4-ethynyl-4'-hexyloxybiphenyl

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4-ethynyl-4'-hexyloxybiphenyl
• 英文别名: 1-Ethynyl-4-(4-hexoxyphenyl)benzene
• 化学式: C₂₀H₂₂O
• 分子量: 278.394
• InChiKey: AOCVTODPZHACTJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.1
• 重原子数：
  21
• 可旋转键数：
  8
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.3
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  4-ethynyl-4'-hexyloxybiphenyl 在 四甲基乙二胺 、 氧气 、 copper(l) chloride 作用下， 以 四氢呋喃 、 丙酮 为溶剂， 以49%的产率得到1,4-bis(4'-hexyloxybiphenyl-4-yl)buta-1,3-diyne
  参考文献：
  名称：

  Synthesis of Liquid Crystal Molecules Based on Bis(biphenyl)diacetylene and Their Liquid Crystallinity

  摘要：

  我们合成了含有双（联苯）二炔介质的 novel 液晶分子，并通过 1H NMR、13C NMR、傅里叶变换红外光谱（FT-IR）和质谱确认了它们的结构。这些化合物在一个广泛的温度范围内形成了热致液晶，并通过光学显微镜和 X 射线测量进行了良好的表征。

  DOI：

  10.1246/cl.2010.513
• 作为产物：
  描述：

  4-羟基-4'-溴联苯 在 bis-triphenylphosphine-palladium(II) chloride 、 copper(l) iodide 、 18-冠醚-6 、 potassium carbonate 、 三乙胺 、 三苯基膦 、 potassium hydroxide 作用下， 以 丙酮 、 甲苯 为溶剂， 反应 34.0h， 生成 4-ethynyl-4'-hexyloxybiphenyl
  参考文献：
  名称：

  Photoluminescent Gold(I) Complex with Biphenyl Acetylene Ligand Showing Stable Nematic Liquid-Crystalline Phase

  摘要：

  A novel liquid-crystalline (LC) gold(I) complex (Biph6) having biphenyl acetylene ligand was designed and synthesized, and its LC behavior and photoluminescence properties were compared with those of a previously reported gold complex (Ph6) with phenyl acetylene ligand. Biph6 exhibited an enantiotropic nematic phase in a temperature range wider than that of Ph6. Ph6 and Biph6 showed intense photoluminescence with different colors in the crystalline phase: blue and yellowish green luminescence, respectively. We demonstrated that the color of luminescence of the gold complexes could be changed by changing the structure of the molecules and molecular aggregates.

  DOI：

  10.1080/15421406.2014.940510

文献信息

• US4528114A
  申请人：——

  公开号：US4528114A

  公开（公告）日：1985-07-09
• Synthesis of Liquid Crystal Molecules Based on Bis(biphenyl)diacetylene and Their Liquid Crystallinity
  作者：Makoto Uchimura、Sungmin Kang、Rohei Ishige、Junji Watanabe、Gen-ichi Konishi

  DOI：10.1246/cl.2010.513

  日期：2010.5.5

  We synthesized novel liquid crystalline molecules that contain a bis(biphenyl)diacetylene mesogen and confirmed their structures by 1H NMR, 13C NMR, and FT-IR spectroscopy and mass spectrometry. These compounds formed thermotropic liquid crystals in a wide temperature region that was well characterized by optical microscopic and X-ray measurements.

  我们合成了含有双（联苯）二炔介质的 novel 液晶分子，并通过 1H NMR、13C NMR、傅里叶变换红外光谱（FT-IR）和质谱确认了它们的结构。这些化合物在一个广泛的温度范围内形成了热致液晶，并通过光学显微镜和 X 射线测量进行了良好的表征。
• Photoluminescent Gold(I) Complex with Biphenyl Acetylene Ligand Showing Stable Nematic Liquid-Crystalline Phase
  作者：Nana Sugimoto、Sho Tamai、Kaori Fujisawa、Osamu Tsutsumi

  DOI：10.1080/15421406.2014.940510

  日期：2014.9.22

  A novel liquid-crystalline (LC) gold(I) complex (Biph6) having biphenyl acetylene ligand was designed and synthesized, and its LC behavior and photoluminescence properties were compared with those of a previously reported gold complex (Ph6) with phenyl acetylene ligand. Biph6 exhibited an enantiotropic nematic phase in a temperature range wider than that of Ph6. Ph6 and Biph6 showed intense photoluminescence with different colors in the crystalline phase: blue and yellowish green luminescence, respectively. We demonstrated that the color of luminescence of the gold complexes could be changed by changing the structure of the molecules and molecular aggregates.