三苯基硫脲 | 18371-52-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 三苯基硫脲
• 英文名称: triphenylthiourea
• 英文别名: N,N,N'-triphenylthiourea；1,1,3-triphenylthiourea
• CAS: 18371-52-3
• 化学式: C₁₉H₁₆N₂S
• 分子量: 304.415
• InChiKey: OLTJYOMEFRRCKA-UHFFFAOYSA-N

物化性质

• 熔点：
  69-70 °C
• 沸点：
  437.0±28.0 °C(Predicted)
• 密度：
  1.253±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.9
• 重原子数：
  22
• 可旋转键数：
  3
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  47.4
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  2,2-dibromo-1-(4-methoxyphenyl)ethanone 、 三苯基硫脲 以 乙醇 为溶剂， 反应 12.0h， 以55%的产率得到2-[2-(4-Methoxy-phenyl)-2-oxo-ethyl]-1,1,3-triphenyl-isothiourea
  参考文献：
  名称：

  Ahluwalia, V. K.; Mehta, Bhupinder; Kumar, Rakesh, Synthetic Communications, 1989, vol. 19, # 3and4, p. 619 - 626

  摘要：

  DOI：
• 作为产物：
  描述：

  硫代异氰酸苯酯 、 二苯胺 生成 三苯基硫脲
  参考文献：
  名称：

  Gebhardt, Chemische Berichte, 1884, vol. 17, p. 2092

  摘要：

  DOI：

文献信息

• METHODS OF DEGRADING ORGANIC POLLUTANTS AND PREVENTING OR TREATING MICROBE USING Bi2S3-CdS PARTICLES
  申请人：Imam Abdulrahman Bin Faisal University

  公开号：US20200102228A1

  公开（公告）日：2020-04-02

  Methods of synthesizing Bi 2 S 3 —CdS particles in the form of spheres as well as properties of these Bi 2 S 3 —CdS particles are described. Methods of photocatalytic degradation of organic pollutants employing these Bi 2 S 3 —CdS particles and methods of preventing or reducing microbial growth on a surface by applying these Bi 2 S 3 —CdS particles in the form of a solution or an antimicrobial product onto the surface are also specified.

  本文描述了合成球形Bi2S3-CdS颗粒的方法以及这些颗粒的性质。还介绍了利用这些Bi2S3-CdS颗粒进行光催化降解有机污染物的方法，以及通过将这些Bi2S3-CdS颗粒以溶液或抗微生物产品的形式涂布在表面上来防止或减少微生物生长的方法。
• Stabilized lactam polymerization solutions
  申请人：DSM RIM NYLON V.O.F

  公开号：EP0239170A1

  公开（公告）日：1987-09-30

  Unsaturated oligomers and solutions thereof are stabilized with a trisubstituted urea to provide improved storage stability. The stabilized unsaturated oligomer solutions are useful in lactam polymerization processes which yield nylon block copolymers containing unsaturated oligomer segments. The unsaturated oligomers disclosed herein have at least 4 carbons and have pendant thereto at least one hydroxy, amine, epoxy, acyllactam, or acyllactam precursor group.

  使用三取代脲稳定不饱和低聚物及其溶液，可提高储存稳定性。稳定的不饱和低聚物溶液适用于内酰胺聚合工艺，该工艺可产生含有不饱和低聚物段的尼龙嵌段共聚物。本文公开的不饱和低聚物至少有 4 个碳原子，并至少有一个羟基、胺、环氧、酰内酰胺或酰内酰胺前体基团。
• 6-Epithioethyl-3-oxatricyclo (3.2.1.02.4) octane and process for preparation thereof
  申请人：NIPPON OIL CO. LTD.

  公开号：EP0452092A2

  公开（公告）日：1991-10-16

  6-Epithioethyl-3-oxatricyclo [3.2.1.02.4] octane, a novel compound, is prepared by reaction of the corresponding 6-epoxyethyl-3-oxatricyclo [3.2.1.02.4] octane with an ammonium or alkali or alkaline earth metal thiocyanate or a thiourea, and is useful as a monomer for preparation of, e.g., heat resistant plastics and plastics for optical use.

  6-环氧乙基-3-氧杂三环[3.2.1.02.4]辛烷是一种新型化合物，由相应的 6-环氧乙基-3-氧杂三环[3.2.1.02.4]辛烷与铵或碱或碱土金属硫氰酸盐或硫脲反应制备而成，可用作制备耐热塑料和光学塑料等的单体。
• Composition including polyester resin and method of using the same
  申请人：3M INNOVATIVE PROPERTIES COMPANY

  公开号：US10927273B2

  公开（公告）日：2021-02-23

  The composition includes a polymeric resin having at least one α,β-unsaturated ester group, a vinyl aromatic compound having at least one vinyl substituent on an aromatic ring, and an amino- or mercapto-substituted compound represented by formula (HD)1-4-R. Each D is independently —S— or —N(H)— and R is a monovalent alkyl, alkenyl, or polyalkyleneoxy or a multivalent alkylene, alkenylene, or polyalkyleneoxy, wherein the alkyl, alkenyl, alkylene, or alkenylene are each interrupted by at least two —O—, —N(H)—, —N(H)—C(O)—, —S—C(O)—, or —O—C(O)— groups or a combination thereof. A method of repairing a damaged surface using the composition is also described.

  该组合物包括具有至少一个 α、β-不饱和酯基的聚合树脂、在芳香环上具有至少一个乙烯基取代基的乙烯基芳香族化合物，以及由式 (HD)1-4-R 所代表的氨基或巯基取代的化合物。每个 D 独立地是-S-或-N(H)-，R 是一价烷基、烯基或聚亚烷氧基或多价亚烷基、亚烯基或聚亚烷氧基，其中烷基、烯基、亚烷基或亚烷基各自被至少两个-O-、-N(H)-、-N(H)-C(O)-、-S-C(O)-或-O-C(O)-基团或它们的组合间断。此外，还描述了使用该组合物修复受损表面的方法。
• Methods of degrading organic pollutants and preventing or treating microbe using Bi2S3-CdS particles
  申请人：Imam Abdulrahman Bin Faisal University

  公开号：US10934176B2

  公开（公告）日：2021-03-02

  Methods of synthesizing Bi2S3—CdS particles in the form of spheres as well as properties of these Bi2S3—CdS particles are described. Methods of photocatalytic degradation of organic pollutants employing these Bi2S3—CdS particles and methods of preventing or reducing microbial growth on a surface by applying these Bi2S3—CdS particles in the form of a solution or an antimicrobial product onto the surface are also specified.

  描述了合成球状 Bi2S3-CdS 颗粒的方法以及这些 Bi2S3-CdS 颗粒的特性。此外，还说明了利用这些 Bi2S3-CdS 颗粒光催化降解有机污染物的方法，以及通过将这些溶液形式的 Bi2S3-CdS 颗粒或抗菌产品涂抹到表面，防止或减少表面微生物生长的方法。