乙烯基,2,2-二氯- | 134153-49-4

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 乙烯基卤化物
• 中文名称: 乙烯基,2,2-二氯-
• CAS: 134153-49-4
• 化学式: C₂HCl₂
• 分子量: 95.9359
• InChiKey: DHLUJLBQYGYFJV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.3
• 重原子数：
  4
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  1,1-二氯乙烯 在 hydroxide 作用下， 以 gas 为溶剂， 24.9 ℃ 、98.66 kPa 条件下， 生成 水 、 乙烯基,2,2-二氯-
  参考文献：
  名称：

  Laser photolysis/laser-induced fluorescence studies of the reaction of hydroxyl with 1,1,1-trichloroethane over an extended temperature range

  摘要：

  Absolute rate coefficients are determined for the gas-phase reaction of OH radicals with 1,1,1-trichloroethane over an extended temperature range. Employing a laser photolysis/laser-induced fluorescence technique, experiments were conducted with a flow system at a total pressure of 740 +/- 10 Torr using He as diluent and carrier gas. The rate coefficients, obtained over the temperature range 298-761 K, exhibited pronounced non-Arrhenius behavior and were best described by the modified Arrhenius equation k(T) = (3.95 +/- 0.78) X 10(-13)(T/300)2.08 exp{(-1068 +/- 108)/T} CM3 Molecule-1 s-1. Comparison of the data with numerous lower temperature measurements is presented. The temperature dependence of the data is compared with empirical and transition-state model calculations. The reactivity of this compound with OH compared to other chlorinated ethanes at both lower and higher reaction temperatures is presented and discussed.

  DOI：

  10.1021/j100201a048

文献信息

• Laser photolysis/laser-induced fluorescence studies of the reaction of hydroxyl with 1,1-dichloroethane over an extended temperature range
  作者：Zhen Jiang、Philip H. Taylor、Barry Dellinger

  DOI：10.1021/j100201a049

  日期：1992.10

  Absolute rate coefficients are determined for the gas-phase reaction of OH radicals with 1,1-dichloroethane over an extended temperature range using a laser photolysis/laser-induced fluorescence technique. Experiments were performed in a flow system at a total pressure of 740 +/- 10 Torr using He as diluent and carrier gas. The rate coefficients, obtained over the temperature range 294-800 K, exhibited pronounced non-Arrhenius behavior and were best described by the modified Arrhenius equation k(T) = (8.29 +/- 0.36) X 10(-14)(T/300)2.67 exp(378 +/- 18)/T} CM3 Molecule-1 s-1. Comparison of the data with one previous room-temperature measurement is presented. The temperature dependence of the data is compared with empirical and transition-state model calculations. The influence of C-H bond energy and Cl substitution is discussed.
• Laser photolysis/laser-induced fluorescence studies of the reaction of hydroxyl with 1,1,1-trichloroethane over an extended temperature range
  作者：Zhen Jiang、Philip H. Taylor、Barry Dellinger

  DOI：10.1021/j100201a048

  日期：1992.10

  Absolute rate coefficients are determined for the gas-phase reaction of OH radicals with 1,1,1-trichloroethane over an extended temperature range. Employing a laser photolysis/laser-induced fluorescence technique, experiments were conducted with a flow system at a total pressure of 740 +/- 10 Torr using He as diluent and carrier gas. The rate coefficients, obtained over the temperature range 298-761 K, exhibited pronounced non-Arrhenius behavior and were best described by the modified Arrhenius equation k(T) = (3.95 +/- 0.78) X 10(-13)(T/300)2.08 exp(-1068 +/- 108)/T} CM3 Molecule-1 s-1. Comparison of the data with numerous lower temperature measurements is presented. The temperature dependence of the data is compared with empirical and transition-state model calculations. The reactivity of this compound with OH compared to other chlorinated ethanes at both lower and higher reaction temperatures is presented and discussed.