(2-cyclohexylphenyl)(phenyl)methanone

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (2-cyclohexylphenyl)(phenyl)methanone
• 英文别名: Cyclohexyl benzophenone；(2-cyclohexylphenyl)-phenylmethanone
• 化学式: C₁₉H₂₀O
• 分子量: 264.367
• InChiKey: VDOZYQWISJXGLO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.8
• 重原子数：
  20
• 可旋转键数：
  3
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.32
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  sodium benzoate 、 sodium cyclohexanolate 在 iron(II,III) oxide 作用下， 反应 22.0h， 以66.4 g的产率得到(2-cyclohexylphenyl)(phenyl)methanone
  参考文献：
  名称：

  一种羟基酮类光引发剂中间体芳基烷基酮的 制备方法

  摘要：

  本发明涉及的内容为一种羟基酮类光引发剂中间体芳基烷基酮的制备方法，具体涉及一种（取代）苯基烷基酮的制备方法。该制备方法在反应过程中将产物分离，工艺简单，缩短生产周期；催化剂和溶剂容易循环套用；产品收率高，生产成本低；整个反应过程环境友好。

  公开号：

  CN107778155B

文献信息

• Bis(tri-n-butylstannyl)benzopinacolate: Preparation and use as a mediator of intermolecular free radical reactions
  作者：David J. Hart、Ramanarayanan Krishnamurthy、Lori M. Pook、Franklin L. Seely

  DOI：10.1016/s0040-4039(00)61484-3

  日期：1993.12

  Bis(tri-n-butylstannyl)benzopinacolate (2) serves as a thermal source of tri-n-butylstannyl radicals and mediates intermolecular coupling of selected alkyl halides to O-benzylformaldoxime and electron deficient olefins. A free radical non-chain mechanism is proposed for these reactions.

  双（三正丁基锡烷基）苯甲酸频哪酸酯（2）充当三正丁基锡烷基自由基的热源，并介导所选的烷基卤化物与O-苄基甲醛肟和缺电子烯烃的分子间偶联。提出了用于这些反应的自由基非链机制。
• PHOTOSENSITIVE INSULATING RESIN COMPOSITION, CURED PRODUCT THEREOF AND ABA BLOCK COPOLYMER
  申请人：ITO Atsushi

  公开号：US20110172349A1

  公开（公告）日：2011-07-14

  A photosensitive insulating resin composition includes a block copolymer, a crosslinking agent, a photosensitive compound, and a solvent. The block copolymer includes a first structural unit shown by a following formula (1) and a second structural unit shown by a following formula (2), wherein R 1 represents a hydrogen atom or an alkyl group having 1 to 4 carbon atoms, and R 2 represents an alkyl group having 1 to 4 carbon atoms.

  一种光敏绝缘树脂组合物，包括嵌段共聚物、交联剂、光敏化合物和溶剂。嵌段共聚物包括以下公式（1）所示的第一结构单元和以下公式（2）所示的第二结构单元，其中R1代表氢原子或具有1至4个碳原子的烷基基团，R2代表具有1至4个碳原子的烷基基团。
• Light emitting polymer composition, and organic electroluminescene device and production process thereof
  申请人：JSR Corporation

  公开号：EP1311138A1

  公开（公告）日：2003-05-14

  Disclosed herein is a light emitting polymer composition which permits providing an organic electroluminescence device high in luminous efficiency and excellent in durability and forming a functional organic material layer with ease by the wet process. The light emitting polymer composition comprising a polymer component and a phosphorescent agent contained in the polymer component, wherein the polymer component is composed of a hole transporting component formed from 50 to 99 mol% of a hole transporting monomer and an electron transporting component formed from 50 to 1 mol% of an electron transporting monomer. The polymer component is a copolymer composed of 50 to 99 mol% of structural units derived from the hole transporting monomer and 50 to 1 mol% of structural units derived from the electron transporting monomer, or is composed of a hole transporting polymer obtained from the hole transporting monomer and an electron transporting polymer obtained from the electron transporting monomer, and a proportion of the hole transporting polymer to the electron transporting polymer is 50:50 to 99:1 in terms of a molar ratio reduced to the monomers. The light emitting polymer composition is used in an organic electroluminescence device and a production process thereof.

  本文公开了一种发光聚合物组合物，该组合物可提供发光效率高、耐用性好的有机电致发光器件，并可通过湿法工艺轻松形成功能性有机材料层。 该发光聚合物组合物包括聚合物成分和聚合物成分中所含的磷光剂，其中聚合物成分由50-99 摩尔%的空穴传输单体形成的空穴传输成分和50-1 摩尔%的电子传输单体形成的电子传输成分组成。聚合物组分是由 50 至 99 摩尔%的空穴传输单体衍生的结构单元和 50 至 1 摩尔%的电子传输单体衍生的结构单元组成的共聚物，或者是由空穴传输单体获得的空穴传输聚合物和电子传输单体获得的电子传输聚合物组成的共聚物，并且空穴传输聚合物与电子传输聚合物的摩尔比为 50:50 至 99:1。该发光聚合物组合物可用于有机电致发光装置及其生产工艺中。
• PHOSPHORS AND PROCESS FOR PRODUCTION THEREOF, LUMINESCENT COMPOSITIONS, AND ORGANIC ELECTROLUMINESCENT DEVICES AND PROCESSES FOR PRODUCTION THEREOF
  申请人：JSR Corporation

  公开号：EP1516901A1

  公开（公告）日：2005-03-23

  Disclosed herein are, a phosphorescent agent which can form a thin film by a wet method and provide an organic electroluminescence device having high luminance and production process thereof, and a luminescent composition containing the phosphorescent agent, an organic electroluminescence device having a luminescent layer containing the phosphorescent agent and production process thereof. A phosphorescent agent according to the present invention comprising a polymer having in its molecule a structural unit represented by the following general formula (1). [In the general formula (1), M represents a metal atom having a valence of 2 to 4, each of R1 and R2 represents a hydrogen atom, a halogen atom, a cycloalkyl group, an aryl group and a heterocycle group and R1 and R2 may be either the same or different, X1 represents a phenylene group or a carbonyloxy group, X2 represents an alkylene group, L represents an organic ligand, p is an integer of 1 to 3, and q is 0 or 1.]

  本发明公开了一种可通过湿法形成薄膜并提供具有高亮度的有机电致发光器件的磷光剂及其生产工艺，以及一种含有该磷光剂的发光组合物、一种具有含有该磷光剂的发光层的有机电致发光器件及其生产工艺。 根据本发明的磷光剂包括一种聚合物，其分子中具有由以下通式（1）表示的结构单元。 [通式（1）中，M 代表价数为 2 至 4 的金属原子，R1 和 R2 分别代表氢原子、卤素原子、环烷基、芳基和杂环基，且 R1 和 R2 可以相同或不同，X1 代表亚苯基或碳酰氧基，X2 代表亚烷基，L 代表有机配位体，p 为 1 至 3 的整数，q 为 0 或 1。］
• Light emitting polymer composition, and organic electroluminescence device and production process thereof
  申请人：JSR CORPORATION

  公开号：US20030116788A1

  公开（公告）日：2003-06-26

  Disclosed herein is a light emitting polymer composition which permits providing an organic electroluminescence device high in luminous efficiency and excellent in durability and forming a functional organic material layer with ease by the wet process. The light emitting polymer composition comprising a polymer component and a phosphorescent agent contained in the polymer component, wherein the polymer component is composed of a hole transporting component formed from 50 to 99 mol % of a hole transporting monomer and an electron transporting component formed from 50 to 1 mol % of an electron transporting monomer. The polymer component is a copolymer composed of 50 to 99 mol % of structural units derived from the hole transporting monomer and 50 to 1 mol % of structural units derived from the electron transporting monomer, or is composed of a hole transporting polymer obtained from the hole transporting monomer and an electron transporting polymer obtained from the electron transporting monomer, and a proportion of the hole transporting polymer to the electron transporting polymer is 50:50 to 99:1 in terms of a molar ratio reduced to the monomers. The light emitting polymer composition is used in an organic electroluminescence device and a production process thereof.

  本文公开了一种发光聚合物组合物，该组合物可提供发光效率高、耐用性好的有机电致发光器件，并可通过湿法工艺轻松形成功能性有机材料层。 该发光聚合物组合物包括聚合物成分和聚合物成分中所含的磷光剂，其中聚合物成分由 50 至 99 摩尔%的空穴传输单体形成的空穴传输成分和 50 至 1 摩尔%的电子传输单体形成的电子传输成分组成。该聚合物成分是由 50 至 99 摩尔%的空穴传输单体衍生的结构单元和 50 至 1 摩尔%的电子传输单体衍生的结构单元组成的共聚物，或者是由空穴传输单体获得的空穴传输聚合物和电子传输单体获得的电子传输聚合物组成的共聚物，并且空穴传输聚合物与电子传输聚合物的摩尔比为 50:50 至 99:1。该发光聚合物组合物可用于有机电致发光装置及其生产工艺中。