三缩水甘油基氨基间甲酚 | 110656-67-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 中文名称: 三缩水甘油基氨基间甲酚
• 中文别名: N-[2-甲基-4-(环氧乙烷基甲氧基)苯基]-N-(环氧乙烷基甲基)-2-环氧乙烷甲胺
• 英文名称: 2-Methyl-4-(oxiran-2-ylmethoxy)-N,N-bis(oxiran-2-ylmethyl)aniline
• CAS: 110656-67-2
• 化学式: C₁₆H₂₁NO₄
• 分子量: 291.34
• InChiKey: IWRZKNMUSBNOOD-UHFFFAOYSA-N

物化性质

• 沸点：
  466.3±30.0 °C(Predicted)
• 密度：
  1.274±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.5
• 重原子数：
  21
• 可旋转键数：
  8
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.62
• 拓扑面积：
  50.1
• 氢给体数：
  0
• 氢受体数：
  5

安全信息

• 海关编码：
  2922199090

文献信息

• RESIN COMPOSITION, CURED PRODUCT THEREOF, FIBRE-REINFORCED PLASTIC, AND FIBRE-REINFORCED PLASTIC FLAMEPROOFING METHOD
  申请人：ADEKA CORPORATION

  公开号：US20210163733A1

  公开（公告）日：2021-06-03

  Provided is a resin composition that is capable of producing a cured product having excellent environmental suitability, high strength, and excellent flame retardancy, and that is suitably usable as a matrix resin for fiber-reinforced plastics. A resin composition contains (A) an epoxy resin, (B) a cyanate resin, (C) an aromatic amine curing agent that is liquid at 25° C., and (D) a phosphorus-containing compound represented by formula (1). Preferably, in formula (1), R 1 and R 2 each independently represent an alkyl group or an aryl group, and X and Y are an oxygen atom.

  提供的是一种树脂组成物，能够产生具有优良环境适应性、高强度和优异阻燃性的固化产品，适合用作纤维增强塑料的基体树脂。该树脂组成物包含（A）环氧树脂，（B）氰酸酯树脂，（C）在25℃下为液态的芳香胺固化剂，以及（D）由公式（1）表示的含磷化合物。在公式（1）中，最好是R1和R2各自独立地表示烷基或芳基，而X和Y则是氧原子。
• EPOXY RESIN COMPOSITION, EPOXY RESIN COMPOSITION FOR FIBER-REINFORCED COMPOSITE, AND FIBER-REINFORCED COMPOSITE CONTAINING THE SAME
  申请人：TORAY INDUSTRIES, INC.

  公开号：EP1094087A1

  公开（公告）日：2001-04-25

  An object of the invention is to provide an epoxy resin composition having a low viscosity around a room temperature and excellent reinforcing fiber impregnating properties, thereby to provide a composite material having excellent heat resistance and mechanical properties including compressive strength. According to the present invention there is provided an epoxy resin composition comprising an aromatic epoxy resin having at least di-functionality, an aromatic amine compound and/or an alicyclic amine compound, wherein 5 minutes after the main agent comprising the epoxy resin and the curing agent comprising the aromatic amine compound and/or the alicyclic amine compound are mixed, the composition shows a viscosity at 25°C in the range of from 1 to 1500 mPas, and Tc, tc, and Tg satisyfy the following equation.Tg ≥ Tc + 20 - k x (Tc - 90) k = 0 when 60 ≤ Tc < 90 k = 0.35 when 90 ≤ Tc ≤ 200 Tc: highest temperature (°C) during the curing process (60 ≤ Tc ≤ 200) tc: retention time (min) at the highest temperature (1 ≤ tc ≤ 120) Tg: glass transition temperature of the epoxy resin composition after a lapse of tc (min) at Tc (°C).

  本发明的目的是提供一种环氧树脂组合物，该组合物在室温下具有低粘度和优异的增强纤维浸渍性能，从而提供一种具有优异耐热性和机械性能（包括抗压强度）的复合材料。 根据本发明，提供了一种环氧树脂组合物，该组合物包含至少具有二官能度的芳香族环氧树脂、芳香族胺化合物和/或脂环族胺化合物，其中包含环氧树脂的主剂和包含芳香族胺化合物和/或脂环族胺化合物的固化剂混合 5 分钟后，该组合物在 25°C 时的粘度范围为 1 至 1500 mPas，且 Tc、tc 和 Tg 满足下式。Tg ≥ Tc + 20 - k x (Tc - 90) 当 60 ≤ Tc < 90 时，k = 0 当 90 ≤ Tc ≤ 200 时，k = 0.35 Tc：固化过程中的最高温度（℃）（60 ≤ Tc ≤ 200） tc：最高温度下的停留时间（分钟）（1 ≤ tc ≤ 120） Tg：环氧树脂组合物在 Tc（℃）时经过 tc（分钟）后的玻璃化转变温度。
• COMPOSITION FOR OPTICAL THREE-DIMENSIONAL MODELING AND METHOD FOR PRODUCING THREE-DIMENSIONAL MODEL USING SAME
  申请人：Okamoto Chemical Industry Co., Ltd

  公开号：EP3281964A1

  公开（公告）日：2018-02-14

  An object of the present invention is to provide: a safe, water-soluble composition for optical stereo lithography imposing less environmental burden and enabling cured film layers to adhere to one another in a process of producing a stereo lithographic object, producing a stereo lithographic object having a small warp deformation and excellent mechanical properties; and a method for producing a stereolithographic object using the composition. Specifically, provided is a water-soluble composition for optical stereolithography, containing: 10 to 70% by mass of (A) a water-soluble cationic polymerizable compound which is an ether derivative compound of sorbitol having a glycidyl ether structure: 1 to 30% by mass of (B) a water-soluble radical polymerizable compound having a methacrylic group and/or an acrylic group; 0.1 to 20% by mass of (C) an antimony-free cationic polymerization initiator which is a sulfonium compound or a bis(alkylphenyl)iodonium compound; and 0.1 to 20% by mass of (D) a radical polymerization initiator.

  本发明的目的是提供：一种用于光学立体光刻的安全水溶性组合物，该组合物对环境造成的负担较小，并能使固化膜层在立体光刻物体的生产过程中相互附着，生产出的立体光刻物体具有较小的翘曲变形和优异的机械性能；以及一种使用该组合物生产立体光刻物体的方法。具体而言，本发明提供了一种用于光学立体平版印刷的水溶性组合物，其中含有：10%至 70% （A）水溶性阳离子可聚合化合物，该化合物是具有缩水甘油醚结构的山梨醇的醚衍生物化合物：1-30%（质量百分比）的(B) 具有甲基丙烯酸基和/或丙烯酸基的水溶性自由基可聚合化合物；0.1-20%（质量百分比）的(C) 无锑阳离子聚合引发剂，它是一种锍化合物或双(烷基苯基)碘鎓化合物；以及 0.1-20%（质量百分比）的(D) 自由基聚合引发剂。
• COMPOSITION OPTICAL THREE-DIMENSIONAL MOLDING
  申请人：Okamoto Chemical Industry Co., Ltd

  公开号：EP3418313A1

  公开（公告）日：2018-12-26

  Provided is a composition for optical stereolithography, which is photo-curable within a shorter time, and is excellent in mechanical properties after photo-curing. Specifically, provided is a composition for optical stereolithography containing (A) a cationic polymerizable epoxy resin that is a novolac epoxy resin and/or an epoxy resin having a predetermined structure; (B) a cationic polymerizable compound being other than the component (A) and having a glycidyl ether structure; (C) a radical polymerizable compound having a methacrylic group and/or an acrylic group; (D) a styrene-containing copolymer resin that is a copolymer resin of styrene and predetermined maleic anhydride and/or a copolymer resin of styrene and methacrylic acid or acrylic acid; (E) a cationic polymerization initiator that is a sulfonium compound or a bis(alkylphenyl)iodonium compound; (F) a radical polymerization initiator; and (G) a sensitizer.

  本发明提供了一种用于光学立体光刻的组合物，该组合物可在较短时间内实现光固化，并且在光固化后具有优异的机械性能。具体地说，本发明提供了一种光学立体光刻用组合物，该组合物含有：（A）阳离子可聚合环氧树脂，该环氧树脂为酚醛环氧树脂和/或具有预定结构的环氧树脂；（B）阳离子可聚合化合物，该化合物与组分（A）不同，具有缩水甘油醚结构；（C）自由基可聚合化合物，该化合物具有甲基丙烯酸基和/或丙烯酸基；(D) 含苯乙烯的共聚樹脂，即苯乙烯與預定馬來酸酐的共聚樹脂及/或苯乙烯 與甲基丙烯酸或丙烯酸的共聚樹脂； (E) 陽離子聚合誘發劑，即磺鎓化合物或雙(烷基苯基)碘鎓化合物； (F) 自由基聚合誘發劑；及 (G) 增感劑。
• CURABLE COMPOSITION FOR MECHANICAL FOAMING, AND METHOD FOR MANUFACTURING FOAM OF SAME
  申请人：ThreeBond Co., Ltd.

  公开号：EP3885399A1

  公开（公告）日：2021-09-29

  Provided is a curable composition for mechanical foaming in which bubbles are evenly dispersed and bubbles do not rise to the liquid surface and from which a foam can be favorably formed when the curable composition for mechanical foaming is mechanically foamed. A curable composition for mechanical foaming having a complex viscosity η* that satisfies the following conditions (A) and (B) in frequency dependence measurement by a rheometer, in which the curing form of the curable composition for mechanical foaming is not a moisture curing form: condition (A): η* at 0.1 Hz and 25°C is in a range of 1000 to 50000 Pa·s; and condition (B): η* at 10.0 Hz and 25°C is in a range of 100 to 1000 Pa·s.

  本发明提供了一种用于机械发泡的可固化组合物，在该组合物中气泡分散均匀，且气泡不会上升到液体表面，在对该用于机械发泡的可固化组合物进行机械发泡时，可从该组合物中有利地形成泡沫。 一种机械发泡用可固化组合物，其复合粘度 η* 在流变仪的频率依赖性测量中满足以下条件 (A) 和 (B)，其中机械发泡用可固化组合物的固化形式不是湿气固化形式： 条件 (A)：在 0.1 Hz 和 25°C 时，η* 的范围为 1000 至 50000 Pa-s；以及 条件 (B)：在 10.0 赫兹和 25°C 时，η* 在 100 至 1000 Pa-s 之间。