triphenylsulfonium phenol salt

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: triphenylsulfonium phenol salt
• 英文别名: triphenylsulfonium phenolate；triphenylsulfanium;phenoxide
• 化学式: C₆H₅O*C₁₈H₁₅S
• 分子量: 356.488
• InChiKey: TUATYNIJSCVYHN-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  5.54
• 重原子数：
  26
• 可旋转键数：
  3
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  24.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  甲基叔丁基醚 、 三苯基溴化锍 以 甲醇 为溶剂， 以99%的产率得到triphenylsulfonium phenol salt
  参考文献：
  名称：

  PHOTO-DESTROYABLE QUENCHER AND ASSOCIATED PHOTORESIST COMPOSITION, AND DEVICE-FORMING METHOD

  摘要：

  一种可被光破坏的猝灭剂具有以下结构，其中X、n和R1-R6如本文所定义，且R2、R3、R4、R5和R6中至少有一个是卤素、硝基、C1-12氟化烷基、氰基、醛基、C2-20酯、C2-20酮、C1-20烷基磺氧基、C1-20烷基磺酰基或磺胺基。该可被光破坏的猝灭剂相对于三苯基砜酚酚酚酚具有改善的溶液稳定性和减少的亲湿性能。包括酸敏感聚合物、光酸发生剂和可被光破坏的猝灭剂的光刻胶组合物相对于相应的光刻胶组合物比较照片破坏性猝灭剂具有增加的对比度和/或临界尺寸均匀性。

  公开号：

  US20150346599A1

文献信息

• NOVEL PROCESS FOR PREPARING RESISTS
  申请人：Clariant International Ltd.

  公开号：EP0942329A1

  公开（公告）日：1999-09-15

  A resist composition is prepared by reacting an alkali-soluble polymer having a phenolic hydroxyl or carboxyl groups with a vinyl ether compound in an aprotic solvent, such as propylene glycol monomethyl ether acetate, in the presence of an acid catalyst, suspending the reaction by the addition of a base, and directly adding a photoacid generator to the reaction solution. When a dialkyl dicarbonate is used in stead of the vinyl ether compound, a resist composition is prepared by carrying out the reaction in the presence of a basic catalyst and adding a photoacid generator directly to the reaction. Thus resist compositions can be prepared without isolating or purifying an alkali-soluble polymer which has been substituted by a catalytic reaction.

  在酸催化剂存在下，将具有酚羟基或羧基的碱溶性聚合物与乙烯基醚化合物在非沸腾溶剂（如丙二醇单甲醚醋酸酯）中反应，通过添加碱使反应暂停，并直接向反应溶液中添加光酸发生器，从而制备抗蚀剂组合物。当使用二烷基二碳酸酯代替乙烯基醚化合物时，在碱性催化剂存在下进行反应，并在反应中直接加入光酸发生器，即可制备抗蚀剂组合物。因此，在制备抗蚀剂组合物时，无需分离或提纯已被催化反应取代的碱溶性聚合物。
• Liquid ink and recording apparatus
  申请人：Toshiba Tec Kabushiki Kaisha

  公开号：EP1357159A2

  公开（公告）日：2003-10-29

  There is disclosed a liquid ink comprising a photo acid generating agent that generates an acid upon irradiation with light, a coloring component, and at least one kind of a solvent that is polymerized in the presence of an acid. It is preferable that the amount of the photo acid generating agent contained in the liquid ink falls within a range of between 1 part by weight and 10 parts by weight relative to 100 parts by weight of the solvent, the coloring component consists of a pigment, and the solvent contains at least 50 parts by weight of an acid polymerizable compound, the acid polymerizing compound polymerizing in the presence of the acid, having an alicyclic skeleton and/or an aliphatic skeleton having a viscosity of 50 mPa·s or less and a boiling point of 150°C or more under room temperature and atmospheric pressure.

  本发明公开了一种液体油墨，该油墨由在光照射下产生酸的光酸生成剂、着色成分和至少一种在酸存在下聚合的溶剂组成。相对于 100 重量份的溶剂，液体油墨中所含的光酸生成剂的量最好在 1 重量份到 10 重量份之间，着色成分由颜料组成、溶剂中含有至少 50 份（重量）的可酸聚合化合物，该酸聚合化合物在酸存在下聚合，具有脂环族骨架和/或脂肪族骨架，在室温和常压下粘度为 50 mPa-s 或更低，沸点为 150°C 或更高。
• Processes for preparing photoresist compositions
  申请人：E.I. DUPONT DE NEMOURS AND COMPANY

  公开号：EP1479700A1

  公开（公告）日：2004-11-24

  An anhydrous, liquid phase process for preparing polymers of enhanced purity and low polydispersity comprising the steps of polymerization, optional purification, transesterification, optional purification, catalyst removal, and solvent exchange. The resultant polymer in solution can be used directly, without further processing steps, to prepare a photoresist composition.

  一种用于制备纯度更高、多分散性更低的聚合物的无水液相工艺，包括聚合、可选提纯、酯交换、可选提纯、去除催化剂和溶剂交换等步骤。所得溶液聚合物可直接用于制备光刻胶组合物，无需进一步加工步骤。
• Ink for ink jet and ink jet recording apparatus
  申请人：Toshiba Tec Kabushiki Kaisha

  公开号：EP1514911A1

  公开（公告）日：2005-03-16

  There is disclosed an ink jet recording apparatus (1) comprising a color ink container (5) having a capacity V1 accommodating therein a solvent polymerizable in the presence of an acid and a colorant, a reaction liquid container (3) having a capacity V2 (V2

  本发明公开了一种喷墨记录装置 (1)，包括一个容量为 V1 的彩色墨水容器 (5)，其中装有可在酸和着色剂存在下聚合的溶剂；一个容量为 V2 (V2
• Inkjet ink
  申请人：Toshiba Tec Kabushiki Kaisha

  公开号：EP1528088A1

  公开（公告）日：2005-05-04

  There is provided an inkjet ink comprising a photo-acid generating agent which is capable of generating an acid as it is irradiated with light, a color component, and an acid-polymerizable compound which can be polymerized in the presence of an acid, wherein at least 40% of the acid-polymerizable solvent is a vinyl ether compound represented by the following general formula (1):         R13-R14-(R13)p     (1)    (Wherein R13(s) is a group selected from the group consisting of a vinyl ether group, a group having a vinyl ether skeleton, an alkoxy group, substituted hydroxyl group and hydroxyl group wherein at least one of R13(s) is vinyl ether group or a group having a vinyl ether skeleton, R14 is a group comprising a substituted or unsubstituted cyclic skeleton and having a valence of (p+1), and p is a positive integer including zero).

  本发明提供了一种喷墨墨水，该墨水包含一种在光照射下能产生酸的光酸生成剂、一种颜色成分和一种可在酸存在下聚合的可酸聚合化合物，其中至少 40% 的可酸聚合溶剂是由下式（1）表示的乙烯基醚化合物： R13-R14-(R13)p (1) (其中，R13(s)是从乙烯基醚基、具有乙烯基醚骨架的基团、烷氧基、取代羟基和羟基组成的组中选出的基团，其中 R13(s) 中至少有一个是乙烯基醚基或具有乙烯基醚骨架的基团，R14 是由取代或未取代的环状骨架组成且价数为 (p+1) 的基团，p 是包括零在内的正整数）。