二丁基(甲基)膦 | 33374-48-0

• 分子结构分类: 有机化合物 - 有机磷化合物 - 有机膦及其衍生物
• 中文名称: 二丁基(甲基)膦
• 英文名称: dibutyl-methyl-phosphine
• 英文别名: Di-n-butyl-methyl-phosphin；Methyl-di-n-butylphosphin；Di-n-butylmethylphosphine；dibutyl(methyl)phosphane
• CAS: 33374-48-0
• 化学式: C₉H₂₁P
• 分子量: 160.239
• InChiKey: LOEIOOSCALHKOG-UHFFFAOYSA-N

物化性质

• 沸点：
  196.2±9.0 °C(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.4
• 重原子数：
  10
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

安全信息

• 海关编码：
  2931900090

反应信息

• 作为反应物：
  描述：

  二丁基(甲基)膦 在 sulfur 作用下， 以 四氢呋喃 为溶剂， 生成 dibutyl(methyl)phosphine sulfide
  参考文献：
  名称：

  三种不同C-P键的高度原子经济一键形成：无环叔膦硫化物的一般合成

  摘要：

  苯并噻二磷1与R 1 MgBr和R 2 MgBr的等摩尔混合物反应生成中间体A '，仅在4-5分钟后，用等摩尔量的R 3 MgBr处理中间体A ' ，得到不对称膦PR 1 R 2 R 3占总产率的45％（当R 1 = R 2时产率为75-80％，当R 1 = R 2 = R 3时产率为85-90％），副产物6的产率为90％。用PCl 3处理6可定量再生起始试剂1。用元素硫处理膦，得到相应的硫化物。

  DOI：

  10.1021/jo0502145
• 作为产物：
  描述：

  dibutyl(methoxycarbonyl)phosphine 、 碘甲烷 以 乙腈 为溶剂， 生成 二丁基(甲基)膦
  参考文献：
  名称：

  Prishchenko, A. A.; Livantsov, M. V.; Moshnikov, S. A., Journal of general chemistry of the USSR, 1987, vol. 57, p. 1484 - 1485

  摘要：

  DOI：

文献信息

• METHOD FOR PRODUCING CATALYST FOR CYCLIC CARBONATE SYNTHESIS
  申请人：MARUZEN PETROCHEMICAL CO., LTD.

  公开号：US20160108071A1

  公开（公告）日：2016-04-21

  The present invention provides a method for easily and inexpensively producing a heterogeneous catalyst used to synthesize a cyclic carbonate by reacting an epoxide with carbon dioxide and having excellent catalyst activity; a catalyst obtained using said manufacturing method; and a method for synthesizing a cyclic carbonate using said catalyst. A method for producing a catalyst that is used for the purpose of synthesizing a cyclic carbonate by subjecting to a reaction an epoxide with carbon dioxide, said method comprising the following steps (a) and (b): (a) a step of obtaining a catalyst precursor having a haloalkyl group or a haloaryl group by reacting a silane compound with a silica gel in the presence of xylene, the silane compound having a haloalkyl group or a haloaryl group and (b) a step of obtaining a catalyst for synthesizing a cyclic carbonate by reacting the catalyst precursor obtained in step (a) with a tertiary phosphine.

  本发明提供了一种用于通过将环氧化合物与二氧化碳反应来合成环状碳酸酯的异质催化剂的简便且廉价的生产方法；采用所述制备方法获得的催化剂；以及使用该催化剂合成环状碳酸酯的方法。用于生产一种用于合成环状碳酸酯的催化剂的方法，通过将环氧化合物与二氧化碳反应，该方法包括以下步骤(a)和(b)：(a)通过在二甲苯存在下将硅烷化合物与二氧化硅反应以获得具有卤代烷基或卤代芳基的催化剂前驱体的步骤，其中所述硅烷化合物具有卤代烷基或卤代芳基；以及(b)通过将步骤(a)中获得的催化剂前驱体与三膦反应以获得用于合成环状碳酸酯的催化剂的步骤。
• A Fast Catalytic Process of Transfer of a Phosphorus Atom: How Folding of the Reagent is Related to its Catalytic Activity. A Possible Correlation with Rna Behavior
  作者：Graziano Baccolini、Gabriele Micheletti

  DOI：10.1080/10426507.2014.883625

  日期：2014.8.3

  different Grignard reagents giving, in a very fast and in a highly selective manner, only one phosphorus-containing compound with an enormous rate enhancement with respect to the corresponding no-catalyzed reaction which gives a final cluttered mixture of many organophosphorus products. The focal factor to explain this highly selective process of P transport lies in the folded structure of the reagent with

  摘要 描述了一种简单且非常快速的磷原子转移过程，该过程由作为催化剂的简单分子在几乎无限的催化循环中进行。该催化剂将一个 P 原子提供给两种不同格氏试剂的混合物，以非常快速和高度选择性的方式，仅产生一种含磷化合物，相对于相应的无催化反应，具有极大的速率提高，从而产生许多有机磷产品的最终杂乱混合物。解释这种高选择性 P 传输过程的焦点因素在于试剂的折叠结构，围绕磷原子具有特定角度，这可以促进环状三方双锥五配位物质的形成，进而促进其催化活性。以类似的方式，RNA 可以采用，在一个精确的位置，一个特定的三维结构，可能有助于形成导致催化功能的五配位物种。图形概要
• Selective Hydrogenation Catalyst and Methods of Making and Using Same
  申请人：Cheung Tin-Tack Peter

  公开号：US20100228065A1

  公开（公告）日：2010-09-09

  A composition comprising a supported hydrogenation catalyst comprising palladium and an organophosphorous compound, the supported hydrogenation catalyst being capable of selectively hydrogenating highly unsaturated hydrocarbons to unsaturated hydrocarbons. A method of making a selective hydrogenation catalyst comprising contacting a support with a palladium-containing compound to form a palladium supported composition, contacting the palladium supported composition with an organophosphorus compound to form a catalyst precursor, and reducing the catalyst precursor to form the catalyst. A method of selectively hydrogenating highly unsaturated hydrocarbons to an unsaturated hydrocarbon enriched composition comprising contacting a supported catalyst comprising palladium and an organophosphorous compound with a feed comprising highly unsaturated hydrocarbon under conditions suitable for hydrogenating at least a portion of the highly unsaturated hydrocarbon feed to form the unsaturated hydrocarbon enriched composition.

  一种包括支持的氢化催化剂的组合物，其中氢化催化剂包括钯和有机磷化合物，支持的氢化催化剂能够选择性地将高度不饱和烃氢化为不饱和烃。一种制备选择性氢化催化剂的方法，包括将支持物与含钯化合物接触以形成支持的钯组合物，将支持的钯组合物与有机磷化合物接触以形成催化剂前体，并还原催化剂前体以形成催化剂。一种将高度不饱和烃选择性氢化为富含不饱和烃的组合物的方法，包括将包括钯和有机磷化合物的支持催化剂与含高度不饱和烃的进料接触，在适宜的氢化条件下至少部分氢化高度不饱和烃进料以形成富含不饱和烃的组合物。
• METHYL-IODIDE-FREE CARBONYLATION OF AN ALCOHOL TO ITS HOMOLOGOUS ALDEHYDE AND/OR ALCOHOL
  申请人：EASTMAN CHEMICAL COMPANY

  公开号：US20160185701A1

  公开（公告）日：2016-06-30

  Disclosed is a process for the reductive carbonylation of a low molecular weight alcohol to produce the homologous aldehyde and/or alcohol. The process includes conducting the reaction to produce the aldehyde in the presence of a catalyst complex composed of cobalt, an onium cation and iodide in a ratio of 1:2:4 with a phosphine ligand. A ruthenium co-catalyst is used in the production of the homologous alcohol. The reductive carbonylation reaction does not require an additional iodide promoter and produces a crude reductive carbonylation product substantially free of methyl iodide.

  本发明公开了一种还原羰基化低分子量醇以产生同系物醛和/或醇的过程。该过程包括在催化剂复合物的存在下进行反应，该催化剂复合物由钴、离子和碘组成，比例为1:2:4，含有膦配体，以产生醛。在同系物醇的生产中使用了钌共催化剂。还原羰基化反应不需要额外的碘促进剂，并且产生的粗还原羰基化产物基本上不含甲基碘。
• ORGANOMETALLIC COMPOUND, CATALYST FOR POLYMERIZATION OF POLAR GROUP-CONTAINING NORBORNENE AND PROCESS FOR PRODUCING NORBORNENE POLYMER
  申请人：Watanabe Saisuke

  公开号：US20090247729A1

  公开（公告）日：2009-10-01

  An organometallic compound obtained by mixing following (a), (b) and (c): (a) a neutral organopalladium complex that has a palladium atom and two organic ligands each having at least three carbon atoms participating in a bond to the palladium atom; (b) an organophosphorus compound having one phosphorus atom; and (c) a salt comprising: an anion having no unshared electron pair in a central atom; and a counter-cation. And a process for producing a norbornene compound polymer, the process comprising: subjecting at least one norbornene compound represented by formula (A) as defined in the specification to polymerization reaction in a presence of an organometallic complex catalyst produced by mixing compound (a) and compound (d) described in the specification.

  一种有机金属化合物，通过混合以下物质（a）、（b）和（c）获得：（a）一种中性有机钯配合物，其具有钯原子和两个有机配体，每个配体至少有三个碳原子参与与钯原子的键合；（b）一种含有一个磷原子的有机磷化合物；和（c）一种盐，包括：一个中心原子中没有未共享电子对的阴离子；和一个对离子。以及一种生产诺博尔烯化合物聚合物的方法，该方法包括：在混合化合物（a）和规范中描述的化合物（d）的有机金属配合物催化剂的存在下，将至少一种由式（A）表示的诺博尔烯化合物进行聚合反应。