2-(acryloyl)succinic acid

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: 2-(acryloyl)succinic acid
• 英文别名: acryloyl malic acid；2-Prop-2-enoyloxybutanedioic acid
• 化学式: C₇H₈O₆
• 分子量: 188.137
• InChiKey: GLXXNAZOLXIHIH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.2
• 重原子数：
  13
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.29
• 拓扑面积：
  101
• 氢给体数：
  2
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  苹果酸 、 丙烯酰氯 以 水 为溶剂， 以78%的产率得到2-(acryloyl)succinic acid
  参考文献：
  名称：

  Anti-crease finishing of cotton fabrics based on crosslinking of cellulose with acryloyl malic acid

  摘要：

  Maleic acid (MA) has been explored to replace formaldehyde-based dimethylol dihydroxy ethylene urea (DMDHEU) for cotton anti-crease finishing. However, the resilience of treated fabrics was not satisfactorily improved. In this study, acryloyl malic acid (AMA) was synthesized and applied on fabrics as a novel crosslinking agent. The results showed that both crease recovery angle and whiteness index of treated samples were higher than those of MA in the presence/absence of catalyst sodium hypophosphite (SHP). Chemical structure of AMA was confirmed by NMR and MS spectra. The possible crosslinking mechanism between AMA and cellulose was investigated by means of C-13 NMR, MS, FTIR and phosphorus content analyses. It was found that AMA could form ester bonds with cellulose by formation of anhydride intermediate. Meanwhile, additional reaction of double bonds on AMA with another molecule or P-H of SHP residual has also contributed to the crosslinking. A reaction equation was proposed based on the analyses. (C) 2015 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.carbpol.2015.08.014

文献信息

• Polymerizable unsaturated polyester resin composition
  申请人：DAINIPPON INK AND CHEMICALS, INC.

  公开号：EP1149874A1

  公开（公告）日：2001-10-31

  A practical polymerizable unsaturated polyester resin composition is provided, wherein a polyester skeleton derived from collected PET is introduced, for effective utilization of waste PET such as a PET bottle which has recently been considered a large obstacle to environmental protection. The polymerizable unsaturated polyester resin composition comprises a straight-chain polyester (A) having a (meth)acryloyl group at both ends of molecules and an ethylenically unsaturated monomer (B), said straight-chain polyester (A) having a (meth)acryloyl group at both ends of molecules being obtained by reacting: (a) a terephthalate oligomer having a hydroxyl group at both ends of molecules resulted from the alcoholysis reaction of collected waste polyethylene terephthalate by an aliphatic glycol having an ether bond, (b) a dibasic acid containing an aromatic dibasic acid as a principal component, and (c) a glycidyl (meth)acrylate.

  本发明提供了一种实用的可聚合不饱和聚酯树脂组合物，其中引入了一种从收集的 PET 中提取的聚酯骨架，用于有效利用废 PET，如最近被认为是环境保护一大障碍的 PET 瓶。可聚合的不饱和聚酯树脂组合物包括分子两端具有 (甲基)丙烯酰基的直链聚酯 (A) 和乙烯基不饱和单体 (B)，所述分子两端具有 (甲基)丙烯酰基的直链聚酯 (A) 是通过以下反应获得的：(a) 分子两端具有羟基的对苯二甲酸酯低聚物，该低聚物是由具有醚键的脂肪族乙二醇对收集的聚对苯二甲酸乙二醇酯进行醇解反应而得到的；(b) 以芳香族二元酸为主要成分的二元酸；以及 (c) (甲基)丙烯酸缩水甘油酯。
• DISPERSION COMPOSITION AND INK-JET PRINTER INK COMPRISING THE SAME
  申请人：HITACHI MAXELL, LTD.

  公开号：EP1394207A1

  公开（公告）日：2004-03-03

  A dispersion composition comprising a colorant and an acrylic polymer having the furan structure, and an ink for an ink jet printer comprising such a dispersion composition. This dispersion composition can achieve the satisfactory stability of the colorant irrespective of the kind of the colorant, and allows the inks to be formulated to have the same composition. The ink for an ink jet printer has good storage stability and printing stability.

  一种由着色剂和具有呋喃结构的丙烯酸聚合物组成的分散组合物，以及一种包含这种分散组合物的喷墨打印机墨水。无论着色剂的种类如何，这种分散组合物都能使着色剂达到令人满意的稳定性，并能配制出具有相同成分的墨水。喷墨打印机墨水具有良好的储存稳定性和打印稳定性。
• AQUEOUS DISPERSION AND PROCESS FOR PRODUCTION THEREOF
  申请人：HITACHI MAXELL, LTD.

  公开号：EP1621587A1

  公开（公告）日：2006-02-01

  An aqueous dispersion containing a water-insoluble solid, wherein the solid consists of fine particles surfaces of which are coated with a resin having a polyether structure, and a coated amount of the resin is 15 to 1,000 parts by weight per 100 parts of the solid. This aqueous dispersion has improved dispersion stability for various solids such as pigments, dyes, and so on, causes no problems such as precipitation of the solid particles during the storage of the dispersion, and thus can be stably stored for a long time. The present invention can provide an aqueous dispersion used as an ink-jet printing ink, which has good high speed printing properties besides the above properties.

  一种含有不溶于水的固体的水性分散体，其中固体由细小颗粒组成，颗粒表面涂有聚醚结构的树脂，每 100 份固体中树脂的涂布量为 15 至 1000 份（按重量计）。这种水分散液对颜料、染料等各种固体具有更好的分散稳定性，在分散液的储存过程中不会出现固体颗粒沉淀等问题，因此可以长期稳定地储存。本发明可以提供一种用作喷墨打印墨水的水性分散体，除了上述特性外，它还具有良好的高速打印特性。
• 紫外線硬化型樹脂組成物及びその用途
  申请人：日本合成化学工業株式会社

  公开号：JP2002069138A

  公开（公告）日：2002-03-08

  (57)【要約】\n【課題】 ポリエステルフイルム、金属、ガラスに対する密着性に優れた紫外線硬化型樹脂組成物を提供すること。\n【解決手段】 （Ａ）水添ポリブタジエンポリオール、ポリイソシアネート及びヒドロキシアルキルアクリレートを反応させてなるウレタンアクリレート系樹脂、（Ｂ）炭素数６以上の脂肪族又は脂環族アルキルアクリレートを含んでなる放射線硬化型樹脂組成物、好ましくは更に（Ｃ）アクリル酸のミカエル付加物、あるいは２−アクリロイルオキシエチルジカルボン酸モノエステルを配合した放射線硬化型樹脂組成物からなる。

  (57) [摘要] Јn[主题事项] 提供一种对聚酯薄膜、金属和玻璃具有优异粘附性的紫外线固化树脂组合物。\(A) 一种辐射固化树脂组合物，包括(A) 由氢化聚丁二烯多元醇、多异氰酸酯和丙烯酸羟烷基酯反应而成的聚氨酯丙烯酸酯树脂，(B) 碳原子数为 6 或更多的脂肪族或脂环族丙烯酸烷基酯，以及优选的(C)包含丙烯酸或 2-丙烯酰氧乙基二羧酸单酯的迈克尔加合物的辐射固化树脂组合物。
• Pavement marking composition
  申请人：3M Innovative Properties Company

  公开号：US20020016421A1

  公开（公告）日：2002-02-07

  A pavement marking composition comprises (a) a polyfunctional ethylenically unsaturated polymer selected from the group consisting of polyfunctional ethylenically unsaturated polyurethanes, polyureas, polythiocarbamates, polythiocarbamateurethanes, polythiocarbamateureas, and polyurethaneureas comprising at least one chain extender-derived segment and at least one polycarbonate, polyether, or polyester segment; and (b) at least one ethylenically unsaturated monomer. The composition can be easily applied, cures in a reasonable amount of time at any of a wide range of commonly-encountered temperatures, and provides pavement markings that exhibit both improved cold impact resistance and improved wear resistance.

  一种路面标线组合物包括：(a) 多官能团乙烯基不饱和聚合物，选自由多官能团乙烯基不饱和聚氨酯、聚脲、聚硫代氨基甲酸酯、聚硫代氨基甲酸酯、聚硫代氨基甲酸酯和聚氨酯组成的组；(b) 至少一种乙烯基不饱和单体。该组合物易于使用，在各种常见温度下均可在合理的时间内固化，并可提供具有更好的抗冷冲击性和耐磨性的路面标记。