1-<<1-(2-Nitro-4,5-dimethoxyphenyl)ethoxy>carbonyl>-2,2,6,6-tetramethylpiperidine

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1-<<1-(2-Nitro-4,5-dimethoxyphenyl)ethoxy>carbonyl>-2,2,6,6-tetramethylpiperidine
• 英文别名: 1-(4,5-Dimethoxy-2-nitrophenyl)ethyl 2,2,6,6-tetramethylpiperidine-1-carboxylate
• 化学式: C₂₀H₃₀N₂O₆
• 分子量: 394.468
• InChiKey: ALQCYQDODOMKNZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.9
• 重原子数：
  28
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.65
• 拓扑面积：
  93.8
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  2,2,6,6-四甲基哌啶 在 4-二甲氨基吡啶 、 三乙胺 作用下， 以 1,4-二氧六环 、 甲苯 为溶剂， 生成 1-<<1-(2-Nitro-4,5-dimethoxyphenyl)ethoxy>carbonyl>-2,2,6,6-tetramethylpiperidine
  参考文献：
  名称：

  Photosensitive Tetramethylpiperidine Urethanes: Synthesis and Characterization

  摘要：

  The problem of synthesizing photosensitive urethanes of the highly sterically hindered 2,2,6,6-tetramethylpiperidine is solved by first preparing the 1-chlorocarbonyl derivative which was shown to react with a series of o-nitrobenzylic alcohols, including 2,8-dinitrobenzyl alcohol. These products are potential photogenerators of this amine. Full characterization is reported, along with a crystal structure.

  DOI：

  10.1021/jo00091a012

文献信息

• Photosensitive Tetramethylpiperidine Urethanes: Synthesis and Characterization
  作者：Stefano Martina、Scott A. MacDonald、Volker Enkelmann

  DOI：10.1021/jo00091a012

  日期：1994.6

  The problem of synthesizing photosensitive urethanes of the highly sterically hindered 2,2,6,6-tetramethylpiperidine is solved by first preparing the 1-chlorocarbonyl derivative which was shown to react with a series of o-nitrobenzylic alcohols, including 2,8-dinitrobenzyl alcohol. These products are potential photogenerators of this amine. Full characterization is reported, along with a crystal structure.