salicylidene anthanilic acid(-2H)(2-)

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: salicylidene anthanilic acid(-2H)(2-)
• 英文别名: 2-[(2-oxidophenyl)methylideneamino]benzoate
• 化学式: C₁₄H₉NO₃
• 分子量: 239.23
• InChiKey: AMNAGEKFWSNOTE-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  0.87
• 重原子数：
  18.0
• 可旋转键数：
  3.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  75.55
• 氢给体数：
  0.0
• 氢受体数：
  4.0

反应信息

• 作为反应物：
  描述：

  salicylidene anthanilic acid(-2H)(2-) 在 H₂O₂ 、 pyridine 作用下， 以 甲醇 、 丙酮 、 乙腈 为溶剂， 生成
  参考文献：
  名称：

  Novel peroxo complexes of thorium containing organic ligands

  摘要：

  DOI：

  10.1021/ic00138a059

文献信息

• Synthesis, structure and properties of ternary copper(II) complexes of ONO donor Schiff base, imidazole, 2,2′-bipyridine and 1,10-phenanthroline
  作者：R.N. Patel、Nripendra Singh、V.L.N. Gundla

  DOI：10.1016/j.poly.2006.06.017

  日期：2006.12

  Reaction of copper(II) salt with salicylidene anthanilic acid (SAA), a tridentate ligand and imidazole (ImH), a monodentate ligand or bidentate polypyridyl ligands like 2,2'-bipyridine (bipy) or 1,10-phenanthroline(phen) in MeOH:MeCN (1:1 V/V) yields [Cu(SAA)(ImH)] (1), [Cu(SAA)(bipy)]CH3CN (2) and [Cu(SAA)(phen)] (3) in similar to 80% yield. These complexes were characterized by elemental analysis, magnetic susceptibility, X-band e.p.r., electronic spectroscopy and cyclic voltammetry. All the reported complexes show g(parallel to) > g(perpendicular to) > 2.0023 and G values falling within the range of 2-4 are consistent with a d(x2-y2) ground state in a square planar or square pyramidal geometry. Single crystal X-ray analysis of 1 has revealed the presence of a distorted square planar geometry (N2O2) and 2 has revealed the presence of distorted square pyramidal (4 + 1) geometry. In both structures the ONO Schiff base occupies the basal plane. Magnetic susceptibility measurements at room temperature were in the range 1.79 +/- 0.01 BM. Superoxide dismutase (SOD) activity of the present complexes were also measured. (c) 2006 Elsevier Ltd. All rights reserved.
• Novel peroxo complexes of thorium containing organic ligands
  作者：Alan D. Westland、M. T. H. Tarafder

  DOI：10.1021/ic00138a059

  日期：1982.8