vanadium (II) oxalate * 2 H2O

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: vanadium (II) oxalate * 2 H2O
• 英文别名: vanadium(II) oxalate dihydrate；[V(II)(oxalate)3(OH)2]n；Oxalate;vanadium(2+);hydrate；oxalate;vanadium(2+);hydrate
• 化学式: C₂O₄*2H₂O*V
• 分子量: 174.992
• InChiKey: GLCMVSDQDKQXEK-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  -4.34
• 重原子数：
  8
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  81.3
• 氢给体数：
  1
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  vanadium (II) oxalate * 2 H2O 以 neat (no solvent) 为溶剂， 以1%的产率得到vanadia
  参考文献：
  名称：

  Characterisation and thermal analysis of vanadium(II) oxalate

  摘要：

  The synthesis, compositional formula and mode of thermal decomposition of a compound for which there existed only a single literature reference [1] have been investigated in this work.The product of the aqueous phase reaction between vanadium(II) ions and oxalate ions at low pH has been identified: vanadium(II) oxalate dihydrate, VC2O4 . 2H(2)O, has been characterised by thermal methods of analysis supported by a range of complementary analytical techniques.The findings of a previous author [1] have been confirmed and extended in this work. In addition, a synthetic procedure for the preparation of gram quantities of vanadium(II) oxalate dihydrate, VC2O4 . 2H(2)O, is reported here for the first time.The oxalate compound prepared was found to be remarkably stable in relation to aerial oxidation, unlike other representative solid state compounds of the vanadium(II) oxidation state. Vanadium(II) oxalate dihydrate may, therefore, serve as an important intermediate in the future synthesis of other vanadium(II) compounds.

  DOI：

  10.1007/bf01980762
• 作为产物：
  描述：

  硫酸氧钒水合物 在 Zn 作用下， 以 硫酸 为溶剂， 生成 vanadium (II) oxalate * 2 H2O
  参考文献：
  名称：

  Characterisation and thermal analysis of vanadium(II) oxalate

  摘要：

  The synthesis, compositional formula and mode of thermal decomposition of a compound for which there existed only a single literature reference [1] have been investigated in this work.The product of the aqueous phase reaction between vanadium(II) ions and oxalate ions at low pH has been identified: vanadium(II) oxalate dihydrate, VC2O4 . 2H(2)O, has been characterised by thermal methods of analysis supported by a range of complementary analytical techniques.The findings of a previous author [1] have been confirmed and extended in this work. In addition, a synthetic procedure for the preparation of gram quantities of vanadium(II) oxalate dihydrate, VC2O4 . 2H(2)O, is reported here for the first time.The oxalate compound prepared was found to be remarkably stable in relation to aerial oxidation, unlike other representative solid state compounds of the vanadium(II) oxidation state. Vanadium(II) oxalate dihydrate may, therefore, serve as an important intermediate in the future synthesis of other vanadium(II) compounds.

  DOI：

  10.1007/bf01980762

文献信息

• Synthesis, Structure, and Magnetic Ordering of Layered (2-D) V-Based Tris(oxalato)metalates
  作者：Kil Sik Min、Arnold L. Rhinegold、Joel S. Miller

  DOI：10.1021/ic051373+

  日期：2005.11.1

  indicating an S = 1 ground state. 2 exhibits intralayer ferromagnetic coupling below 20 K, but does not magnetically order above 2 K, and 3 shows a strong antiferromagnetic interaction between V(II), S = 3/2 and Cr(III), S = 3/2 ions (theta = -116 K) within the 2-D layers. 4 and 4a magnetically order as ferrimagnets at T(c)'s, taken as the onset of magnetization, of 11 and 30 K, respectively. The 2 K

  K 3 [M（III）（ox）3] .3H 2 O的反应[M ＝ V（1），Cr； [M + H] +。ox =草酸盐]，Mn（II）/ V（II）和[N（n-Bu）4] Br在水中导致分离出基于2-D V的配位聚合物[[N（n-Bu） 4] [Mn（II）V（III）（ox）3]] n（2），[[N（n-Bu）4] [V（II）Cr（III）（ox）3]] n（3 ），[[N（n-Bu）4] [V（II）V（III）（ox）3]] n（4）和形成4的中间体，[[N（n-Bu）4 ] [V（II）V（III）（ox）3（H2O）2]] n.2.5H2O（4a），而一维[V（II）（ox）（H2O）2] n（5）为通过在水中使用Na2ox和[V（OH2）6] SO4获得。1-5的结构已经通过单晶和/或粉末X射线晶体学研究。在1中，V（III）与三个草酸盐双阴离子配位，近似为D3对称的，扭曲的八面体八面体。1是顺磁性的[在300
• Seifert, H.-J.; Gerstenberg, B., Zeitschrift fur Anorganische und Allgemeine Chemie
  作者：Seifert, H.-J.、Gerstenberg, B.

  DOI：——

  日期：——
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: V: MVol.B1, 134, page 348 - 350
  作者：

  DOI：——

  日期：——
• Characterisation and thermal analysis of vanadium(II) oxalate
  作者：A. K. Davies、J. V. Gilligan、S. A. Jones

  DOI：10.1007/bf01980762

  日期：1996.6

  The synthesis, compositional formula and mode of thermal decomposition of a compound for which there existed only a single literature reference [1] have been investigated in this work.The product of the aqueous phase reaction between vanadium(II) ions and oxalate ions at low pH has been identified: vanadium(II) oxalate dihydrate, VC2O4 . 2H(2)O, has been characterised by thermal methods of analysis supported by a range of complementary analytical techniques.The findings of a previous author [1] have been confirmed and extended in this work. In addition, a synthetic procedure for the preparation of gram quantities of vanadium(II) oxalate dihydrate, VC2O4 . 2H(2)O, is reported here for the first time.The oxalate compound prepared was found to be remarkably stable in relation to aerial oxidation, unlike other representative solid state compounds of the vanadium(II) oxidation state. Vanadium(II) oxalate dihydrate may, therefore, serve as an important intermediate in the future synthesis of other vanadium(II) compounds.