(+/-)-N-[(3R,4S)-4-hydroxytetrahydrofuran-3-yl]-tert-butylsulfonamide

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机磺酸及其衍生物
• 英文名称: (+/-)-N-[(3R,4S)-4-hydroxytetrahydrofuran-3-yl]-tert-butylsulfonamide
• 英文别名: N-[(3R,4S)-4-hydroxyoxolan-3-yl]-2-methylpropane-2-sulfonamide
• 化学式: C₈H₁₇NO₄S
• 分子量: 223.293
• InChiKey: BIIAZXYRHCSZRW-RNFRBKRXSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.6
• 重原子数：
  14
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  84
• 氢给体数：
  2
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  (+/-)-N-[(3R,4S)-4-hydroxytetrahydrofuran-3-yl]-tert-butylsulfonamide 在 吡啶 、 potassium carbonate 作用下， 以 二氯甲烷 、 乙腈 为溶剂， 反应 32.0h， 生成 6-(tert-butylsulfonyl)-3-oxa-6-azabicyclo[3.1.0]hexane
  参考文献：
  名称：

  The output of amplified spontaneous emission lasers

  摘要：

  The output of amplified spontaneous emission (ASE) lasers such as X-ray lasers operated without mirrors is calculated exactly for Gaussian and Lorentzian small signal gain profiles by a simple Taylor series expansion. The accuracy of the 'Linford' formula commonly used as an approximation for the output of ASE lasers is evaluated by comparison to our exact solutions. The Linford formula is accurate to better than 10% for intensities produced by a Gaussian gain profile, but requires multiplication by a correction factor of at gain length product greater than 5 for Lorentzian gain profiles. (c) 2006 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.jqsrt.2006.02.064
• 作为产物：
  描述：

  3,4-环氧四氢呋喃 、 叔丁基磺酰胺 在 苄基三乙基氯化铵 、 potassium carbonate 作用下， 以 1,4-二氧六环 为溶剂， 反应 96.0h， 以95%的产率得到(+/-)-N-[(3R,4S)-4-hydroxytetrahydrofuran-3-yl]-tert-butylsulfonamide
  参考文献：
  名称：

  The output of amplified spontaneous emission lasers

  摘要：

  The output of amplified spontaneous emission (ASE) lasers such as X-ray lasers operated without mirrors is calculated exactly for Gaussian and Lorentzian small signal gain profiles by a simple Taylor series expansion. The accuracy of the 'Linford' formula commonly used as an approximation for the output of ASE lasers is evaluated by comparison to our exact solutions. The Linford formula is accurate to better than 10% for intensities produced by a Gaussian gain profile, but requires multiplication by a correction factor of at gain length product greater than 5 for Lorentzian gain profiles. (c) 2006 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.jqsrt.2006.02.064

文献信息

• The output of amplified spontaneous emission lasers
  作者：H. Huang、G.J. Tallents

  DOI：10.1016/j.jqsrt.2006.02.064

  日期：2006.12

  The output of amplified spontaneous emission (ASE) lasers such as X-ray lasers operated without mirrors is calculated exactly for Gaussian and Lorentzian small signal gain profiles by a simple Taylor series expansion. The accuracy of the 'Linford' formula commonly used as an approximation for the output of ASE lasers is evaluated by comparison to our exact solutions. The Linford formula is accurate to better than 10% for intensities produced by a Gaussian gain profile, but requires multiplication by a correction factor of at gain length product greater than 5 for Lorentzian gain profiles. (c) 2006 Elsevier Ltd. All rights reserved.