三氟乙酸锶 | 60884-91-5

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 中文名称: 三氟乙酸锶
• 英文名称: stroncium trifluoroacetate
• 英文别名: strontium trifluoroacetate；trifluoro-acetic acid ; strontium trifluoroacetate；Trifluor-essigsaeure; Strontium-trifluoracetat
• CAS: 60884-91-5
• 化学式: 2C₂F₃O₂*Sr
• 分子量: 313.652
• InChiKey: WDNPUVJIPIDLNP-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  -1.08
• 重原子数：
  8.0
• 可旋转键数：
  0.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  40.13
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为反应物：
  描述：

  三氟乙酸锶 在 benzylamine 、 ethylamine 作用下， 以 further solvent(s) 为溶剂， 生成 strontium fluoride
  参考文献：
  名称：

  SrF2 hierarchical flowerlike structures: Solvothermal synthesis, formation mechanism, and optical properties

  摘要：

  We present a solvothermal route to the synthesis of SrF2 hierarchical flowerlike structures based on thermal decomposition of single source precursor (SSP) of strontium trifluoroacetate in benzylamine solvent. These flowerlike superstructures are actually composed of numerous aggregated nanoplates, and the growth process involves the initial formation of spherical nanoparticles and subsequent transformation into nanoplates. which aggregated together to form microdisks and finally flowerlike superstructures. The results demonstrate the important role of benzylamine in the formation of well-defined SrF2 superstructures, not only providing size and shape control to form nanoplates but also contributing to the self-assembly behavior of nanoplates to build into flower-like superstructures. Additionally, the photoluminescence properties of the obtained SrF2 superstructures are studied. (C) 2008 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.materresbull.2008.11.011
• 作为产物：
  描述：

  strontium(II) carbonate 、 三氟乙酸 生成 三氟乙酸锶
  参考文献：
  名称：

  金属氟化物纳米晶体诱导的脱甲硅烷基化使体内裂解化学成为可能

  摘要：

  金属氟化物纳米晶体由于其独特的物理化学性质而被广泛用于生物医学研究。由于溶解度平衡，金属离子和氟化物从纳米晶体的释放是固有的。它曾经被认为是一个缺点，因为它与金属氟化物纳米晶体的分解和功能有关。已经开发了许多策略来稳定纳米晶体，氟化物的平衡浓度通常 <1 mM。在这里，我们充分利用了这种最少量的氟化物，并揭示了金属氟化物纳米晶体可以有效地诱导脱甲硅烷基裂解化学，从而能够在试管、活细胞和荷瘤小鼠中控制释放荧光团和药物分子。生物相容性 PEG（聚乙二醇）涂层 CaF 2已经制备了纳米晶体来测定脱甲硅烷化诱导的功能分子受控释放的效率。我们将该策略应用于单甲基 auristatin E (MMAE) 的前药激活，显示出显着的抗癌作用，而副作用几乎可以忽略不计。总之，这种去甲硅烷基化诱导的裂解化学利用了赋予金属氟化物纳米晶体新的扰动或激活功能以用于进一步生物应用的缺点。

  DOI：

  10.1021/jacs.0c10399

文献信息

• Breeze, Steven R.; Wang, Suning; Thompson, Laurence K., Inorganica Chimica Acta, 1996, vol. 250, # 1-2 PART I, p. 163 - 171
  作者：Breeze, Steven R.、Wang, Suning、Thompson, Laurence K.

  DOI：——

  日期：——
• Open-Framework Structures of Anhydrous Sr(CF₃COO)₂ and Ba(CF₃COO)₂
  作者：K. Tauni Dissanayake、Laura M. Mendoza、Philip D. Martin、Leopoldo Suescun、Federico A. Rabuffetti

  DOI：10.1021/acs.inorgchem.5b02081

  日期：2016.1.4

  Anhydrous Sr(CF3COO)(2) and Ba(CF3COO)(2) open-framework structures featuring three-dimensional connectivity of metal oxygen polyhedra were crystallized from a mixture of water and CF3COOH. Crystallization was induced via evaporation of the solvent mixture under a dry nitrogen flow. This approach differs from that routinely employed for crystallization of metal trifluoroacetates, which achieves solvent evaporation by heating under air and yields hydrated salts. Thermogravimetric and differential thermal analysis as well as single-crystal and synchrotron powder X-ray diffraction were employed to characterize the alkaline-earth trifluoroacetate products. Neither thermal analysis nor single-crystal X-ray diffraction detected the presence of crystallization water molecules, demonstrating these trifluoroacetates can be obtained in anhydrous form. Single-crystal X-ray diffraction studies showed that Sr(CF3COO)(2) and Ba(CF3COO)(2) are isostructural and crystallize in the rhombohedral R (3) over bar space group. Both compounds belong to the class of organic inorganic extended hybrids and exhibit an open-framework structural motif with three-dimensional connectivity of the metal oxygen polyhedra and one-dimensional channels along the c axis. The channels are decorated with the trifluoromethyl groups of the trifluoroacetate ligands, and their average (minimum) diameters are similar to 3.75 (2.60) and 3.45 (2.25) angstrom for Sr(CF3COO)(2) and Ba(CF3COO)(2), respectively. This size range is comparabld to the kinetic diameter of small molecules such as hydrogen (2.3 angstrom). Chemical substitution of barium for strontium affects not only the diameter of the channels but also the spatial arrangement of the trifluoromethyl groups within the channels and the coordination environment of the metal atoms. The different coordination requirements of the strontium and barium atoms are accommodated through the displacement of one of the two chemically distinct trifluoroacetate ligands relative to the metal center.