benzyltributylammonium acetate

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: benzyltributylammonium acetate
• 英文别名: Benzyl(tributyl)azanium;acetate
• 化学式: C₂H₃O₂*C₁₉H₃₄N
• 分子量: 335.53
• InChiKey: DMFFPWIZNUMJNS-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  4.16
• 重原子数：
  24
• 可旋转键数：
  11
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  40.1
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  乙酸苄酯 、 苄基三丁基溴化铵 以 甲苯 为溶剂， 生成 溴甲苯 、 benzyltributylammonium acetate
  参考文献：
  名称：

  Kinetics of the nucleophilic substitution of benzyl-tributylammonium bromide with allyl, butyl, and benzyl chlorides and with benzyl acetate and benzyl ether

  摘要：

  In this study, we investigated the kinetics of the nucleophilic substitutions, RX + (BzBu(3)NBr) reversible arrow RBr + (BzBu(3)NX), where R = allyl, Bu and Bz, when X = CI; and X = AcO and BzO when R = Bz. The forward and backward rate constants in addition to the activation energies for R = allyl and Bu were also determined. However, only the rate constants at 35 degrees C were determined for the benzyl compounds with toluene as the solvent to reduce the reaction rate. Moreover, the effects of the structures of the groups R and the leaving groups X on the reactivity were compared. Results in this study can provide valuable information for future studies involving the phase transfer catalyzed displacements. (C) 1996 John Wiley & Sons, Inc.

  DOI：

  10.1002/(sici)1097-4601(1996)28:8<615::aid-kin7>3.0.co;2-y

文献信息

• Process for the preparation of carboxylic benzyl esters
  申请人：——

  公开号：US20030233008A1

  公开（公告）日：2003-12-18

  Carboxylic benzyl esters can be prepared by reacting benzyl chloride with carboxylic acids in the presence of one or more quaternary ammonium carboxylates as catalyst.

  羧基苄酯可以通过在一个或多个季铵羧酸盐存在的催化剂下，将苄基氯与羧酸反应制备而成。
• Verfahren zur Herstellung von Carbonsäurebenzylestern
  申请人：Bayer Aktiengesellschaft

  公开号：EP1371627A1

  公开（公告）日：2003-12-17

  Carbonsäurebenzylester können durch Umsetzung von Benzylchlorid mit Carbonsäuren in Gegenwart eines oder mehrerer quartären Ammoniumcarboxylate als Katalysator hergestellt werden.

  Carbonsäure苯甲酯可以通过在一个或多个季铵羧酸盐存在下，将苯甲酰氯与羧酸反应制备而成。
• Method for preparing aliphatic polythioether
  申请人：ZHEJIANG UNIVERSITY

  公开号：US11440995B2

  公开（公告）日：2022-09-13

  A method for preparing aliphatic polythioether is provided. In the method, aliphatic polythioether is obtained by polymerization reaction using a sulfur-carbon compound and an oxygen-containing monomer as raw materials and using Lewis base as a catalyst, and the polymerization reaction is performed under a self-generated pressure at 80˜180° C. Based on the defects of the traditional preparation process of aliphatic polythioether, a bran-new synthetic routine is provided, in which a new process for preparing polythioether in one-pot reaction is achieved through oxygen-sulfur exchange reaction between the sulfur-carbon compound and the oxygen-containing monomer.

  本发明提供了一种制备脂肪族聚硫醚的方法。在该方法中，以硫碳化合物和含氧单体为原料，以路易斯碱为催化剂，通过聚合反应得到脂肪族聚硫醚，聚合反应在 80 ˜180°C的自生压力下进行。根据脂肪族聚硫醚传统制备工艺的缺陷，提供了一种全新的合成工艺，通过硫碳化合物与含氧单体之间的氧硫交换反应，实现了一锅反应制备聚硫醚的新工艺。
• Synthesis of aliphatic 1, 3-diols utilizing reduced ligand concentration and water extraction
  申请人：——

  公开号：US20030166977A1

  公开（公告）日：2003-09-04

  This invention is a process for synthesizing aliphatic 1,3-diols in one step by hydroformylation and hydrogenation of oxirane, carbon monoxide, and hydrogen employing a catalyst comprising a cobalt carbonyl compound and a cocatalyst metal compound ligated with a ligand in a ligand to cocatalyst metal atom molar ratio in the range of 0.2:1.0 to 0.6:1.0, optionally in the presence of a promoter, where recovery of product is preferably accomplished via water extraction of a diol rich phase from the bulk reaction mixture. The process modifications can, particularly in combination, be beneficial with respect to product recovery, catalyst recycle, and overall economics of a one-step process for producing aliphatic 1,3-diols.

  本发明是一种通过环氧乙烷、一氧化碳和氢的加氢甲酰化和氢化一步合成脂族 1，3-二元醇的工艺，采用的催化剂包括羰基钴化合物和与配体配位的助催化剂金属化合物，配体与助催化剂金属原子摩尔比在 0.产品的回收最好通过从反应混合物中水萃取富含二元醇的相来完成。这些工艺改良，尤其是结合使用，可有利于产品回收、催化剂循环以及一步法生产脂肪族 1,3-二元醇的整体经济性。
• Dispersions of water-insoluble photographic addenda
  申请人：EASTMAN KODAK COMPANY (a New Jersey corporation)

  公开号：EP0183480B1

  公开（公告）日：1990-03-14