三溴甲基(1+) | 55426-79-4

• 分子结构分类: 有机化合物 - 碳氢化合物衍生物
• 中文名称: 三溴甲基(1+)
• 英文名称: tribromomethyl(1+)
• 英文别名: tribromomethylium；tribromomethane
• CAS: 55426-79-4
• 化学式: CBr₃
• 分子量: 251.723
• InChiKey: DQQLUGDZQNBOAM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.8
• 重原子数：
  4
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  四溴化碳 以 neat (no solvent) 为溶剂， 生成 三溴甲基(1+)
  参考文献：
  名称：

  Franklin, J. L.; Dillard, J. G.; Rosenstock, H. M., Natl. Std. Ref. Data Ser. Natl. Bur. Std. (U. S.) Nr. 26 (1969), S. 1/285

  摘要：

  DOI：

文献信息

• Reactions of H₃O⁺ and H₂O⁺ with Several Fully Halogenated Bromomethanes
  作者：R. D. Thomas、R. A. Kennedy、C. A. Mayhew、P. Watts

  DOI：10.1021/jp9719624

  日期：1997.11.1

  The bimolecular rate coefficients and ion products for the reactions of H3O+ and H2O+ with the bromine-containing molecules CF3Br, CF2Br2, CF2BrCl, CFBr3, CFBr2Cl, and CBrCl3 at 300 K are reported. With the exception of the reactions of H3O+ with CF3Br and CF2BrCl, the rate coefficients are near the collisional values (k approximate to 10(-9) cm(3) molecule(-1) s(-1)). The most efficient exit pathway for the majority of the H3O+ reactions is the formation of a trihalomethyl cation, together with water and a hydrogen halide as the neutral products. In each case, more than one trihalomethyl cation can be formed. The branching ratios are largest for the products resulting from the breaking of a C-F bond. This is attributed to the high bond strength of HF relative to HCl and HBr. Similarly for CBrCl3, the major product cation is CCl2Br+. The H2O+ reactions are found to proceed predominantly via charge transfer. For the reaction of H2O+ with CF3Br there is clear evidence for intimate reaction pathways in which bonds are broken and formed.
• Chemical ionization mass spectrometry of halomethanes with tetramethylsilane as reagent gas
  作者：Oleg S. Chizhov、Valentin I. Kadentsev、Andrei A. Stomakhin

  DOI：10.1002/oms.1210270610

  日期：1992.6

  AbstractChemical ionization mass spectra of halomethanes measured using tetramethylsilane as reagent gas exhibit three major peaks corresponding to [M + SiMe3]+, [M − X]+ and (MeSi)2X+ ions (X = Cl, Br or I). Dihalomethanes CH2X2 form the most stable silylated molecular ions, whereas in the mass spectra of tetrahalomethanes (CX4) these ions have not been detected and the ions CX3+ are the most abundant. Production of bistrimethylsilyl‐halonium ions is the most pronounced process for haloforms (CHX3).
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: C: MVol.D2, 3.3, page 71 - 71
  作者：

  DOI：——

  日期：——
• OLAH, GEORGE A.;HEILIGER, LUDGER;PRAKASH, G. K. SURYA, J. AMER. CHEM. SOC., 111,(1989) N0, C. 8020-8021
  作者：OLAH, GEORGE A.、HEILIGER, LUDGER、PRAKASH, G. K. SURYA

  DOI：——

  日期：——