辛基二氯丙基磷酸酯 | 117617-70-6

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机磷酸及其衍生物
• 中文名称: 辛基二氯丙基磷酸酯
• 英文名称: Octyldichloropropyl phosphate
• 英文别名: 3,3-dichloropropyl octyl hydrogen phosphate
• CAS: 117617-70-6
• 化学式: C₁₁H₂₃Cl₂O₄P
• 分子量: 321.17
• InChiKey: LEYKLJDREJGQML-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.1
• 重原子数：
  18
• 可旋转键数：
  12
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  55.8
• 氢给体数：
  1
• 氢受体数：
  4

文献信息

• Method for handling maleimides
  申请人：NIPPON SHOKUBAI CO., LTD.

  公开号：EP0437342A2

  公开（公告）日：1991-07-17

  A method for handling a maleimide, which method comprises handling said maleimide in the presence of a stabilizer at a temperature exceeding the melting point thereof in a state kept in contact with a gas phase having a molecular oxygen content of not more than 10% by volume.

  一种处理马来酰亚胺的方法，该方法包括在有稳定剂存在的情况下，在与分子氧含量不超过 10%（体积分数）的气相接触的状态下，在超过其熔点的温度下处理所述马来酰亚胺。
• MALEIMIDE COMPOUND IMPROVED IN STORAGE STABILITY
  申请人：NIPPON SHOKUBAI CO., LTD.

  公开号：EP0627420A1

  公开（公告）日：1994-12-07

  A stabilized maleimide compound which is hardly discolored during storage, wherein the content of primary amines is 500 ppm or less, that of maleic anhydride is 5-2,000 ppm, and that of 2-amino-N-substituted succinimide is 300 ppm or less. It is preferable that the content of chlorine compounds be 10 ppm or less in terms of chlorine and that of volatile components having each a boiling point of 200 °C or below under an ordinary pressure be 2,000 ppm or less.

  一种在贮存期间几乎不褪色的稳定马来酰亚胺化合物，其中伯胺的含量为 500 ppm 或以下，马来酸酐的含量为 5-2,000 ppm，2-氨基-N-取代琥珀酰亚胺的含量为 300 ppm 或以下。氯化合物的含量最好不超过 10 ppm，而在常压下沸点不超过 200 °C 的挥发性成分的含量最好不超过 2,000 ppm。
• Acrylonitrile solutions of maleimides, method for preparation thereof, and acrylonitrile based copolymers obtained by use of the solutions
  申请人：NIPPON SHOKUBAI CO., LTD.

  公开号：EP0768300A1

  公开（公告）日：1997-04-16

  An acrylonitrile solution of maleimide manifesting transparency, precluding coloration and opacification during the course of handling, and excelling in stability, a method for the preparation of the acrylonitrile solution, and an acrylonitrile based copolymer obtained by using the acrylonitrile solution are provided. The acrylonitrile solution of maleimide is such that, when it is subjected to a forced coloration test, the differences Δ L, Δa, and Δb values (invariably as absolute values) each between L, a, and b values before and after the test are respectively not more than 5, not more than 5, and not more than 10. The acrylonitrile solution of maleimide is prepared by lowering the water content in the acrylonitrile solution to a level of not more than 0.1% by weight, or causing the acrylonitrile solution to permit coexistence therein of at least one member selected from the group consisting of alkyl-substituted hydroxybenzenes and hindered phenols and at least one member selected from the group consisting of phosphorous esters, phosphoric esters, phosphine, and phosphoric acid amides, or lowering the water content in the acrylonitrile solution to a level of not more than 0.3% by weight and causing the acrylonitrile solution to permit coexistence therein of at least one member selected from the group consisting of alkyl-substituted hydroxybenzenes, hindered phenols, phosphorous esters, phosphoric esters, phosphine, and phosphoric acid amides.

  本发明提供了一种马来酰亚胺的丙烯腈溶液，该溶液具有透明性，在处理过程中不会着色和不透明，而且稳定性极佳；还提供了一种丙烯腈溶液的制备方法，以及使用该丙烯腈溶液获得的丙烯腈基共聚物。 马来酰亚胺的丙烯腈溶液在进行强制着色试验时，试验前后 L 值、a 值和 b 值之间的差值 ΔL、Δa 和 Δb（均为绝对值）分别不超过 5、不超过 5 和不超过 10。马来酰亚胺的丙烯腈溶液是通过将丙烯腈溶液中的水含量降低到不超过 0.1%（按重量计），或使丙烯腈溶液允许至少一种选自烷基取代的羟苯和受阻酚组成的组的成员与至少一种选自磷酯、磷酸酯、膦和磷酸酰胺组成的组的成员共存，或将丙烯腈溶液中的水含量降至不超过 0.3%（重量百分比）的水平，并使丙烯腈溶液允许至少一种选自烷基取代的羟基苯、受阻酚、磷酯、磷酸酯、膦和磷酸酰胺的成员共存。
• Acrylonitrile solutions of maleimides
  申请人：NIPPON SHOKUBAI CO., LTD.

  公开号：EP0768300B1

  公开（公告）日：2003-05-07
• PROCESS FOR THE SYNTHESIS OF MALEIMIDE COMPOUND IMPROVED IN STORAGE STABILITY
  申请人：NIPPON SHOKUBAI CO., LTD.

  公开号：EP0627420B1

  公开（公告）日：2007-03-14