N-(1-(4-bromophenyl)ethyl)maleimide

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N-(1-(4-bromophenyl)ethyl)maleimide
• 英文别名: 1-[1-(4-Bromophenyl)ethyl]pyrrole-2,5-dione
• 化学式: C₁₂H₁₀BrNO₂
• mdl: MFCD14649138
• 分子量: 280.121
• InChiKey: AMBFXLXWCCQZDR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.1
• 重原子数：
  16
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.166
• 拓扑面积：
  37.4
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  N-(1-(4-bromophenyl)ethyl)maleimide 在 tris(dibenzylideneacetone)dipalladium(0) chloroform complex 、 甲酸 、 三氟甲磺酸三甲基硅酯 、 三乙胺 、 三(邻甲基苯基)磷 作用下， 以 乙醚 、 N,N-二甲基甲酰胺 为溶剂， 反应 7.41h， 生成 N-(1-(4-(2,5-bicyclo[2.2.1]heptenyl)phenyl)ethyl)maleimide
  参考文献：
  名称：

  Mechanochromic luminescent material, mechanochromic resin obtained by crosslinking mechanochromic luminescent material, method for producing mechanochromic luminescent material, and method for producing mechanochromic

  摘要：

  提供一种机械致变色树脂，可实时可视化材料受到的应力，以及用于合成机械致变色树脂的机械致发光材料。通过公式（1）或公式（2）所表示的机械致发光材料和交联该机械致发光材料所得到的机械致变色树脂，可以实时可视化应力。【化学式1】（在公式中，Y1和Y2分别表示抑制公式（1）所表示的机械致发光材料聚集的取代基，Y1和Y2可以相同也可以不同。Z1和Z2分别表示可聚合基团，可以相同也可以不同。）【化学式2】（在公式中，Y1和Y2分别表示抑制公式（2）所表示的机械致发光材料聚集的取代基，Y1和Y2可以相同也可以不同。Z1和Z2分别表示可聚合基团，可以相同也可以不同。）

  公开号：

  US10442886B2
• 作为产物：
  描述：

  马来酸酐 、 4-溴-α-甲基苄胺 在 sodium acetate 、 乙酸酐 作用下， 以 乙醚 为溶剂， 反应 6.0h， 以79%的产率得到N-(1-(4-bromophenyl)ethyl)maleimide
  参考文献：
  名称：

  Mechanochromic luminescent material, mechanochromic resin obtained by crosslinking mechanochromic luminescent material, method for producing mechanochromic luminescent material, and method for producing mechanochromic

  摘要：

  提供一种机械致变色树脂，可实时可视化材料受到的应力，以及用于合成机械致变色树脂的机械致发光材料。通过公式（1）或公式（2）所表示的机械致发光材料和交联该机械致发光材料所得到的机械致变色树脂，可以实时可视化应力。【化学式1】（在公式中，Y1和Y2分别表示抑制公式（1）所表示的机械致发光材料聚集的取代基，Y1和Y2可以相同也可以不同。Z1和Z2分别表示可聚合基团，可以相同也可以不同。）【化学式2】（在公式中，Y1和Y2分别表示抑制公式（2）所表示的机械致发光材料聚集的取代基，Y1和Y2可以相同也可以不同。Z1和Z2分别表示可聚合基团，可以相同也可以不同。）

  公开号：

  US10442886B2

文献信息

• MECHANOCHROMIC LUMINESCENT MATERIAL, MECHANOCHROMIC RESIN OBTAINED BY CROSSLINKING MECHANOCHROMIC LUMINESCENT MATERIAL, METHOD FOR PRODUCING MECHANOCHROMIC LUMINESCENT MATERIAL, AND METHOD FOR PRODUCING MECHANOCHROMIC RESIN
  申请人：Japan Science and Technology Agency

  公开号：EP3222694A1

  公开（公告）日：2017-09-27

  Provided is a mechanochromic resin by which a stress applied to a material can be visualized in real time, and a mechanochromic luminescent material that is used in the synthesis of the mechanochromic resin. Stress can be visualized in real time by means of a mechanochromic luminescent material represented by formula (1) or formula (2) and a mechanochromic resin obtained by crosslinking the mechanochromic luminescent material. [Chemical formula 1] (In the formula, Y1 and Y2 each denote a substituent group that inhibits aggregation of the mechanochromic luminescent material represented by formula (1), and Y1 and Y2 may be same as or different from each other. Z1 and Z2 each denote a polymerizable group, and may be same as or different from each other.) [Chemical formula 2] (In the formula, Y1 and Y2 each denote a substituent group that inhibits aggregation of the mechanochromic luminescent material represented by formula (2), and Y1 and Y2 may be same as or different from each other. Z1 and Z2 each denote a polymerizable group, and may be same as or different from each other.)

  本发明提供了一种可实时显示施加在材料上的应力的机致变色树脂，以及一种用于合成该机致变色树脂的机致变色发光材料。通过由式（1）或式（2）表示的机械变色发光材料和通过交联该机械变色发光材料获得的机械变色树脂，可实时显示应力。[化学式 1]（式中，Y1 和 Y2 分别表示抑制由式（1）代表的机械致色发光材料聚集的取代基，Y1 和 Y2 可以相同或不同。Z1 和 Z2 分别表示一个可聚合基团，可以相同或不同)。[化学式 2]（式中，Y1 和 Y2 分别表示可抑制由式（2）表示的机械致色发光材料聚集的取代基，且 Y1 和 Y2 可以相同或不同。Z1 和 Z2 分别表示可聚合基团，两者可以相同或不同)。
• MECHANOCHROMIC LUMINESCENT MATERIAL, MECHANOCHROMIC RESIN OBTAINED BY CROSSLINKING MECHANOCHROMIC LUMINESCENT MATERIAL, METHOD FOR PRODUCING MECHANOCHROMIC LUMINESCENT MATERIAL, AND METHOD FOR PRODUCING MECHANOCHROMIC
  申请人：JAPAN SCIENCE AND TECHNOLOGY AGENCY

  公开号：US20190031820A1

  公开（公告）日：2019-01-31

  Provided is a mechanochromic resin by which a stress applied to a material can be visualized in real time, and a mechanochromic luminescent material that is used in the synthesis of the mechanochromic resin. Stress can be visualized in real time by means of a mechanochromic luminescent material represented by formula (1) or formula (2) and a mechanochromic resin obtained by crosslinking the mechanochromic luminescent material. [Chemical formula 1] (In the formula, Y 1 and Y 2 each denote a substituent group that inhibits aggregation of the mechanochromic luminescent material represented by formula (1), and Y 1 and Y 2 may be same as or different from each other. Z 1 and Z 2 each denote a polymerizable group, and may be same as or different from each other.) [Chemical formula 2] (In the formula, Y 1 and Y 2 each denote a substituent group that inhibits aggregation of the mechanochromic luminescent material represented by formula (2), and Y 1 and Y 2 may be same as or different from each other. Z 1 and Z 2 each denote a polymerizable group, and may be same as or different from each other.)
• Mechanochromic luminescent material, mechanochromic resin obtained by crosslinking mechanochromic luminescent material, method for producing mechanochromic luminescent material, and method for producing mechanochromic
  申请人：JAPAN SCIENCE AND TECHNOLOGY AGENCY

  公开号：US10442886B2

  公开（公告）日：2019-10-15

  Provided is a mechanochromic resin by which a stress applied to a material can be visualized in real time, and a mechanochromic luminescent material that is used in the synthesis of the mechanochromic resin. Stress can be visualized in real time by means of a mechanochromic luminescent material represented by formula (1) or formula (2) and a mechanochromic resin obtained by crosslinking the mechanochromic luminescent material. [Chemical formula 1] (In the formula, Y1 and Y2 each denote a substituent group that inhibits aggregation of the mechanochromic luminescent material represented by formula (1), and Y1 and Y2 may be same as or different from each other. Z1 and Z2 each denote a polymerizable group, and may be same as or different from each other.) [Chemical formula 2] (In the formula, Y1 and Y2 each denote a substituent group that inhibits aggregation of the mechanochromic luminescent material represented by formula (2), and Y1 and Y2 may be same as or different from each other. Z1 and Z2 each denote a polymerizable group, and may be same as or different from each other).

  提供一种机械致变色树脂，可实时可视化材料受到的应力，以及用于合成机械致变色树脂的机械致发光材料。通过公式（1）或公式（2）所表示的机械致发光材料和交联该机械致发光材料所得到的机械致变色树脂，可以实时可视化应力。【化学式1】（在公式中，Y1和Y2分别表示抑制公式（1）所表示的机械致发光材料聚集的取代基，Y1和Y2可以相同也可以不同。Z1和Z2分别表示可聚合基团，可以相同也可以不同。）【化学式2】（在公式中，Y1和Y2分别表示抑制公式（2）所表示的机械致发光材料聚集的取代基，Y1和Y2可以相同也可以不同。Z1和Z2分别表示可聚合基团，可以相同也可以不同。）