[2-Hydroxy-3-[4-[2-[4-(2-hydroxy-3-prop-2-enoyloxypropoxy)cyclohexyl]propan-2-yl]cyclohexyl]oxypropyl] prop-2-enoate | 82810-36-4

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 甘油脂
• 英文名称: [2-Hydroxy-3-[4-[2-[4-(2-hydroxy-3-prop-2-enoyloxypropoxy)cyclohexyl]propan-2-yl]cyclohexyl]oxypropyl] prop-2-enoate
• CAS: 82810-36-4
• 化学式: C₂₇H₄₄O₈
• 分子量: 496.642
• InChiKey: RHYFWDXPRUVTNO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.9
• 重原子数：
  35
• 可旋转键数：
  16
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.78
• 拓扑面积：
  112
• 氢给体数：
  2
• 氢受体数：
  8

反应信息

• 作为产物：
  描述：

  丙烯酸 、 2,2’-[(1-甲基亚乙基)双(4,1-环亚己基氧基亚甲基)]双环氧乙烷 在 Cr(III) isooctanoate 、 2,6-二叔丁基-4-甲基苯酚 作用下， 反应 6.03h， 生成 [2-Hydroxy-3-[4-[2-[4-(2-hydroxy-3-prop-2-enoyloxypropoxy)cyclohexyl]propan-2-yl]cyclohexyl]oxypropyl] prop-2-enoate
  参考文献：
  名称：

  Uv-curable epoxy acrylates

  摘要：

  公式（A）、（B）的环氧丙烯酸酯，以及包含化合物（A）或（B）中至少一种的环氧丙烯酸酯混合物是新颖的，并且可用于具有高紫外线稳定性的涂料材料或胶粘剂中。

  公开号：

  US20060052628A1

文献信息

• SINGLE LAYER FILM AND HYDROPHILIC MATERIAL COMPOSED OF SAME
  申请人：Mitsui Chemicals, Inc.

  公开号：EP1955782A1

  公开（公告）日：2008-08-13

  A single layer film containing at least one anionic hydrophilic group selected from a sulfonic acid group, a carboxyl group and a phosphate group, wherein an anion concentration ratio (Sa/Da) of an anion concentration at a surface (Sa) to an anion concentration at a deep part (Da) is 1.1 or more. The single layer film is a copolymer prepared by polymerizing a composition containing a compound (I) represented by the general formula (1) ([X]s[M1]1[M2]m (1)) and a compound (II) having two or more (meth)acryloyl groups in a molecule at a molar ratio of 15:1 to 1: 30 and having a water contact angle of 30° or less. Such a single layer film has high hydrophilicity and surface hardness and is excellent in antifogging property, antifouling property and antistatic property, thus is useful as an antifogging material, an antifouling material, an antistatic material and a multilayer body.

  一种单层薄膜，含有至少一个选自磺酸基、羧基和磷酸基的阴离子亲水基团，其中表层阴离子浓度（Sa）与深层阴离子浓度（Da）之比（Sa/Da）为 1.1 或以上。单层膜是一种共聚物，它是通过聚合含有通式(1)（[X]s[M1]1[M2]m (1)）表示的化合物(I)和分子中含有两个或两个以上(甲基)丙烯酰基的化合物(II)的组合物制备而成，摩尔比为 15:1 至 1:30，水接触角为 30°或更小。这种单层薄膜具有高亲水性和表面硬度，防雾性能、防污性能和抗静电性能优异，因此可用作防雾材料、防污材料、抗静电材料和多层体。
• Polarizing plate and image display apparatus comprising same
  申请人：LG CHEM, LTD.

  公开号：US10012772B2

  公开（公告）日：2018-07-03

  The present invention relates to a polarizing plate including: a polarizer; and a protective layer formed on at least one surface of the polarizer, in which the protective layer is a cured product of a radical curable composition including: (A) a radical polymerizable compound including at least one hydrophilic functional group in a molecule thereof; (B) a multifunctional (meth)acrylic compound; (C) a phosphate compound including one or two (meth)acryl groups in a molecule thereof; and (D) a radical initiator, and an image display device including the same.

  本发明涉及一种偏光板，包括：偏光板；和形成在偏光板至少一个表面上的保护层，其中保护层是一种可自由基固化组合物的固化产物，该组合物包括：(A) 可自由基聚合的化合物，其分子中包括至少一个亲水官能团；(B) 多功能（甲基）丙烯酸化合物；(C) 磷酸酯化合物，其分子中包括一个或两个（甲基）丙烯酸基团；和 (D) 自由基引发剂，以及包括上述内容的图像显示设备。
• Radical curable adhesive composition, and polarizing plate and optical member comprising same
  申请人：LG CHEM, LTD.

  公开号：US10228491B2

  公开（公告）日：2019-03-12

  The present invention relates to a radical-curable adhesive composition including a radical-polymerizable first compound that includes at least two hydroxyl groups in the molecule, and having hydroxyl value of 500 mg KOH/g or greater, and a polarizing plate and an optical member including the radical-curable adhesive composition.

  本发明涉及一种可自由基固化的粘合剂组合物，包括可自由基聚合的第一种化合物，其分子中至少包含两个羟基，羟基值大于等于 500 毫克 KOH/g，以及包括该可自由基固化的粘合剂组合物的偏光板和光学部件。
• Photocurable composition, denture base, and plate denture
  申请人：MITSUI CHEMICALS, INC.

  公开号：US10562995B2

  公开（公告）日：2020-02-18

  Provided is a photocurable composition including a monomer component including: a monomer (X) containing, within one molecule, two aromatic rings and two (meth)acryloyloxy groups, and having an Mw of from 400 to 580, and a monomer (H) containing, within one molecule, at least one of a hydroxyl group or a carboxy group, and a (meth)acryloyloxy group, and having an Mw of from 100 to 700; and a photopolymerization initiator. The composition has a functional group value (a) of from 0.5×10−3 to 2.0×10−3 mol/g. Functional group value (a)=(nH/MH)×PH  Formula (a) wherein nH represents the total number of hydroxyl groups and carboxy groups contained in one molecule of the (meth)acrylic monomer (H); MH represents the Mw of the (meth)acrylic monomer (H); and PH represents the mass ratio of the (meth)acrylic monomer (H) with respect to the total amount of the (meth)acrylic monomer component.

  本发明提供了一种光固化组合物，其单体成分包括：单分子内含有两个芳香环和两个（甲基）丙烯酰氧基且分子量在 400 至 580 之间的单体（X），以及单分子内含有羟基或羧基和（甲基）丙烯酰氧基中至少一个且分子量在 100 至 700 之间的单体（H）；以及一种光聚合引发剂。该组合物的官能团值（a）为 0.5×10-3 至 2.0×10-3 mol/g。 官能团值 (a)=(nH/MH)×PH 公式 (a) 其中，nH 表示一个分子的(甲基)丙烯酸单体(H)中所含羟基和羧基的总数；MH 表示(甲基)丙烯酸单体(H)的分子量；PH 表示(甲基)丙烯酸单体(H)相对于(甲基)丙烯酸单体组分总量的质量比。
• Reactive polyurethane dispersions
  申请人：Hewlett-Packard Development Company, L.P.

  公开号：US10640599B2

  公开（公告）日：2020-05-05

  The present disclosure is drawn to a reactive polyurethane dispersion including a polymer strand having a polymer backbone that has two ends terminating at a first capping unit and a second capping unit. The polymer backbone can include polymerized monomers including a reactive diol and a diisocyanate. The reactive diol can be an acrylate-containing diol, a methacrylate-containing diol, or combination thereof. The first capping unit can be an acrylate-containing monoalcohol or a methacrylate-containing monoalcohol reacted with an isocyanate group of the diisocyanate. The second capping unit can be 3-(cyclohexylamino)-1-propanesulfonic acid or 2-(cyclohexylamino)ethanesulfonic acid reacted with an isocyanate group of the diisocyanate.

  本公开涉及一种反应性聚氨酯分散体，包括具有聚合物骨架的聚合物链，该聚合物骨架的两端分别终止于第一封端单元和第二封端单元。聚合物骨架可包括聚合单体，其中包括活性二元醇和二异氰酸酯。活性二元醇可以是含丙烯酸酯的二元醇、含甲基丙烯酸酯的二元醇或它们的组合。第一封端单元可以是与二异氰酸酯的异氰酸酯基反应的含丙烯酸酯的一元醇或含甲基丙烯酸酯的一元醇。第二封端单元可以是与二异氰酸酯的异氰酸酯基反应的 3-(环己基氨基)-1-丙磺酸或 2-(环己基氨基)乙磺酸。