢、具有1-20个碳原子的单价碳氢基团或具有1-20个碳原子的烷氧基；R5表示氢或甲基基团；n表示自然数），以及活性能量射线聚合引发剂（B）。
• Hydrophilic interpolymers of acrylic acid and an olefin or a styrene
  申请人：The B.F. GOODRICH Company

  公开号：EP0047009A1

  公开（公告）日：1982-03-10

  Highly water absorbent polymers are obtained by polymerizing 70 to 93 weight percent of acrylic acid and 7 to 30 weight percent of a comonomer selected from a-olefins having 6 to 18 carbon atoms, styrene and substituted styrenes. The polymerization can be carried out in the presence of a free radical catalyst in which case the polymer is thereafter preferably neutralized with a base. Alternatively, carboxylic groups are neutralized prior to polymerization by subjecting the monomer mixture either to radiation or to UV light in the presence of a photoinitiator. Such polymers are useful in the manufacture of articles which absorb water or body fluids.

  高吸水性聚合物是由 70 至 93 重量百分比的丙烯酸和 7 至 30 重量百分比的共聚单体聚合而成，共聚单体选自具有 6 至 18 个碳原子的 a-烯烃、苯乙烯和取代的苯乙烯。聚合反应可在自由基催化剂存在下进行，在这种情况下，聚合物随后最好用碱中和。或者，在聚合之前，先将单体混合物置于有光引发剂存在的辐射或紫外线下，使羧基中和。这种聚合物可用于制造吸水或体液的物品。
• (METH)ACRYLOYL-TERMINATED POLYISOBUTYLENE POLYMER, METHOD FOR PRODUCING SAME, AND ACTIVE ENERGY RAY-CURABLE COMPOSITION
  申请人：Kaneka Corporation

  公开号：EP2762506A1

  公开（公告）日：2014-08-06

  The purpose of the present invention is to provide a polymer having a low halogen atom content remaining in the polymer, a simple production method thereof, an active energy ray-curable composition that can be rapidly cured by an irradiation of a small amount of light, and a cured product thereof. These purpose can be achieved by an active energy ray-curable composition, including a polyisobutylene polymer (A) represented by the following general formula (1) (wherein R1 represents a monovalent or polyvalent aromatic hydrocarbon group, or a monovalent or a polyvalent aliphatic hydrocarbon group; A represents a polyisobutylene polymer; R2 represents a divalent saturated hydrocarbon group having 2-6 carbon atoms, which contains no hetero atoms; R3 and R4 each represent hydrogen, a monovalent hydrocarbon group having 1-20 carbon atoms, or an alkoxy group having 1-20 carbon atoms; R5 represents hydrogen or a methyl group; and n denotes a natural number), and an active energy ray polymerization initiator (B).

  本发明的目的是提供一种在聚合物中残留卤原子含量低的聚合物、一种简单的生产方法、一种可通过少量光照射快速固化的活性能量射线固化组合物及其固化产品。这些目的可以通过一种活性能量射线固化组合物来实现，该组合物包括由以下通式（1）表示的聚异丁烯聚合物（A）（其中 R1 代表一价或多价芳香烃基团，或一价或多价脂肪烃基团；A 代表聚异丁烯聚合物；R2 代表具有 2-6 个碳原子、不含杂原子的二价饱和烃基；R3 和 R4 分别代表氢、具有 1-20 个碳原子的一价烃基或具有 1-20 个碳原子的烷氧基；R5 代表氢或甲基；n 表示自然数），以及活性能量射线聚合引发剂 (B)。