copper cupferronate

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: copper cupferronate
• 英文别名: copper cupferrate；Cu(cup)₂；Cu(cup)2
• 化学式: 2C₆H₅N₂O₂*Cu
• 分子量: 337.782
• InChiKey: QYYCJJOGUMPEGX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.67
• 重原子数：
  11.0
• 可旋转键数：
  2.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  55.73
• 氢给体数：
  0.0
• 氢受体数：
  3.0

反应信息

• 作为反应物：
  描述：

  copper cupferronate 以 neat (no solvent) 为溶剂， 生成 铜
  参考文献：
  名称：

  过渡金属氧化物表面活性剂包覆纳米晶体的一种新的非水解单前驱体方法

  摘要：

  制备半导体和金属纳米晶体的新方法的出现，特别是将分子前体注入热有机表面活性剂中，已经产生了显着改进的样品，具有良好的尺寸控制、窄尺寸分布以及单个和可分散纳米晶体的良好结晶度。将这些方法应用于过渡金属氧化物纳米粒子的合成具有相当大的意义，它们通常通过涉及水作为溶剂或反应物的方法制备。作者报告了一种新的非水解单前体方法合成过渡金属氧化物的可分散纳米晶体的初步结果。

  DOI：

  10.1021/ja993280v
• 作为产物：
  描述：

  铜 、 cupferron 以 溶剂黄146 为溶剂， 生成 copper cupferronate
  参考文献：
  名称：

  Biltz, H.; Hoedtke, O., Zeitschrift fur anorganische Chemie, 1910, vol. 68, p. 426 - 431

  摘要：

  DOI：

文献信息

• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Cu: MVol.B4, 156, page 1793 - 1795
  作者：

  DOI：——

  日期：——
• Einfache Bildung von o-Nitrosophenol aus Benzol und Hydroxylamin durch Luftoxydation. Pr�parative Darstellung von o-Nitrosophenol und Nitrosocresol aus Benzol bzw. Toluol durch H2O2 Oxydation
  作者：Oskar Baudisch

  DOI：10.1007/bf01498121

  日期：1939.11
• Solvothermal synthesis of CdO and CuO nanocrystals
  作者：Moumita Ghosh、C.N.R. Rao

  DOI：10.1016/j.cplett.2004.06.092

  日期：2004.8

  Nanocrystals of CdO have been obtained by the decomposition of the cupferron complex in the presence of tri-n-octylphosphine oxide (TOPO) under solvothermal conditions. The precursor:TOPO ratio plays an important role in determining the size of the nanocrystals. The nanocrystals have been characterized by electron microscopy, absorption spectroscopy and fluorescence spectroscopy, besides X-ray diffraction. The CdO nanocrystals are single crystalline and show evidence for quantum confinement. CuO nanocrystals could also be prepared by the decomposition of the cupferronate under solvothermal conditions, the particle size being controlled by the initial precursor concentration. (C) 2004 Elsevier B.V. All rights reserved.
• Ionic liquids-modulated two-phase thermal synthesis of three-dimensional CuS nanostructures
  作者：Kaisheng Yao、Weiwei Lu、Xinying Li、Jianji Wang

  DOI：10.1016/j.jssc.2012.07.023

  日期：2012.12

  A novel method was proposed for successful fabrication of CuS nanostructures with various morphologies. At the ionic liquids (ILs)-modulated CHCl3-H2O interface, copper cupferronate [Cu(cup)(2)] in CHCl3 reacted with thiourea in water to generate CuS nanostructures via a solvothermal reaction process. The effects of alkyl chain length of imidazolium cations and nature of anions of the ILs, molar ratio of Cu(cup)(2) to thiourea, the reaction temperature and time on the morphology of the products were studied systematically. It was shown that by changing alkyl chain length of imidazolium cations and nature of anions of the ILs, CuS nanostructures with various morphologies, including flowers, urchins, large nanodisks and nanoparticles, could be obtained at the liquid-liquid interface, and the ILs played important template roles in directing the formation of CuS nanostructures. Furthermore, the as-prepared CuS samples exhibited high catalytic activity for photodegradation of methyl orange and thermal decomposition of ammonium perchlorate. (C) 2012 Elsevier Inc. All rights reserved.
• Baudisch, O., Chemiker-Zeitung, 1909, vol. 33, p. 1298 - 1300
  作者：Baudisch, O.

  DOI：——

  日期：——