乙基2-[4-(2,2-二氯环丙基)苯氧基]-2-甲基丙酸盐 | 52519-51-4

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 中文名称: 乙基2-[4-(2,2-二氯环丙基)苯氧基]-2-甲基丙酸盐
• 中文别名: 3,3,4,4,4-五氟丁基甲基丙烯酸酯
• 英文名称: 3,3,4,4,4-Pentafluorobutyl methacrylate
• 英文别名: 3,3,4,4,4-pentafluorobutyl 2-methylprop-2-enoate
• CAS: 52519-51-4
• 化学式: C₈H₉F₅O₂
• 分子量: 232.15
• InChiKey: DJMQEXDGIXFVSC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.8
• 重原子数：
  15
• 可旋转键数：
  5
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.62
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  7

文献信息

• Transition metal compound, polymerization-initiator system comprising the same, and process for producing polymer
  申请人：Uemura Makoto

  公开号：US20070270521A1

  公开（公告）日：2007-11-22

  A transition metal compound represented by the formula, [(CpR 1 m )(CO) 2 M 1 ][M 2 (CO) 2 (CpR 2 n )], wherein Cp is a cyclopentadienyl ring, R 1 and R 2 are independently of each other a hydrocarbyl group having 1 to 20 carbon atoms, and each of at least one R 1 and at least one R 2 is a hydrocarbyl group having 5 to 20 carbon atoms, m and n are independently of each other an integer of 1 to 5, and M 1 and M 2 are independently of each other a transition metal atom of the group 8 in the periodic table of elements; a polymerization-initiator system comprising said transition metal compound; and a process for producing a polymer in the presence of the polymerization-initiator system.

  一个由该公式表示的过渡金属化合物，[(CpR1m)(CO)2M1][M2(CO)2(CpR2n)]，其中Cp是一个环戊二烯环，R1和R2是独立的烃基团，含有1至20个碳原子，至少一个R1和至少一个R2是含有5至20个碳原子的烃基团，m和n是独立的1至5的整数，M1和M2是元素周期表中8族的过渡金属原子；包括所述过渡金属化合物的聚合物化引发剂系统；以及在聚合物化引发剂系统存在的情况下生产聚合物的过程。
• INK COMPOSITION, INKJET RECORDING METHOD AND PROCESS FOR PRODUCING MOLDED PRINTED MATERIAL
  申请人：MOCHIZUKI Kyohei

  公开号：US20110242191A1

  公开（公告）日：2011-10-06

  An ink composition is provided that includes (Component a) an open-chain and/or cyclic ether bond-containing monofunctional (meth)acrylate, (Component b) one or more monofunctional ethylenically unsaturated compounds selected from the group consisting of a polycyclic aliphatic group-containing monofunctional (meth)acrylate and N-vinyl-2-caprolactam, (Component c) a polymerization initiator, (Component e) a polyfunctional (meth)acrylate at no greater than 10 wt % relative to the ink composition, and (Component f) a fluorine-substituted hydrocarbon group- or siloxane structure-containing polymer, the ratio by weight of (Component a)/(Component b) being 0.7 to 1.9. There are also provided an inkjet recording method that includes (a 1 ) an image formation step of forming an image above a recording medium by discharging the ink composition by an inkjet method and (b 1 ) a curing step of curing the ink composition by irradiating the obtained image with actinic radiation to thus obtain a cured image above the recording medium, and a process for producing a molded printed material that includes (a 2 ) an image formation step of forming an image above a recording medium by discharging the ink composition by an inkjet method, (b 2 ) a curing step of curing the ink composition by irradiating the obtained image with actinic radiation to thus obtain a printed material having a cured image above the recording medium, and (c 2 ) a molding step of molding the printed material.

  提供了一种墨水组合物，包括（组分a）一种开链和/或环状醚键含有单官能基（甲基）丙烯酸酯，（组分b）一种或多种单官能基乙烯基不饱和化合物，所述化合物选自包含多环脂肪族基的单官能基（甲基）丙烯酸酯和N-乙烯基-2-己内酰胺的群组，（组分c）一种聚合引发剂，（组分e）一种多官能基（甲基）丙烯酸酯，相对于墨水组合物不大于10重量％，以及（组分f）一种含有氟代烃基或硅氧烷结构的聚合物，其中（组分a）/（组分b）的重量比为0.7到1.9。还提供了一种喷墨记录方法，包括（a1）通过喷墨方法排放墨水组合物形成记录介质上的图像形成步骤和（b1）通过照射获得的图像进行光致固化的固化步骤，从而在记录介质上获得固化图像，以及一种生产模塑印刷材料的过程，包括（a2）通过喷墨方法排放墨水组合物形成记录介质上的图像形成步骤，（b2）通过照射获得的图像进行光致固化的固化步骤，从而在记录介质上获得具有固化图像的印刷材料，以及（c2）模塑印刷材料的模塑步骤。
• Novel functional polymers
  申请人：WAKO PURE CHEMICAL INDUSTRIES, LTD

  公开号：EP0794199A2

  公开（公告）日：1997-09-10

  To provide a polymer comprising as a structural unit a monomer unit containing a hydroxy group or other hydrophilic radical and other functional group in the molecule which is useful in medical, cosmetic and electric industries. A polymer comprising as a structural unit a monomer unit shown by the general formfula [1] (wherein R1 and R2 are, independently, a hydrogen atom or a halogen atom, R3 is a hydrophilic radical and R4 is a cyano group or a carboxyl group which may be esterified).

  提供一种聚合物，其结构单元是分子中含有羟基或其他亲水基团和其他官能团的单体单元，可用于医疗、化妆品和电气行业。 一种聚合物，其结构单元包括通式富拉[1]所示的单体单元 (其中 R1 和 R2 分别为氢原子或卤素原子，R3 为亲水基团，R4 为氰基或可酯化的羧基）。
• PHOTOSENSITIVE RESIN COMPOSITION AND FLEXOGRAPHIC RESIN PLATE
  申请人：TOKYO OHKA KOGYO CO., LTD.

  公开号：EP0950923A1

  公开（公告）日：1999-10-20

  The present invention provides a photosensitive resin composition which comprises an urethane resin obtained by reacting (A) a carboxyl group-containing polymer having an acid value of 30 mg KOH/g or more and a glass transition temperature of 30°C or more, (B) a compound having two isocyanate groups in one molecule, (C) a compound having two hydroxyl groups in one molecule and (D) a photopolymerizable unsaturated monomer having one hydroxyl group in one molecule, and a photopolymerization initiator, and a resin plate for flexography using the photosensitive resin composition, whereby the photosensitive resin composition having water developing properties, high in sensitivity and impact resilience, and excellent in water resistance, ink resistance and press life of a hardened portion forming a line pattern area of a printing plate material and the resin plate for flexography prepared by the use of the photosensitive resin composition can be provided.

  本发明提供了一种感光树脂组合物，它包括由以下物质反应得到的聚氨酯树脂：(A)酸值大于等于30毫克KOH/克且玻璃化温度大于等于30℃的含羧基聚合物；(B)一个分子中含有两个异氰酸酯基团的化合物；(C)一个分子中含有两个羟基的化合物；(D)一个分子中含有一个羟基的可光聚合不饱和单体、和一种光聚合引发剂，以及一种使用该感光树脂组合物的柔性版印刷用树脂版，从而可以提供具有水显影特性、高灵敏度和高冲击回弹性，以及在形成印刷版材料的线条图案区域的硬化部分和使用该感光树脂组合物制备的柔性版印刷用树脂版中具有优异的耐水性、耐油墨性和印刷寿命的感光树脂组合物。
• Relining material for dentures
  申请人：Kuraray Co., Ltd.

  公开号：EP1033125A1

  公开（公告）日：2000-09-06

  Provided is a denture rebase comprising a fluoro(meth)acrylate having a specific side chain structure and a specific amount of a polyfunctional (meth)acrylate. The denture rebase is free from the serious problems with conventional denture rebases that are readily discolored and stained and absorb smelling substances and water. It has good contamination and staining resistance, and its cured product is tough.

  本文提供了一种义齿修复剂，它由具有特定侧链结构的氟丙烯酸酯和特定量的多官能（甲基）丙烯酸酯组成。该义齿修复基托不存在传统义齿修复基托容易褪色、染色、吸附异味物质和水分等严重问题。它具有良好的抗污染和抗染色性，固化后的产品韧性强。