biphenyl-3,4,5-tricarboxylic acid

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: biphenyl-3,4,5-tricarboxylic acid
• 英文别名: H₃BPTC；Biphenyl-3,4,5-tricarbonsaeure；5-phenylbenzene-1,2,3-tricarboxylic acid
• 化学式: C₁₅H₁₀O₆
• 分子量: 286.241
• InChiKey: HKDYKRFXYCKBCZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.1
• 重原子数：
  21
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  112
• 氢给体数：
  3
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  zinc(II) nitrate hexahydrate 、 biphenyl-3,4,5-tricarboxylic acid 、 水 、 硝酸 反应 80.0h， 以43%的产率得到
  参考文献：
  名称：

  Employing tetrahedral {Zn 4 O} clusters as building subunits to construct a new acentric metal–organic framework

  摘要：

  Hydrothermal reaction of H3L and Zn(NO3)(2) produced a new noncentrosymmetric Zn(II) compound, namely [Zn-4(mu(4)-O)(L)(2)(H2O)(3)](n) (1 H3L = biphenyl-3,4,5-tricarboxylic acid). Single-crystal X-ray diffraction analysis reveals that compound 1 crystallizes in the acentric Pna2(1) space group and features a 3D framework based on isolated tetrahedral {Zn4O} clusters as building subunits. Topological analysis reveals that it can be simplified into a 3-nodal (3,3,6)-connected topological network with the Schlafli symbol of (4.6(2)}2(4(2).6(7).8(6)} In addition, the nonlinear optic and luminescent properties of this compound were also investigated at room temperature. (C) 2014 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2014.08.017
• 作为产物：
  描述：

  phenylmagnesium bromide 、 alkaline earth salt of/the/ methylsulfuric acid 在 乙醚 作用下， 生成 biphenyl-3,4,5-tricarboxylic acid
  参考文献：
  名称：

  器官提取物的研究。第十五次沟通。关于母马尿液中二酮D（氧-顺-四氢离子）中第二个羰基的位置

  摘要：

  1.通过使母马尿液中的二酮D与苯基溴化镁反应，用硒将反应产物脱水，并用高锰酸钾氧化脱氢产物，得到先前未知的二苯基-3,4,5-三羧酸。

  DOI：

  10.1002/hlca.19490320534

文献信息

• DESIGN, SYNTHESIS AND CHARACTERIZATION OF METAL ORGANIC FRAMEWORKS
  申请人：EDDAOUDI Mohamed

  公开号：US20170096394A1

  公开（公告）日：2017-04-06

  A molecular building block composition can include a metal ion component; and a ligand component including a core including at least one functional group associated with the metal ion component and the core.

  一个分子构建块组合可以包括一个金属离子组分；以及一个配体组分，包括一个核心，其中至少包括一个与金属离子组分和核心相关的功能基团。
• Controllable synthesis of a non-interpenetrating microporous metal–organic framework based on octahedral cage-like building units for highly efficient reversible adsorption of iodine
  作者：Wen-Wen He、Shun-Li Li、Guang-Sheng Yang、Ya-Qian Lan、Zhong-Min Su、Qiang Fu

  DOI：10.1039/c2cc34196d

  日期：——

  A novel non-interpenetrating metal–organic framework IFMC-15 was successfully constructed based on octahedral cage-like building units and its outstanding performance in reversible adsorption of iodine was investigated.

  一种新型非互穿金属-有机框架IFMC-15成功构建，该框架基于八面体笼状结构单元，并对其在碘的可逆吸附方面的优异性能进行了研究。
• Design, synthesis and characterization of metal organic frameworks
  申请人：KING ABDULLAH UNIVERSITY OF SCIENCE AND TECHNOLOGY

  公开号：US10273209B2

  公开（公告）日：2019-04-30

  A molecular building block composition can include a metal ion component; and a ligand component including a core including at least one functional group associated with the metal ion component and the core.

  分子构件组合物可包括金属离子成分；以及配体成分，配体成分包括一个核心，该核心包括至少一个与金属离子成分和核心相关的官能团。
• Synthesis and characterization of metal organic frameworks
  申请人：King Abdullah University of Science and Technology

  公开号：US10913718B2

  公开（公告）日：2021-02-09

  A molecular building block composition can include a metal ion component; and a ligand component including a core including at least one functional group associated with the metal ion component and the core.

  分子构件组合物可包括金属离子成分；以及配体成分，配体成分包括一个核心，该核心包括至少一个与金属离子成分和核心相关的官能团。
• PROTON-CONDUCTING MEMBRANE, METHOD FOR THEIR PRODUCTION AND THEIR USE IN ELECTROCHEMICAL CELLS
  申请人：BASF SE

  公开号：EP2804889B1

  公开（公告）日：2019-03-13