二(1-羟基庚基)过氧化物 | 16128-22-6

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 中文名称: 二(1-羟基庚基)过氧化物
• 英文名称: Bis(1-hydroxyheptyl)peroxide
• 英文别名: 7-(7-hydroxyheptylperoxy)heptan-1-ol
• CAS: 16128-22-6
• 化学式: C₁₄H₃₀O₄
• 分子量: 262.39
• InChiKey: QLZINFDMOXMCCJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.7
• 重原子数：
  18
• 可旋转键数：
  15
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  58.9
• 氢给体数：
  2
• 氢受体数：
  4

安全信息

• 海关编码：
  2909600000

文献信息

• Monohydric polyfluorooxetane oligomers, polymers, and copolymers and coatings containing the same
  申请人：——

  公开号：US20030208015A1

  公开（公告）日：2003-11-06

  Monofunctional polyfluorooxetane oligomers, polymers, and copolymers are prepared by the cationic polymerization of fluorooxetane monomers with a monoalcohol. In addition to serving as an initiator, the monoalcohol can also serve as a solvent for the fluorooxetane or other monomers to produce oligomers, polymers, or copolymers having low cyclic content. Suitable comonomers generally include various cyclic ethers. The polyfluorooxetane oligomer, polymer, or copolymer having a single hydroxyl end group can be functionalized with a variety of compounds so as to yield a functional end group such as an acrylate, a methacrylate, an allylic, an amine, etc., with the functionalized oligomer or polymer being suitable for use in radiation curable or thermal curable coating compositions. These functionalized polymers can be copolymerized and cured to provide improvements in wetting and surface properties.

  通过氟氧杂环烷单体与单醇的阳离子聚合反应制备了单官能团聚合物、高聚物和共聚物。除了作为引发剂外，单醇还可以作为溶剂，与氟氧杂环烷或其他单体一起产生低环含量的寡聚物、高聚物或共聚物。适当的共聚单体通常包括各种环氧化合物。具有单一羟基末端的聚氟氧杂环烷寡聚物、高聚物或共聚物可以与各种化合物进行官能化，从而产生诸如丙烯酸酯、甲基丙烯酸酯、烯丙基、胺等官能末端基团，官能化的寡聚物或高聚物适用于辐射固化或热固化涂料配方。这些官能化聚合物可以共聚合和固化，从而提供润湿和表面性能的改善。
• Monohydric polyfluorooxetane oligomers, polymers, and copolymers and coating containing the same
  申请人：OMNOVA SOLUTIONS INC

  公开号：US20030149186A1

  公开（公告）日：2003-08-07

  Monofunctional polyfluorooxetane oligomers, polymers, and copolymers are prepared by the cationic polymerization of fluorooxetane monomers with a monoalcohol. In addition to serving as an initiator, the monoalcohol can also serve as a solvent for the fluorooxetane or other monomers to produce oligomers, polymers, or copolymers having low cyclic content. Suitable comonomers generally include various cyclic ethers. The polyfluorooxetane oligomer, polymer, or copolymer having a single hydroxyl end group can be functionalized with a variety of compounds so as to yield a functional end group such as an acrylate, a methacrylate, an allylic, an amine, etc., with the functionalized oligomer or polymer being suitable for use in radiation curable or thermal curable coating compositions. These functionalized polymers can be copolymerized and cured to provide improvements in wetting and surface properties.

  单官能聚合物氟氧杂环戊烷寡聚物、聚合物和共聚物是通过氟氧杂环戊烷单体与单醇的阳离子聚合制备的。除了作为引发剂外，单醇还可以作为溶剂，用于制备低环含量的寡聚物、聚合物或共聚物。适当的共聚单体通常包括各种环状醚。具有单一羟基端基的聚氟氧杂环戊烷寡聚物、聚合物或共聚物可以与各种化合物功能化，以产生诸如丙烯酸酯、甲基丙烯酸酯、烯丙基、胺等功能端基，功能化的寡聚物或聚合物适用于辐射固化或热固化涂料组合物。这些功能化聚合物可以共聚和固化，以提供润湿和表面性能的改善。
• RESIN COMPOSITION FOR SOLAR CELL ENCAPSULANT, SOLAR CELL ENCAPSULANT AND SOLAR CELL MODULE USING THE SAME
  申请人：Amamiya Takahiro

  公开号：US20120000514A1

  公开（公告）日：2012-01-05

  A resin composition for a solar cell encapsulant is provided, containing an ethylene•α-olefin copolymer and an organic peroxide or a silane coupling agent or the like, and having superior heat resistance, transparency, flexibility and adhesion property to a glass substrate, as well as good balance between rigidity and cross-linking efficiency, as well as a solar cell encapsulant, and a solar cell module using the same. The resin composition has an ethylene•α-olefin copolymer (A), having the characteristics (a1) to (a4), along with characteristics (a5) or (a6), and an organic peroxide (B) and/or a silane coupling agent (C).

  提供了一种用于太阳能电池封装的树脂组合物，包含乙烯•α-烯烃共聚物和有机过氧化物或硅烷偶联剂等，具有优异的耐热性、透明度、柔韧性和与玻璃基板的粘附性，以及良好的刚度和交联效率平衡，以及使用该组合物的太阳能电池封装材料和太阳能电池模块。该树脂组合物具有乙烯•α-烯烃共聚物（A）的特性（a1）至（a4），以及特性（a5）或（a6），以及有机过氧化物（B）和/或硅烷偶联剂（C）。
• Water-soluble phosphorus containing carboxylic polymers
  申请人：The B.F. GOODRICH Company

  公开号：EP0001561A1

  公开（公告）日：1979-05-02

  The compositions are formed as the reaction product, preferably in an organic solvent, of phosphorous acid or PC13 and a water-soluble carboxyl polymer. A precursor of phosphorous acid, which precursor is capable of generating phosphorous acid in aqueous solution, may be used, and preferably, the water-soluble carboxyl polymer has a relatively low molecular weight, preferably in the range from about 400 to about 6000. The molar ratio of the reactants, namely of carboxyl polymer, calculated as carboxyl groups to phosphorous acid is in the range from about 10:1 to about 1:1. The carboxyl polymer, such as polyacrylic acid, may be derived from an α,β-olefinically unsaturated monomer having a carboxyl group, or the carboxyl polymer such as an acid anhydride polymer may be derived from a monomer readily converted to one having a carboxylic acid group. CROSS REFERENCE TO RELATED APPLICATION This is a continuation-in-part of our copending U.S. Patent Application Serial No. 835,660 filed September 22, 1977.

  这些组合物是磷酸或 PC13 与水溶性羧基聚合物在有机溶剂中的反应产物。可以使用能在水溶液中生成磷酸的磷酸前体，水溶性羧基聚合物的分子量相对较低，最好在约 400 至约 6000 之间。反应物的摩尔比，即羧基聚合物的摩尔比，以羧基与磷酸计算，在约 10:1 至约 1:1 的范围内。羧基聚合物（如聚丙烯酸）可来自具有羧基的 α、β-烯烃不饱和单体，或羧基聚合物（如酸酐聚合物）可来自易于转化为具有羧基的单体。 与相关申请的对照检索 本申请是 1977 年 9 月 22 日提交的美国专利申请序列号 835,660 的部分延续。
• Process for the manufacture of objects from an unsaturated polyester composition
  申请人：AKZO N.V.

  公开号：EP0002871A1

  公开（公告）日：1979-07-11

  The invention relates to a process for the manufacture of objects having a thickness of at least 2 mm from an unsaturated polyester composition, in which the emission of ethylenically unsaturated monomer during the processing of the polyester composition is limited by exposing the latter to UV-radiation with a low-pressure UV-lamp, after which the composition is cured under the influence of a radical initiator at a temperature lower than 70° C.

  本发明涉及一种用不饱和聚酯组合物制造厚度至少为 2 毫米的物体的工艺，在该工艺中，聚酯组合物在加工过程中乙烯不饱和单体的释放受到限制，方法是用低压紫外线灯对聚酯组合物进行紫外线照射，然后在自由基引发剂的作用下，在低于 70°C 的温度下使组合物固化。