三(三溴新戊基)磷酸酯 | 19186-97-1

• 物质功能分类: 有机原料 - 羧酸类化合物及衍生物 - 羧酸酯及其衍生物
• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机磷酸及其衍生物
• 中文名称: 三(三溴新戊基)磷酸酯
• 中文别名: 三[[3-溴-2,2-二(溴甲基)]丙基]磷酸酯；(三(三溴新戊基)磷酸酯)；阻燃剂FR-680
• 英文名称: tris(tribromoneopentyl)phosphate
• 英文别名: Tris-(3-bromo-2,2-bis-(bromomethyl)-propyl)-phosphat；tris[3-bromo-2,2-bis(bromomethyl)propyl] phosphate
• CAS: 19186-97-1
• 化学式: C₁₅H₂₄Br₉O₄P
• 分子量: 1018.46
• InChiKey: BHYQWBKCXBXPKM-UHFFFAOYSA-N

物化性质

• 熔点：
  172-173 °C
• 沸点：
  719.3±60.0 °C(Predicted)
• 密度：
  2.324±0.06 g/cm3(Predicted)
• 溶解度：
  可溶于氯仿（少量）
• LogP：
  4.87 at 20℃

计算性质

• 辛醇/水分配系数(LogP)：
  6.7
• 重原子数：
  29
• 可旋转键数：
  18
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  44.8
• 氢给体数：
  0
• 氢受体数：
  4

安全信息

• 储存条件：
  室温且干燥环境下使用。

SDS

Material Safety Data Sheet

---

Section 1. Identification of the substance
Product Name: Tris(tribromoneopentyl)phosphate
Synonyms:

---

Section 2. Hazards identification
Harmful by inhalation, in contact with skin, and if swallowed.

---

Section 3. Composition/information on ingredients.
Ingredient name: Tris(tribromoneopentyl)phosphate
CAS number: 19186-97-1

---

Section 4. First aid measures
Skin contact: Immediately wash skin with copious amounts of water for at least 15 minutes while removing
contaminated clothing and shoes. If irritation persists, seek medical attention.
Eye contact: Immediately wash skin with copious amounts of water for at least 15 minutes. Assure adequate
flushing of the eyes by separating the eyelids with fingers. If irritation persists, seek medical
attention.
Inhalation: Remove to fresh air. In severe cases or if symptoms persist, seek medical attention.
Ingestion: Wash out mouth with copious amounts of water for at least 15 minutes. Seek medical attention.

---

Section 5. Fire fighting measures
In the event of a fire involving this material, alone or in combination with other materials, use dry
powder or carbon dioxide extinguishers. Protective clothing and self-contained breathing apparatus
should be worn.

---

Section 6. Accidental release measures
Personal precautions: Wear suitable personal protective equipment which performs satisfactorily and meets local/state/national
standards.
Respiratory precaution: Wear approved mask/respirator
Hand precaution: Wear suitable gloves/gauntlets
Skin protection: Wear suitable protective clothing
Eye protection: Wear suitable eye protection
Methods for cleaning up: Mix with sand or similar inert absorbent material, sweep up and keep in a tightly closed container
for disposal. See section 12.
Environmental precautions: Do not allow material to enter drains or water courses.

---

Section 7. Handling and storage
Handling: This product should be handled only by, or under the close supervision of, those properly qualified
in the handling and use of potentially hazardous chemicals, who should take into account the fire,
health and chemical hazard data given on this sheet.
Store in closed vessels, refrigerated.
Storage:

---

Section 8. Exposure Controls / Personal protection
Engineering Controls: Use only in a chemical fume hood.
Personal protective equipment: Wear laboratory clothing, chemical-resistant gloves and safety goggles.
General hydiene measures: Wash thoroughly after handling. Wash contaminated clothing before reuse.

---

Section 9. Physical and chemical properties
Appearance: Not specified
Boiling point: No data
No data
Melting point:
Flash point: No data
Density: No data
Molecular formula: C15H24Br9O4P
Molecular weight: 1018.5

---

Section 10. Stability and reactivity
Conditions to avoid: Heat, flames and sparks.
Materials to avoid: Oxidizing agents.
Possible hazardous combustion products: Carbon monoxide, hydrogen bromide.

---

Section 11. Toxicological information
No data.

---

Section 12. Ecological information
No data.

---

Section 13. Disposal consideration
Arrange disposal as special waste, by licensed disposal company, in consultation with local waste
disposal authority, in accordance with national and regional regulations.

---

Section 14. Transportation information
Non-harzardous for air and ground transportation.

---

Section 15. Regulatory information
No chemicals in this material are subject to the reporting requirements of SARA Title III, Section
302, or have known CAS numbers that exceed the threshold reporting levels established by SARA
Title III, Section 313.

---

SECTION 16 - ADDITIONAL INFORMATION
N/A

制备方法与用途

用途：添加型阻燃剂

反应信息

• 作为产物：
  描述：

  季戊四醇 在 溴 、 乙酸酐 、 尿素 、 aluminum (III) chloride 、 四氯化钛 、 四氯化锡 、 三氯氧磷 作用下， 生成 三(三溴新戊基)磷酸酯
  参考文献：
  名称：

  一种三(三溴新戊基)磷酸酯阻燃剂的一锅法合成工艺

  摘要：

  本发明公开了一种三(三溴新戊基)磷酸酯阻燃剂的一锅法合成工艺，它属于三(三溴新戊基)磷酸酯阻燃剂生产技术领域，采用一锅法合成工艺，首先以季戊四醇、溴素、尿素为原料反应得到三溴新戊基乙酸酯，然后在三溴新戊基乙酸酯中加入三氯氧磷、催化剂、缚酸剂合成三(三溴新戊基)磷酸酯，不需要单独合成三溴新戊醇后再以三溴新戊醇为原料合成三(三溴新戊基)磷酸酯，可以实现三(三溴新戊基)磷酸酯的“一锅”合成，工艺简化，提高了三(三溴新戊基)磷酸酯的生产效率，有利于三(三溴新戊基)磷酸酯的大规模工业化生产。本发明通过合理控制原料、反应时间及温度等工艺参数，缩短了反应时间，提高了产品的产率和纯度。

  公开号：

  CN112778356B

文献信息

• [EN] STERICALLY HINDERED AMINE STABILIZERS<br/>[FR] STABILISANTS D'AMINES À ENCOMBREMENT STÉRIQUE
  申请人：BASF SE

  公开号：WO2010142572A1

  公开（公告）日：2010-12-16

  The instant invention pertains to hindered amine compounds having at least two nitrogen atoms with different basicity. One part is substituted on the N-atom by alkoxy moieties and the other part is substituted on the N-atom by a hydroxy-alkyl moiety. These materials are particularly effective in stabilizing polymers, especially thermoplastic polyolefins, against the deleterious effects of oxidative, thermal and actinic radiation. The compounds are also particularly effective in stabilizing acid catalyzed and ambient cured coatings systems.

  这项瞬时发明涉及具有至少两个氮原子且碱度不同的受阻胺化合物。其中一部分在N原子上被烷氧基团取代，另一部分在N原子上被一个羟基-烷基基团取代。这些材料在稳定聚合物方面特别有效，尤其是热塑性聚烯烃，可以抵御氧化、热和光辐射的有害影响。这些化合物在稳定酸催化和环境固化的涂层系统方面也特别有效。
• SULFENAMIDES AS FLAME RETARDANTS
  申请人：SONGWON INTERNATIONAL AG

  公开号：US20160289566A1

  公开（公告）日：2016-10-06

  The present invention is in the field of flame retardants and relates to use of sulfenamides as flame retardants, in particular in polymeric substrates.

  本发明属于阻燃剂领域，涉及将硫代酰胺用作阻燃剂，特别是在聚合物基材中的使用。
• [EN] WATER COMPATIBLE STERICALLY HINDERED ALKOXYAMINES AND HYDROXY SUBSTITUTED ALKOXYAMINES<br/>[FR] ALCOXYAMINES STERIQUEMENT ENCOMBREES ET ALCOXYAMINES HYDROXY SUBSTITUEES HYDROCOMPATIBLES
  申请人：CIBA SC HOLDING AG

  公开号：WO2004076419A1

  公开（公告）日：2004-09-10

  Sterically hindered alkoxyamine and hydroxy substituted alkoxyamine stabilizer compounds are made water compatible via certain backbones with affinity towards water. The sterically hindered amines are for example of the formula where for example E and E’ are 2-hydroxycydohexyloxy, 2-hydroxy-2-methylpropoxy, benzyloxy, methoxy, propoxy, hexyloxy, heptyloxy, oclyloxy or cyclohexyloxy, Rx is for example -NH2+CH2CH20H Cl-, -NH3+ -OAc, =NOH, -NHCH(CH3)COO-K+,- NHCH2CH2NH(CH3)2+ -OAC, -NHCH2CH2SO3-K+, -NHCH(COO- K+)CH2CH2SCH3, -NHCH2COO- K+, -OCH(CH3)COO-K+, -OCH2CH2NH(CH3)2+ -OAC, -OCH2CH2SO3-K+, -OCH(COO- K+)CH2CH2SCH3 or -OCH2COO-K+, and where R5 comprises repeating units of -(OCH2CH2)-, -(OCH2CH2(CH3))-,-(CH2CHCOOH)-, -(CH2C(CH3)COOH)-, -(CH2CHCOOCH3)-, -(NHCH2CH2)-, -(CH2CHOH)-, -(CH2CHCONH2)-or -(CH2CH(NHCOH))-. These compounds are particularly effective in stabilizing aqueous polymer systems against the deleterious effects of oxidative, thermal and actinic radiation. The compounds are effective for example in stabilizing water borne coatings, aqueous inks, aqueous inkjet media and photocured aqueous systems.

  通过具有亲水性的特定骨架，使具有立体位阻的烷氧胺和羟基取代的烷氧胺稳定剂化合物与水相容。其中，立体位阻胺的示例为以下公式，其中 E 和 E’ 为 2-羟基环己氧基、2-羟基-2-甲基丙氧基、苄氧基、甲氧基、丙氧基、己氧基、庚氧基、辛氧基或环己氧基，Rx 为例如 -NH2+CH2CH20H Cl-, -NH3+ -OAc, =NOH, -NHCH(CH3)COO-K+,- NHCH2CH2NH(CH3)2+ -OAC, -NHCH2CH2SO3-K+, -NHCH(COO- K+)CH2CH2SCH3, -NHCH2COO- K+, -OCH(CH3)COO-K+, -OCH2CH2NH(CH3)2+ -OAC, -OCH2CH2SO3-K+, -OCH(COO- K+)CH2CH2SCH3 或 -OCH2COO-K+，R5 包括重复单元 -(OCH2CH2)-, -(OCH2CH2(CH3))-,-(CH2CHCOOH)-, -(CH2C(CH3)COOH)-, -(CH2CHCOOCH3)-, -(NHCH2CH2)-, -(CH2CHOH)-, -(CH2CHCONH2)- 或 -(CH2CH(NHCOH))-. 这些化合物在稳定水性聚合物体系抵抗氧化、热和光辐射的有害影响方面特别有效。这些化合物例如在稳定水性涂料、水性油墨、水性喷墨介质和光固化水性系统方面非常有效。
• USE OF PHOSPHOROUS-CONTAINING ORGANIC OXYIMIDES AS FLAME RETARDANTS AND/OR AS STABILIZERS FOR PLASTICS, FLAME-RETARDANT AND/OR STABILIZED PLASTIC COMPOSITIONS, METHOD FOR THE PRODUCTION THEREOF, MOULDED PART, PAINT AND COATINGS
  申请人：FRAUNHOFER-GESELLSCHAFT ZUR FÖRDERUNG DER ANGEWANDTEN FORSCHUNG E.V.

  公开号：US20170260366A1

  公开（公告）日：2017-09-14

  The present invention relates to the use of phosphorous-containing organic oxyimides according to the general formula (I) as flame retardant for plastic materials, as radical generators in plastic materials and/or stabilisers for plastics. In addition, the present invention relates to a flame-retardant plastic material moulding compound in which the previously described phosphorous-containing organic oxyimides are integrated, and also to a method for the production of the previously mentioned plastic material composition. Furthermore, the present invention relates to a moulded article, a paint or a coating from the previously mentioned flame-retardant plastic material composition.

  本发明涉及根据一般式(I)的含磷有机氧亚胺化合物作为塑料材料的阻燃剂，作为塑料材料中的自由基发生剂和/或塑料的稳定剂。此外，本发明涉及一种阻燃塑料材料成型复合物，其中集成了前述的含磷有机氧亚胺化合物，并且涉及一种用于制备前述塑料材料组合物的方法。此外，本发明涉及一种从前述阻燃塑料材料组合物制成的成型制品、涂料或涂层。
• [EN] PHOSPHO-SUBSTITUTED ALKOXYAMINE COMPOUNDS<br/>[FR] COMPOSÉS ALCOXYAMINE SUBSTITUÉS PAR DES GROUPES PHOSPHO
  申请人：BASF SE

  公开号：WO2011086114A1

  公开（公告）日：2011-07-21

  The invention relates to compounds of the group of so-called sterically hindered amines (HALS) which are substituted by phospho groups. The invention also relates to flame retardant compositions wherein these compounds are added to the polymer substrate.

  该发明涉及一类所谓的受空间位阻影响的胺化合物（HALS），这些化合物被磷基取代。该发明还涉及阻燃组合物，其中这些化合物被添加到聚合物基质中。