dodecyl-carbamic acid butyl ester

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: dodecyl-carbamic acid butyl ester
• 英文别名: Dodecyl-carbamidsaeure-butylester；Butyl N-dodecylcarbamate
• 化学式: C₁₇H₃₅NO₂
• 分子量: 285.47
• InChiKey: XGWVZANXYSUDKG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.8
• 重原子数：
  20
• 可旋转键数：
  15
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.94
• 拓扑面积：
  38.3
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  十二烷基伯胺 、 氨基甲酸丁酯 、 正丁醇 在 5.1 wt% Ni/Fe3O4 作用下， 190.0 ℃ 、2.2 MPa 条件下， 反应 5.0h， 以91%的产率得到dodecyl-carbamic acid butyl ester
  参考文献：
  名称：

  在Ni促进的Fe 3 O 4催化剂上，以氨基甲酸烷基酯为羰基源合成N-取代的氨基甲酸酯

  摘要：

  用共沉淀法制备了一系列含镍量不同的镍的磁性氧化铁催化剂，并在由各种胺和氨基甲酸烷基酯合成N-取代的氨基甲酸酯中进行了测试。在优化的反应条件下，成功合成了各种N-取代的氨基甲酸酯，分离产率为90-98％。可以基于催化剂的磁性来回收催化剂，并在不失活的情况下重复使用五次。通过X射线光电子能谱，X射线衍射，程序升温还原，程序升温脱附和Mössbauer光谱分析对催化剂进行了表征。结果表明，催化活性可能源于镍和铁物种之间细微的协同作用，导致特定的碱性位点。

  DOI：

  10.1016/j.jcat.2011.01.030

文献信息

• METHOD FOR TREATMENT OF ISOCYANATE RESIDUE, AND METHOD FOR TREATMENT OF CARBONATE
  申请人：Mitsui Chemicals, Inc.

  公开号：EP2518044A1

  公开（公告）日：2012-10-31

  A method for treating an isocyanate residue, which comprises carrying out a thermal decomposition reaction of a carbamate that is produced by the reaction among an amine, urea and/or an N-unsubstituted carbamic acid ester and an alcohol to produce a decomposition solution, separating an isocyanate and the alcohol from the decomposition solution to produce the isocyanate residue, and bringing the isocyanate residue into contact with high-pressure/high-temperature water to decompose the isocyanate residue into an amine; and a method for treating a carbonate, which comprises bringing the carbonate into contact with high-pressure/high-temperature water to decompose the carbonate into an alcohol.

  一种处理异氰酸酯残留物的方法，包括对氨基甲酸酯进行热分解反应，该氨基甲酸酯是由胺、尿素和/或 N-未取代氨基甲酸酯与醇反应生成的，从分解溶液中分离出异氰酸酯和醇，生成异氰酸酯残留物，将异氰酸酯残留物与高压/高温水接触，将异氰酸酯残留物分解成胺；一种处理碳酸盐的方法，包括使碳酸盐与高压/高温水接触，将碳酸盐分解成醇。
• Syntheses of polycarbonate and polyurethane precursors utilizing CO2 over highly efficient, solid as-synthesized MCM-41 catalyst
  作者：R. Srivastava、D. Srinivas、P. Ratnasamy

  DOI：10.1016/j.tetlet.2006.04.057

  日期：2006.6

  As-synthesized MCM-41 was used as a reusable, heterogeneous catalyst for the eco-friendly synthesis of cyclic carbonate precursors of polycarbonates via a cycloaddition reaction of CO2 with epoxides. This catalyst is also efficient for the synthesis of alkyl and aryl carbamate precursors of polyurethanes via the reaction of amines, CO2 and alkyl halides. Both these reactions were carried out under mild conditions and without using any solvent or co-catalyst. CO2 is utilized as a raw material replacement for toxic phosgene in the conventional synthesis of these chemicals. (c) 2006 Elsevier Ltd. All rights reserved.
• The Conversion of Formamides into Formamidines¹
  作者：H. George Mandel、Arthur J. Hill

  DOI：10.1021/ja01644a034

  日期：1954.8
• N-substituted carbamates syntheses with alkyl carbamates as carbonyl source over Ni-promoted Fe3O4 catalyst
  作者：Jianpeng Shang、Xiaoguang Guo、Feng Shi、Yubo Ma、Feng Zhou、Youquan Deng

  DOI：10.1016/j.jcat.2011.01.030

  日期：2011.4

  magnetic iron oxide containing Ni with different nickel content were prepared with co-precipitation method and tested in the syntheses of N-substituted carbamates from various amines and alkyl carbamates. Under the optimized reaction conditions, various N-substituted carbamates were successfully synthesized with 90–98% isolated yield. The catalyst could be recovered based on the magnetic property of the catalyst

  用共沉淀法制备了一系列含镍量不同的镍的磁性氧化铁催化剂，并在由各种胺和氨基甲酸烷基酯合成N-取代的氨基甲酸酯中进行了测试。在优化的反应条件下，成功合成了各种N-取代的氨基甲酸酯，分离产率为90-98％。可以基于催化剂的磁性来回收催化剂，并在不失活的情况下重复使用五次。通过X射线光电子能谱，X射线衍射，程序升温还原，程序升温脱附和Mössbauer光谱分析对催化剂进行了表征。结果表明，催化活性可能源于镍和铁物种之间细微的协同作用，导致特定的碱性位点。