3,5-bis(5-hexylcarbamoylpentyloxy)benzoic acid decyl ester

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 3,5-bis(5-hexylcarbamoylpentyloxy)benzoic acid decyl ester
• 英文别名: 3,5-Bis-(5-hexylcarbamoyl-pentyloxy)-benzoic acid decyl ester；decyl 3,5-bis[6-(hexylamino)-6-oxohexoxy]benzoate
• 化学式: C₄₁H₇₂N₂O₆
• 分子量: 689.032
• InChiKey: ITXFRYAAGOYFQM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  11.5
• 重原子数：
  49
• 可旋转键数：
  35
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.78
• 拓扑面积：
  103
• 氢给体数：
  2
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  癸醇 在 四丁基溴化铵 、 potassium carbonate 、 对甲苯磺酸 作用下， 以 N,N-二甲基甲酰胺 、 甲苯 为溶剂， 反应 96.0h， 生成 3,5-bis(5-hexylcarbamoylpentyloxy)benzoic acid decyl ester
  参考文献：
  名称：

  在有机溶剂中的自组装二酰胺纳米管。

  摘要：

  DOI：

  10.1002/anie.200500536

文献信息

• Self-assembling properties of a series of homologous ester-diamides – from ribbons to nanotubes
  作者：François-Xavier Simon、Thi Thanh Tam Nguyen、Nancy Díaz、Marc Schmutz、Bruno Demé、Jacques Jestin、Jérôme Combet、Philippe J. Mésini

  DOI：10.1039/c3sm51369f

  日期：——

  We have studied the aggregation properties of a series of compounds BHPB-n bearing two amide groups and an ester alkyl chain. The number (n) of carbon atoms in this alkyl chain has been varied from 5 to 16. These compounds form gels at low concentration in alkanes. The gel concentrations and the heats of formation of the gels, measured by DSC, are divided into three different regimes: n ≤ 7, 8 ≤ n

  我们研究了一系列带有两个酰胺基和一个酯烷基链的化合物BHPB- n的聚集性质。该烷基链中的碳原子数（n）为5至16。这些化合物在烷烃中形成低浓度的凝胶。凝胶的浓度和形成凝胶，通过DSC测量的预赛，分为三个不同的制度：Ñ ≤7,8≤ Ñ ≤12和Ñ ≥13.冷冻断裂透射电镜显示，所有化合物自组装成高纵横比的目的，即用于扁平带ñ ≤7个不规则为螺旋带ñ ≥13.对于8≤ ñ≤12时，化合物形成管（BHPB-11除外），并由SANS研究。用成对的管子模型由散射强度确定管子的外径和内径分布。直径由酯链的长度（n）控制，范围从BHPB-8的21到BHPB-12的32 nm（外径）不等。SANS测量还提供了成对管的比例以及最终与这些管共存的非管状物体的比例的估计值。可变温度FTIR和DSC证明，酰胺基团之间的H键参与所有类型的自组装。此外，螺旋带和纳米管的FTIR光谱显示出一个双酯ν CO 带子，而平
• SOLID CATALYTIC COMPOSITIONS BASED ON MESOPOROUS ORGANIC MATERIALS
  申请人：Mesini Philippe

  公开号：US20130017944A1

  公开（公告）日：2013-01-17

  The present invention relates to the preparation of a solid catalytic composition based on a functionalized porous organic material, wherein: (A) organogelator compounds are self-assembled, within a medium comprising organic monomers, in the form of fibrillar structures having a diameter ranging from 10 nm to 100 nm; and then (B) the monomers are then polymerized; and then (C) the organogelator compounds are extracted from the polymer material, thereby obtaining a porous polymer material (M 0 ), wherein the monomers bear reactive R functions, for which the presence is sought on the material; or said reactive R functions in protected form; or functions able to allow grafting of said reactive R functions on the polymer materials; and wherein, following step (C), (D) all or part of the functions present at the walls of the mesopores of the polymer material (M 0 ) are converted where appropriate into reactive R functions and a composition is recovered comprising a porous polymer material (M) bearing the reactive R functions, as a catalytic composition.
• Self-Assembled Diamide Nanotubes in Organic Solvents
  作者：Nancy Díaz、François-Xavier Simon、Marc Schmutz、Michel Rawiso、Gero Decher、Jacques Jestin、Philippe J. Mésini

  DOI：10.1002/anie.200500536

  日期：2005.5.20