N-[4-(diphenylamino)phenyl]-2-methylacrylamide

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N-[4-(diphenylamino)phenyl]-2-methylacrylamide
• 英文别名: N-[(p-diphenylamino)phenyl]methacrylamide；N-[4-(diphenylamino)phenyl]-2-methylprop-2-enamide；2-methyl-N-[4-(N-phenylanilino)phenyl]prop-2-enamide
• 化学式: C₂₂H₂₀N₂O
• 分子量: 328.414
• InChiKey: AEDKRXXDRCLFTB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.3
• 重原子数：
  25
• 可旋转键数：
  5
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.05
• 拓扑面积：
  32.3
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  4-溴三苯胺 在 盐酸 、 (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride 、 三乙胺 、 bis(dibenzylideneacetone)-palladium⁽⁰⁾ 、 sodium t-butanolate 作用下， 以 四氢呋喃 、 二氯甲烷 、 水 、 甲苯 为溶剂， 反应 22.5h， 生成 N-[4-(diphenylamino)phenyl]-2-methylacrylamide
  参考文献：
  名称：

  二氮杂磺酸盐作为具有侧链三芳基胺空穴传导单元的聚合物的交联剂

  摘要：

  二氮杂磺酸盐是容易获得的化合物，其可溶于水和极性溶剂。它们强烈吸收UV-VIS光，并在UV辐射下通过自由基或离子中间体分解。这些特性使其具有很高的价值，例如用于分析目的和用于照片打印。在本演示中，将证明具有重氮磺酸侧酯的聚合物起交联剂的作用，具有芳香胺侧基作为空穴传输剂的聚合物可以被认为是有机发光器件（OLED）技术的有用材料。

  DOI：

  10.1515/chempap-2016-0063

文献信息

• Nitrogen-containing heterocyclic compound
  申请人：——

  公开号：US20030057826A1

  公开（公告）日：2003-03-27

  A nitrogen-containing heterocyclic compound represented by the following formula (I): 1 wherein X 1 and X 2 each represent an electron attractive group such as a cyano group; and the rings Z 1 and Z 2 each represent a hydrocarbon ring or a heterocycle (e.g., benzene ring having an electron donative group such as hydroxyl group, an alkoxy group, amino group and an N-substituted amino group, or a condensed ring being a benzene ring condensed with a heterocycle having a nitrogen atom as a hetero atom) is provided. An organic EL device is obtained by allowing an organic layer containing the compound described-above to be interposed between a pair of electrodes. The present invention provides a nitrogen-containing heterocyclic compound useful as a functional material and a process for producing the same, and an organic EL device using the same.

  提供一种含氮杂环化合物，其化学式如下（I）：其中X1和X2各代表一个电子吸引基团，如氰基；环Z1和Z2各代表一个碳氢环或杂环（例如，苯环具有一个电子给体基团，如羟基、烷氧基、氨基和N-取代氨基，或者是一个与氮原子作为杂原子的杂环缩合环的苯环）。通过在一对电极之间插入含有上述化合物的有机层，可以获得有机EL器件。本发明提供了一种作为功能材料有用的含氮杂环化合物，以及制备该化合物的方法和使用该化合物的有机EL器件。
• Azepine compounds
  申请人：——

  公开号：US20020091256A1

  公开（公告）日：2002-07-11

  The azepine compound capable of emitting a light by light-irradiation or action of an electric field is represented by the following formula (I) or (II): 1 wherein X 1 and X 2 are the same or different, each representing an electron attractive group; R 1 represents a hydrogen atom, an alkyl group, an aryl group, an aralkyl group, or an alkoxy group; R 2 represents an amino group or an N-substituted amino group, or, in the formula (I), R 2 bonds a carbon atom adjacent to a ring Z to form a ring; and the ring Z represents a hydrocarbon ring which may have a substituent or a heterocycle which may have a substituent. The compound is useful as a functional material, thus, an organic electroluminescence device can be obtained by interposing an organic layer composed of the above compound between a pair of electrodes.

  具有通过光照射或电场作用而发出光的氮杂环化合物的化学式如下（I）或（II）：1其中，X1和X2相同或不同，分别表示电子吸引基团；R1表示氢原子、烷基、芳基、芳基烷基或烷氧基；R2表示氨基或N-取代氨基，或在式（I）中，R2与环Z相邻的碳原子连接以形成环；环Z表示可能具有取代基的碳氢环或可能具有取代基的杂环。该化合物可用作功能材料，因此，在一对电极之间插入由上述化合物组成的有机层可获得有机电致发光器件。
• Material for organic electroluminescence device and process for producing the same
  申请人：Daicel Chemical Industries, Ltd.

  公开号：EP1107331A2

  公开（公告）日：2001-06-13

  An organic electroluminescence material is produced by bringing a source (1) containing at least an emission center-forming compound absorptive of a laser beam and defined in the predetermined pattern into contact with targets (2a, 2b) which is transmittable of the laser beam and has at least one function selected from an electron-transporting function and a hole-transporting function, and irradiating with the laser beam from the target (2) side to implant the emission center-forming compound (3) contained in the source (1) into the target (2a). The organic electroluminescence device thus obtained has emission centers in the area corresponding to the pattern of the source. The source may be constituted solely of the emission center-forming compound. The present invention provides an organic EL material susceptible of fine patterning, a process for producing the same, and an organic EL device using the same.

  生产有机电致发光材料的方法是：将至少含有可吸收激光束并以预定图案确定的发射中心形成化合物的光源（1）与可透过激光束并具有至少一种从电子传输功能和空穴传输功能中选择的功能的靶材（2a、2b）接触，并用激光束从靶材（2）一侧照射，将光源（1）中所含的发射中心形成化合物（3）植入靶材（2a）中。这样得到的有机电致发光装置在与光源图案相对应的区域内具有发射中心。光源可以完全由形成发射中心的化合物构成。本发明提供了一种可精细图案化的有机电致发光材料、一种生产该材料的工艺以及一种使用该材料的有机电致发光器件。
• MATERIAL FOR ORGANIC ELECTROLUMINESCENCE DEVICE AND ITS MANUFACTURING METHOD
  申请人：Daicel Chemical Industries, Ltd.

  公开号：EP1347670A1

  公开（公告）日：2003-09-24

  A process for producing for a material for an organic electroluminescent device having an emission center comprises irradiating a laser beam to implant an emission center-forming compound 3 constituting a source 1 into a target 2 having at least one function selected from an electron-transporting function and a hole-transporting function. According to the process, the laser beam and at least the target are relatively moved with irradiating the beam to form the emission center with a predetermined pattern. Moreover, the source and the target being in contact with each other may be moved relative to the laser beam for forming the emission center with a predetermined pattern. Further, the emission center at an area, corresponding to an interference pattern of an interference light, of the target may be formed by irradiating the interference light of the laser beam.

  一种用于生产具有发射中心的有机电致发光器件材料的工艺，包括照射一束激光，将构成光源1的发射中心形成化合物3植入具有至少一种从电子传输功能和空穴传输功能中选择的功能的靶2中。根据该工艺，激光束和至少靶标在照射激光束时相对移动，以形成具有预定图案的发射中心。此外，相互接触的光源和目标可以相对于激光束移动，以形成具有预定图案的发射中心。此外，还可以通过照射激光束的干涉光，在目标的干涉光干涉图案对应的区域形成发射中心。
• Vinyl polymer and organic electroluminescent device
  申请人：——

  公开号：US20030164678A1

  公开（公告）日：2003-09-04

  An organic electroluminescent device comprises an organic layer between a pair of electrodes. The organic layer (in particular, a hole-transporting layer) comprises a polymer of a vinyl compound represented by the following formula (1): 1 wherein R 1 and R 2 are the same or different, each representing a hydrogen atom, a halogen atom, an alkyl group or an alkoxy group. The glass transition temperature of the polymer is about 200 to 250° C., and the polymer has high heat-resistance. Thus, the use of the polymer improves heat resistance of an organic EL device.