二乙基2,6-二溴螺[3.3]庚烷-2,6-二羧酸 | 55249-70-2

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 中文名称: 二乙基2,6-二溴螺[3.3]庚烷-2,6-二羧酸
• 英文名称: 2,6-dibromo-spiro[3.3]heptane-2,6-dicarboxylic acid diethyl ester
• 英文别名: 2,6-Dibrom-spiro[3.3]heptan-2,6-dicarbonsaeure-diaethylester；Diethyl 2,6-dibromospiro[3.3]heptane-2,6-dicarboxylate
• CAS: 55249-70-2
• 化学式: C₁₃H₁₈Br₂O₄
• 分子量: 398.092
• InChiKey: XAMKLIDFYSWIFP-UHFFFAOYSA-N

物化性质

• 密度：
  1.65

计算性质

• 辛醇/水分配系数(LogP)：
  3.1
• 重原子数：
  19
• 可旋转键数：
  6
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.85
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  二乙基2,6-二溴螺[3.3]庚烷-2,6-二羧酸 在 氢氧化钾 作用下， 以 甲苯 为溶剂， 生成 Spiro[3.3]hepta-1,5-diene-2,6-dicarboxylic acid
  参考文献：
  名称：

  Synthesis, chemistry, and spectroscopic properties of spiro[3.3]hepta-1,5-diene

  摘要：

  DOI：

  10.1021/ja00814a032
• 作为产物：
  描述：

  2,6-二溴螺[3.3]庚烷-2,6-二甲酸 在 硫酸 作用下， 生成 二乙基2,6-二溴螺[3.3]庚烷-2,6-二羧酸
  参考文献：
  名称：

  In vitro Propagation and Conservation of Atropa acuminata Royle ex Lindl -An Indigenous Threatened Medicinal Plant

  摘要：

  A micropropagation method has been developed for multiplication and conservation of Atropa acuminata by induction of axillary shoot proliferation from shoot tips and nodal explants using Murashige and Skoog (MS) medium supplemented with BAP (1 mg l(-1)) and IBA (1 mg l(-1)). Revised tobacco (RT) medium with IAA (1 mg l(-1)) was found most suitable for shoot elongation. Rooting was highest on full strength RT medium containing IBA (1 mg l(-1)). In vitro raised plantlets; were hardened and transferred to soil.

  DOI：

  10.1007/bf03263148

文献信息

• Synthesis, chemistry, and spectroscopic properties of spiro[3.3]hepta-1,5-diene
  作者：L. A. Hulshof、Hans Wynberg

  DOI：10.1021/ja00814a032

  日期：1974.4
• In vitro Propagation and Conservation of Atropa acuminata Royle ex Lindl -An Indigenous Threatened Medicinal Plant
  作者：Ashok Ahuja、Manju Sambyal、Sushma Koul

  DOI：10.1007/bf03263148

  日期：2002.7

  A micropropagation method has been developed for multiplication and conservation of Atropa acuminata by induction of axillary shoot proliferation from shoot tips and nodal explants using Murashige and Skoog (MS) medium supplemented with BAP (1 mg l(-1)) and IBA (1 mg l(-1)). Revised tobacco (RT) medium with IAA (1 mg l(-1)) was found most suitable for shoot elongation. Rooting was highest on full strength RT medium containing IBA (1 mg l(-1)). In vitro raised plantlets; were hardened and transferred to soil.