2-ethoxy-1-hexanol

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: 2-ethoxy-1-hexanol
• 英文别名: 2-ethoxyhexan-1-ol
• 化学式: C₈H₁₈O₂
• mdl: MFCD02093567
• 分子量: 146.23
• InChiKey: BGVCWPVMJIEXBL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.6
• 重原子数：
  10
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  29.5
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  丁基环氧乙烷 、 乙醇 在 resin-bound Fe(III) mono(terpyridine) 作用下， 生成 1-ethoxy-2-hexanol 、 2-ethoxy-1-hexanol
  参考文献：
  名称：

  A novel mononuclear Fe(iii) mono(terpyridine) complex having labile solvent ligands and its catalytic activityElectronic supplementary information (ESI) available: experimental details. See http://www.rsc.org/suppdata/dt/b2/b208413a/

  摘要：

  通过特意选择聚合物表面锚定的萜吡啶作为螯合配体，成功制备了一种新型铁单（萜吡啶）配合物，该配合物在温和的中性条件下，对各种环氧化物与醇和水的开环反应具有极佳的催化活性，且易于重复使用，可得到立体选择性和区域选择性产物。

  DOI：

  10.1039/b208413a

文献信息

• HYDROCRACKING CATALYST, METHOD FOR PRODUCING SAME, AND METHOD FOR PRODUCING HYDROXY COMPOUND USING SAID CATALYST
  申请人：Yoshii Kiyotaka

  公开号：US20140288335A1

  公开（公告）日：2014-09-25

  The present invention provides a hydrocracking catalyst obtainable by mixing a metal compound (A) including any one metal of Groups 3 to 11 of the Periodic Table, a compound (B) including at least one compound selected from the group consisting of a ruthenium oxide compound (B1) and a high-valence compound (B2) including any metal of Groups 8 to 11 of the Periodic Table, and a metal oxide (C) including a metal of Group 5, Group 6 or Group 7 of the Periodic Table, and conducting reduction treatment.

  本发明提供了一种加氢裂化催化剂，该催化剂可通过混合包括周期表3至11族中任一金属的金属化合物（A）、包括至少一种选自含钌氧化物化合物（B1）和包括周期表8至11族中任一金属的高价化合物（B2）的化合物（B）、以及包括周期表5、6或7族中一种金属的金属氧化物（C），并进行还原处理而获得。
• A novel mononuclear Fe(iii) mono(terpyridine) complex having labile solvent ligands and its catalytic activityElectronic supplementary information (ESI) available: experimental details. See http://www.rsc.org/suppdata/dt/b2/b208413a/
  作者：Dong-Woo Yoo、Sang-Kun Yoo、Cheal Kim、Jin-Kyu Lee

  DOI：10.1039/b208413a

  日期：2002.10.29

  A novel Fe mono(terpyridine) complex was successfully prepared by deliberately choosing the polymer surface-anchored terpyridine as a chelating ligand and it showed an excellent catalytic activity with an easy reusability on the ring-opening reaction of various epoxides by alcohol and water under mild and neutral conditions to give stereospecific and regioselective products.

  通过特意选择聚合物表面锚定的萜吡啶作为螯合配体，成功制备了一种新型铁单（萜吡啶）配合物，该配合物在温和的中性条件下，对各种环氧化物与醇和水的开环反应具有极佳的催化活性，且易于重复使用，可得到立体选择性和区域选择性产物。
• METHOD FOR PRODUCING CYCLOPENTYL ALKYL ETHER COMPOUND
  申请人：ZEON CORPORATION

  公开号：US20170217862A1

  公开（公告）日：2017-08-03

  The present invention is a method for producing a cyclopentyl alkyl ether compound comprising reacting substituted or unsubstituted cyclopentene with an alcohol compound represented by a formula (2): R 1 OH in the presence of an acidic zeolite, the cyclopentyl alkyl ether compound being represented by a formula (1): R 1 —O—R 2 , wherein R 1 represents a substituted or unsubstituted alkyl group having 1 to 10 carbon atoms, or a substituted or unsubstituted cycloalkyl group having 3 to 8 carbon atoms, and R 2 represents a substituted or unsubstituted cyclopentyl group. The present invention provides a method that can produce a cyclopentyl alkyl ether with high reaction efficiency through a liquid-phase reaction even when the raw material feed rate (amount) is increased.

  本发明涉及一种制备环戊基烷基醚化合物的方法，包括在酸性沸石的存在下，将取代或未取代的环戊烯与式（2）表示的醇化合物（R1OH）反应，所述环戊基烷基醚化合物由式（1）表示：R1-O-R2，其中R1表示具有1到10个碳原子的取代或未取代的烷基或具有3到8个碳原子的取代或未取代的环烷基，R2表示取代或未取代的环戊基。本发明提供了一种方法，即使原料进料速率（量）增加，也可以通过液相反应高效地生产环戊基烷基醚。
• TRANSPARENT FLUORINE-CONTAINING POLYMER
  申请人：Kubota Toshio

  公开号：US20120148808A1

  公开（公告）日：2012-06-14

  Disclosed is a fluorine-containing polymer obtained by polymerizing a 1,6-diene-type ether compound represented by formula [1] and, for example, a (meth)acrylic acid compound represented by formula [2]. The fluorine-containing polymer shows high transparency, has a high glass transition point, and is soluble in a solvent and therefore has moldability. In the case where a (meth)acrylic unit has a reactive substituent, by utilizing the crosslinking reaction thereof, a thin film having high solvent resistance can be produced. In formulae [1] and [21, R 1 and R 2 each independently represent a hydrogen atom or an alkyl group having 1 to 12 carbon atoms, which may be substituted, R 3 represents a hydrogen atom, a fluorine atom, or a methyl group, and R 4 represents a hydrogen atom, an alkyl group having 1 to 12 carbon atoms, which may be substituted, or an aromatic group having 5 to 10 ring members, which may be substituted.

  本发明公开了一种含氟聚合物，其通过聚合由式[1]表示的1,6-二烯型醚化合物和例如由式[2]表示的（甲基）丙烯酸化合物等制得。该含氟聚合物具有高透明度，具有较高的玻璃转移温度，可溶于溶剂，因此具有成型性。在（甲基）丙烯酸单元具有反应性取代基的情况下，通过利用其交联反应，可以制备具有高溶剂耐受性的薄膜。在式[1]和[2]中，R1和R2分别独立表示氢原子或具有1至12个碳原子的烷基基团，可以被取代，R3表示氢原子、氟原子或甲基基团，R4表示氢原子、具有1至12个碳原子的烷基基团，可以被取代，或具有5至10个环成员的芳香族基团，可以被取代。
• TRIAZINE RING-CONTAINING POLYMER AND COMPOSITION FOR FILM FORMATION COMPRISING SAME
  申请人：NISSAN CHEMICAL INDUSTRIES, LTD.

  公开号：US20140371367A1

  公开（公告）日：2014-12-18

  Provided is a triazine ring-containing hyperbranched polymer comprising the repeating unit structure represented by formula (1) and having one or more triazine ring terminals, said one or more triazine ring terminals being capped with a compound that differs from the diamine compound serving as the starting material for the polymer and has at least two active hydrogen groups. In addition to the polymer itself exhibiting high heat resistance, high transparency, a high refractive index, high light resistance, high solubility, and low volume shrinkage, it is also possible to use the polymer to provide a composition for film formation capable of yielding a thick film having high hardness. (In formula (1), R and R′ each independently represent a hydrogen atom, an alkyl group, an alkoxy group, an aryl group, or an aralkyl group, and Ar represents a divalent organic group containing an aromatic ring and/or a heterocyclic ring.)

  提供的是一种含有三嗪环的超支化聚合物，其重复单元结构由式（1）表示，并具有一个或多个三嗪环端基，其中，所述一个或多个三嗪环端基被与作为聚合物起始材料的二胺化合物不同的化合物封顶，该化合物具有至少两个活性氢基团。除了聚合物本身具有高耐热性、高透明度、高折射率、高耐光性、高溶解性和低体积收缩率之外，还可以使用该聚合物提供用于制备薄膜的组合物，该组合物能够产生具有高硬度的厚膜。（在式（1）中，R和R'各自独立地表示氢原子、烷基、烷氧基、芳基或芳烷基，Ar表示一个含有芳香环和/或杂环的二价有机基团。）