diaquobis(D,L-lactato)zinc(II) monohydrate

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: diaquobis(D,L-lactato)zinc(II) monohydrate
• 英文别名: zinc(II) dl-lactate trihydrate；zinc dl-lactate trihydrate；zinc lactate trihydrate；DL-lactic acid ; zinc lactate；DL-Milchsaeure; Zinklactat
• 化学式: 2C₃H₅O₃*3H₂O*Zn
• 分子量: 297.578
• InChiKey: COUCUTWWGHEBGD-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  -2.71
• 重原子数：
  8.0
• 可旋转键数：
  1.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  91.86
• 氢给体数：
  1.0
• 氢受体数：
  3.0

反应信息

• 作为反应物：
  描述：

  diaquobis(D,L-lactato)zinc(II) monohydrate 生成 bis(D,L-lactato)zinc(II)
  参考文献：
  名称：

  Verma, R. K.; Verma, Lata; Chandra, M., Journal of the Indian Chemical Society, 1998, vol. 75, # 3, p. 162 - 164

  摘要：

  DOI：
• 作为产物：
  描述：

  乳酸 在 zinc(II) carbonate or hydroxocarbonate 作用下， 以 水 为溶剂， 生成 diaquobis(D,L-lactato)zinc(II) monohydrate
  参考文献：
  名称：

  Chelating properties of lactate anion. perturbing effect of additional ligands on bis(DL-lactato)-metal(II) complexes

  摘要：

  DOI：

  10.1016/s0020-1693(00)86249-0

文献信息

• Non-isothermal dehydration and decomposition of dl-lactates of transition metals and alkaline earth metals
  作者：R. K. Verma、L. Verma、M. Chandra、A. Bhushan

  DOI：10.1007/s10973-005-0659-9

  日期：2005.5

  study of the non-isothermal decomposition of the dl -lactate hydrates of magnesium, calcium and strontium has been made with that of the dl -lactate hydrates chromium(III), manganese(II), iron(II), cobalt(II), nickel(II), copper(II) and zinc(II) keeping dry air as the purge gas and the heating rate maintained at 10 K min-1. While the dl -lactates of manganese(II), cobalt(II) and copper(II) followed

  所述的非等温分解的比较研究 DL 镁，钙和锶的乳酸盐水合物已取得了的 DL -乳水合物铬（III），锰（II），铁（II），钴（II ），镍（II），铜（II）和锌（II）保持干燥的空气作为吹扫气体，加热速率保持在10 K min -1。尽管锰（II），钴（II）和铜（II）的 dl- 乳酸盐遵循单步分解方案，表明脱水和分解步骤重叠，但其他化合物的脱水步骤却截然不同。＆AGR; - Ť 没有一个脱水步骤的曲线显示任何诱导期，表明没有物理解吸，成核或分支。＆agr;都不 最大值和脱水步骤的起始温度均未显示任何模式。还使用Freeman-Carroll，Horowitz-Metzger，Coats-Redfern，Zsak＆oacute;，Fuoss-Salyer-Wilson和Karkhanavala-Dharwadkar方法分析了脱水步骤的TG数据。反应阶数，活化能和阿累尼乌斯因子的值已被
• Electrochemical Synthesis of Complex Compounds of Transition Elements with Carboxyl- and Carbonyl-containing Ligands
  作者：V. Yu. Frolov、S. N. Bolotin、V. T. Panyshkin

  DOI：10.1007/s11167-005-0416-7

  日期：2005.6

  Complex compounds of d- and f-elements with carboxyl- and carbonyl-containing ligands were synthesized by the electrochemical method. The influence exerted by a number of factors on the process course was studied. The dependence of the electrosynthesis parameters on the composition of the forming compounds was established. The composition of these compounds was determined. A new method for anodic synthesis of these compounds was developed.

  采用电化学方法合成了 d 元素和 f 元素与含羧基和羰基配体的复合物。研究了多种因素对合成过程的影响。确定了电合成参数对形成的化合物组成的依赖性。确定了这些化合物的组成。开发了阳极合成这些化合物的新方法。
• Verma, Ranjit K.; Verma, Lata; Chandra, Mukesh, Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical and Analytical, 2003, vol. 42, # 12, p. 2982 - 2987
  作者：Verma, Ranjit K.、Verma, Lata、Chandra, Mukesh

  DOI：——

  日期：——
• ESR and optical study of Mn2+-doped zinc lactate trihydrate
  作者：Ram Kripal、D.K. Singh

  DOI：10.1016/j.jmmm.2006.02.250

  日期：2006.11

  ESR study of Mn2+-doped Zinc Lactate Trihydrate (ZLT) single crystals has been done at room temperature. The Mn2+ spin-Hamiltonian parameters have been evaluated employing a large number of resonant line positions observed for different orientations of the external magnetic field. The values of g, A, B, D, E and a are 1.9769 +/- 0.0002, 89 +/- 2 x 10(-4), 84 +/- 2 x 10(-4), 330 +/- 2 x 10(-4), 103 +/- 2 x 10(-4) and 10 +/- 1 x 10(-4) cm(-1), respectively. The optical absorption study of the crystal has also been done. The observed bands are assigned as transitions from the (6)A(1g)(S) ground state to various excited quartet levels of a Mn2+ ion in a cubic crystalline field. These bands are fitted with four parameters B, C, D-q and alpha and the values found for the parameters are B = 778 cm(-1), C = 3083 cm(-1), D-q = 760 cm(-1), and a = 76 cm(-1). On the basis of the data obtained the surrounding crystalline field and the nature of metal-ligand bonding have been discussed. (C) 2006 Elsevier B.V. All rights reserved.