Ultrathin membrane of polymethacrylate or polycrotonate and device provided with ultrathin membrane
申请人:NIPPON OIL AND FATS COMPANY, LIMITED
公开号:EP0421435A2
公开(公告)日:1991-04-10
An ultrathin polymeric membrane has a membrane thickness of 10 to 1,000 Å. The membrane is constituted of polycarboxylate and obtained by the spin coating method or by the Langmuir-Blodgett method. The polycarboxylate contains recurrent units represented by the formula (I)
wherein R₁ and R₂ represent different groups and each stand for a methyl group or a hydrogen atom, and R represents a hydrocarbon group selected from the group consisting of a branched alkyl group having 3 to 12 carbon atoms, a cycloalkyl group having 3 to 12 carbon atoms, a substituted alkyl group having 2 to 6 carbon atoms, a substituted cycloalkyl group having 3 to 10 carbon atoms and a siloxanic hydrocarbon group.
一种超薄聚合物膜的膜厚为 10 至 1,000 Å。该膜由聚羧酸盐构成,通过旋涂法或朗缪尔-布洛杰特法获得。聚羧酸盐含有由式 (I) 表示的递归单元
其中,R₁ 和 R₂ 代表不同的基团,各自代表一个甲基或一个氢原子,R 代表一个烃基,选自具有 3 至 12 个碳原子的支链烷基、具有 3 至 12 个碳原子的环烷基、具有 2 至 6 个碳原子的取代烷基、具有 3 至 10 个碳原子的取代环烷基和硅氧烷烃基组成的组。