N-[(3-pyridine)-sulfonyl]aspartate

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: N-[(3-pyridine)-sulfonyl]aspartate
• 英文别名: N-3-pyridinesulfonylaminosuccinic acid；2-(Pyridin-3-ylsulfonylamino)butanedioic acid；2-(pyridin-3-ylsulfonylamino)butanedioic acid
• 化学式: C₉H₁₀N₂O₆S
• mdl: MFCD25642398
• 分子量: 274.254
• InChiKey: JGDFPPJEQRTNBC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -1.1
• 重原子数：
  18
• 可旋转键数：
  6
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.222
• 拓扑面积：
  142
• 氢给体数：
  3
• 氢受体数：
  8

反应信息

• 作为反应物：
  描述：

  镉 、 N-[(3-pyridine)-sulfonyl]aspartate 在 三乙胺 作用下， 以 水 为溶剂， 反应 72.0h， 以70%的产率得到
  参考文献：
  名称：

  Effect of different temperature on the N-[(3-pyridine)-sulfonyl]aspartate polymers synthesis: Crystal structure and fluorescence

  摘要：

  The title coordination polymers of Zn(II), Cd(II), Pb(II) based on H2L (H2L = N-[(3-pyridine)-sulfonyl]aspartate) had been synthesized in the same material ratio, under different synthesis temperature. The results show that the polymer 1 is a three-dimensional structure and synthesized under room temperature condition; the polymers 2-4 are two-dimensional structure and synthesized under hydrothermal synthesis conditions. A structural comparison of these polymers suggests that different reaction temperatures play important role in the construction of resulting architectures for 1-4. Fluorescence properties of these polymers showed blue shift occurred.

  DOI：

  10.1134/s0036023617010181
• 作为产物：
  描述：

  吡啶-3-磺酰氯 、 DL-天门冬氨酸 在 sodium hydroxide 作用下， 反应 3.0h， 以73%的产率得到N-[(3-pyridine)-sulfonyl]aspartate
  参考文献：
  名称：

  两种铅 (II) 配位聚合物的合成、结构和荧光

  摘要：

  摘要 两种新型 Pb(II) 配位聚合物：Pb(L)·H2O]n (I) 和 [Pb(L)·(4,4'-bipy)0.5]n (II) (H2L = N-3-pyridine)磺酰基氨基丁二酸），合成并通过FT-IR、元素分析和单晶X射线衍射分析进行表征。结果表明，I在正交晶系Pbca空间群中结晶，a = 7.3492(7) Å, b = 15.4994(15) Å, c = 22.652(2) Å, α=β = γ = 90°, V = 2580.3(4) Å3；II以单斜晶系结晶，P21/n空间群，a = 5.1885(7) Å, b = 19.7136(15) Å, c = 15.4593(11) Å, α = γ = 90°, β = 92.8330(10) )°，V = 1579.3(3) Å3。热重分析（TGA）表明I和II可以分别在35~234°C和35~145°C的温度下保

  DOI：

  10.1080/24701556.2020.1716007

文献信息

• Synthesis, structures, and fluorescence of two lead(II) coordination polymers
  作者：Jianghui Wang、Zhimin Zhang

  DOI：10.1080/24701556.2020.1716007

  日期：2020.5.3

  Abstract Two novel Pb(II) coordination polymers: Pb(L)·H2O]n (I) and [Pb(L)·(4,4’-bipy)0.5]n (II) (H2L = N-3-pyridine sulfonyl amino succinic acid), were synthesized and characterized by FT-IR, elemental analysis, and single-crystal X-ray diffraction analysis. The results show that I crystallizes in orthorhombic system, Pbca space group, with a = 7.3492(7) Å, b = 15.4994(15) Å, c = 22.652(2) Å, α=β = γ = 90°

  摘要 两种新型 Pb(II) 配位聚合物：Pb(L)·H2O]n (I) 和 [Pb(L)·(4,4'-bipy)0.5]n (II) (H2L = N-3-pyridine)磺酰基氨基丁二酸），合成并通过FT-IR、元素分析和单晶X射线衍射分析进行表征。结果表明，I在正交晶系Pbca空间群中结晶，a = 7.3492(7) Å, b = 15.4994(15) Å, c = 22.652(2) Å, α=β = γ = 90°, V = 2580.3(4) Å3；II以单斜晶系结晶，P21/n空间群，a = 5.1885(7) Å, b = 19.7136(15) Å, c = 15.4593(11) Å, α = γ = 90°, β = 92.8330(10) )°，V = 1579.3(3) Å3。热重分析（TGA）表明I和II可以分别在35~234°C和35~145°C的温度下保
• Effect of different temperature on the N-[(3-pyridine)-sulfonyl]aspartate polymers synthesis: Crystal structure and fluorescence
  作者：Jing-Jing Jia、Shi-Xiong Li、Xiu-Ju Yin、Bei-Ling Liao、Yi-Min Jiang

  DOI：10.1134/s0036023617010181

  日期：2017.1

  The title coordination polymers of Zn(II), Cd(II), Pb(II) based on H2L (H2L = N-[(3-pyridine)-sulfonyl]aspartate) had been synthesized in the same material ratio, under different synthesis temperature. The results show that the polymer 1 is a three-dimensional structure and synthesized under room temperature condition; the polymers 2-4 are two-dimensional structure and synthesized under hydrothermal synthesis conditions. A structural comparison of these polymers suggests that different reaction temperatures play important role in the construction of resulting architectures for 1-4. Fluorescence properties of these polymers showed blue shift occurred.