4-terphenoyl benzoic acid

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4-terphenoyl benzoic acid
• 英文别名: 2-[4-(4-Phenylphenyl)benzoyl]benzoic acid
• 化学式: C₂₆H₁₈O₃
• 分子量: 378.427
• InChiKey: ALLWOLNUPRYZFT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.6
• 重原子数：
  29
• 可旋转键数：
  5
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  54.4
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  4-terphenoyl benzoic acid 在 氯化亚砜 作用下， 生成 3-chloro-3-[4-(4-phenylphenyl)phenyl]-2-benzofuran-1-one
  参考文献：
  名称：

  聚亚苯基系列的旋转异构体（R *，S *）-和（R *，R *）-联芳基-3,3'-二邻苯二甲酸酯

  摘要：

  合成了具有聚亚苯基系列的芳族（杂芳族）取代基（包括被卤素取代）的联芳-3,3'-邻苯二甲酸酯的各种非对映异构体对。通过X射线分析，HPLC，IR-，1H和13C NMR光谱法对所有这些物质进行分离和表征。已确定，首先由两个相邻的强极性邻苯二甲酸酯基团的立体电子效应确定联芳基3,3'-二邻苯二甲酸酯非对映异构体的溶解度，吸附趋势及其保留时间，等效氢和碳原子的化学位移。 。结果表明，无论是在结晶相中还是在溶液中，所有的二邻苯二甲酸酯，无论其取代基的化学结构如何，均以具有顺式或间平面（手性形式）的稳定的旋转异构体存在。反或反平面（介观形式）构象。

  DOI：

  10.1016/j.tet.2019.01.043
• 作为产物：
  描述：

  苯酐 、 对三联苯 在 aluminum (III) chloride 作用下， 生成 4-terphenoyl benzoic acid
  参考文献：
  名称：

  聚亚苯基系列的旋转异构体（R *，S *）-和（R *，R *）-联芳基-3,3'-二邻苯二甲酸酯

  摘要：

  合成了具有聚亚苯基系列的芳族（杂芳族）取代基（包括被卤素取代）的联芳-3,3'-邻苯二甲酸酯的各种非对映异构体对。通过X射线分析，HPLC，IR-，1H和13C NMR光谱法对所有这些物质进行分离和表征。已确定，首先由两个相邻的强极性邻苯二甲酸酯基团的立体电子效应确定联芳基3,3'-二邻苯二甲酸酯非对映异构体的溶解度，吸附趋势及其保留时间，等效氢和碳原子的化学位移。 。结果表明，无论是在结晶相中还是在溶液中，所有的二邻苯二甲酸酯，无论其取代基的化学结构如何，均以具有顺式或间平面（手性形式）的稳定的旋转异构体存在。反或反平面（介观形式）构象。

  DOI：

  10.1016/j.tet.2019.01.043

文献信息

• [EN] LIQUID ARYLBENZOYL BENZOIC ACID ESTER DERIVATIVES FOR ENERGY CURABLE COMPOSITIONS<br/>[FR] DÉRIVÉS LIQUIDES D'ESTERS D'ACIDE ARYLBENZOYLBENZOÏQUE POUR COMPOSITIONS DURCISSABLES PAR FAISCEAU D'ÉNERGIE
  申请人：SUN CHEMICAL CORP

  公开号：WO2015164205A1

  公开（公告）日：2015-10-29

  4-Arylbenzoyl benzoic acid esters, such as the ethylhexyl esters and amyl esters of 4-phenylbenzoyl benzoic acid, are described, which are liquid and show excellent solubility in acrylic or methacrylic monomers. Compounds of Formula (1), wherein R1, R2, and A are as defined herein, are disclosed. They are suitable as components for radical photoinitiator systems for UV-curable compositions.

  描述了4-芳基苯甲酰苯甲酸酯，例如4-苯基苯甲酰苯甲酸的乙基己酯和戊酯，这些化合物是液体的，在丙烯酸或甲基丙烯酸单体中显示出优异的溶解性。公开了式（1）的化合物，其中R1、R2和A的定义如本文所述。它们适用于UV固化组合物的自由基光引发剂系统的组分。
• ZOLOTUXIN, M. G.;SEDOVA, EH. A.;SALAZKIN, S. I.;RAFIKOV, S. R., VINITI, 6009-83
  作者：ZOLOTUXIN, M. G.、SEDOVA, EH. A.、SALAZKIN, S. I.、RAFIKOV, S. R.

  DOI：——

  日期：——
• LIGHT EMITTING DEVICE AND FLUORESCENT MATERIAL
  申请人：Murayama Tetsuo

  公开号：US20070085057A1

  公开（公告）日：2007-04-19

  The present invention is to provide a light emitting device which can generate high-intensity light emission, using a fluorescent material containing a rare earth element ion complex and being excellent in durability and also provide the fluorescent material to be used therein. The present invention relates to a light emitting device comprising a semiconductor light emitting element which emits light within the region from near-ultraviolet light to visible light, and a fluorescent material which contains a rare earth element ion complex having an aromatic ring-containing Bronsted acid ion with a pKa value of 7 or less as a ligand and emits light by the action of light of the semiconductor light emitting element.
• LIQUID ARYLBENZOYL BENZOIC ACID ESTER DERIVATIVES FOR ENERGY CURABLE COMPOSITIONS
  申请人：SUN CHEMICAL CORPORATION

  公开号：US20170029360A1

  公开（公告）日：2017-02-02

  4-Arylbenzoyl benzoic acid esters, such as the ethylhexyl esters and amyl esters of 4-phenylbenzoyl benzoic acid, are described, which are liquid and show excellent solubility in acrylic or methacrylic monomers. Compounds of Formula 1, wherein R 1 , R 2 , and A are as defined herein, are disclosed. They are suitable as components for radical photoinitiator systems for UV-curable compositions.
• SURFACE-MODIFIED INORGANIC NITRIDE, COMPOSITION, THERMALLY CONDUCTIVE MATERIAL, AND DEVICE WITH THERMALLY CONDUCTIVE LAYER
  申请人：FUJIFILM Corporation

  公开号：US20200148538A1

  公开（公告）日：2020-05-14

  A first object of the present invention is to provide a surface-modified inorganic nitride having excellent dispersibility. Furthermore, a second object of the present invention is to provide a composition, a thermally conductive material, and a device with a thermally conductive layer which contain the surface-modified inorganic nitride. The surface-modified inorganic nitride of the present invention includes an inorganic nitride, and a compound which is represented by General Formula (I) and is adsorbed onto a surface of the inorganic nitride. In General Formula (1), n represents an integer of 3 or greater. X represents an aromatic hydrocarbon ring group or an aromatic heterocyclic group. Y represents a single bond, —O—, —CO—, —CO—O—, —O—CO—, —S—, —CS—, —NR A —, —N═N—, or a divalent unsaturated hydrocarbon group. R A represents a hydrogen atom or an alkyl group. R 1 and R 2 each independently represent a substituent. Here, at least one of R 1 or R 2 represents a monovalent organic group containing a specific functional group selected from the group A of specific functional groups. In General Formula (1), a plurality of X's may be the same as or different from each other. Moreover, a plurality of Y's may be the same as or different from each other.