过氧-2-乙基己酸叔丁酯 | 62695-55-0

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 中文名称: 过氧-2-乙基己酸叔丁酯
• 英文名称: 2-(tert-butylperoxy)ethyl caproate
• 英文别名: tert-butylperoxy-2-ethyl hexanoate；t-butylperoxy-2-ethyl hexanoate；Hexanoic acid, 2-((1,1-dimethylethyl)dioxy)ethyl ester；2-tert-butylperoxyethyl hexanoate
• CAS: 62695-55-0
• 化学式: C₁₂H₂₄O₄
• 分子量: 232.32
• InChiKey: RVTCOWUIPRZEHC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.9
• 重原子数：
  16
• 可旋转键数：
  10
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.92
• 拓扑面积：
  44.8
• 氢给体数：
  0
• 氢受体数：
  4

安全信息

• 危险等级：
  5.2
• 包装等级：
  II
• 危险类别：
  5.2
• 危险品运输编号：
  UN 3113

反应信息

• 作为反应物：
  描述：

  过氧-2-乙基己酸叔丁酯 在 alkali 作用下， 以 1,4-二氧六环 、 水 为溶剂， 生成 2-[叔丁基二氧基]-乙醇
  参考文献：
  名称：

  Nosan, V. N.; Petrovskaya, G. A.; Pokhmurskaya, M. V., Journal of Organic Chemistry USSR (English Translation), 1987, vol. 23, # 7, p. 1318 - 1320

  摘要：

  DOI：

文献信息

• IONTOPHORESIS APPARATUS
  申请人：TOKUYAMA CORPORATION

  公开号：EP1566197A1

  公开（公告）日：2005-08-24

  An iontophoresis device comprising (A) a working electrode assembly having a working electrode, a medicine-containing portion and an ion-exchange membrane, (B) a counter electrode assembly having an electrode which opposes the working electrode, and (C) a power source unit electrically connected to the working electrode assembly and to the counter electrode assembly, enabling an ionic medicine contained in the medicine containing portion to be permeated into a living body by the electrophoresis through the ion-exchange membrane, wherein the ion-exchange membrane has a structure in which voids of a porous film are filled with an ion-exchange resin. The iontophoresis device using the above ion-exchange membrane makes it possible to administer the medicine in amounts larger than those accomplished by using the conventional devices.

  一种离子透入装置，包括(A)工作电极组件，该组件具有工作电极、含药部分和离子交换膜；(B)对电极组件，该组件具有与工作电极相对的电极；以及(C)与工作电极组件和对电极组件电连接的电源装置、使含药部分所含的离子药物通过离子交换膜的电泳渗透到活体内，其中离子交换膜具有在多孔膜的空隙中填充离子交换树脂的结构。使用上述离子交换膜的离子透入装置可实现比传统装置更大的药量。
• METHOD FOR PRODUCING MODIFIED POLYOLEFIN SOLUTION
  申请人：Tonen Chemical Corporation

  公开号：EP1607415A1

  公开（公告）日：2005-12-21

  A method for producing a modified polyolefin solution, which can reduce polymer loss, solvent loss and further number of steps, and thus has excellent productivity and economic efficiency in a series of steps, wherein an α-olefin is polymerized to obtain a polyolefin, followed by modification with a modifying agent to produce a modified polyolefin solution, characterized by comprising a step wherein an α-olefin is polymerized in the presence of polymerization catalyst in liquid phase to obtain a polyolefin as a polymer solution or slurry state and a step wherein thus obtained polymer is reacted with a modifying agent to modify a polyolefin, and in that the polymer is not isolated, not recovered, nor substantially dried, in a method for producing a modified polyolefin solution by modification, using a modification agent, of a polyolefin obtained by polymerization of an α-olefin.

  一种生产改性聚烯烃溶液的方法，该方法可以减少聚合物损失、溶剂损失和进一步的步骤数量，因此在一系列步骤中具有优异的生产率和经济效益，其中先聚合α-烯烃以获得聚烯烃，然后用改性剂进行改性以生产改性聚烯烃溶液、其特征在于，在通过使用改性剂对α-烯烃聚合得到的聚烯烃进行改性以生产改性聚烯烃溶液的方法中，包括一个步骤，在该步骤中，α-烯烃在液相聚合催化剂存在下进行聚合，以获得聚合物溶液或浆液状态的聚烯烃，以及一个步骤，在该步骤中，由此获得的聚合物与改性剂反应，以改性聚烯烃，并且该聚合物不被分离、不被回收，也不被基本干燥。
• Working electrode assembly for iontophoresis and iontophoresis device
  申请人：TOKUYAMA CORPORATION

  公开号：EP1649891A1

  公开（公告）日：2006-04-26

  A working electrode assembly for iontophoresis having a working electrode, a medicine-containing portion containing an ionic medicine, and an ion-exchange membrane arranged between the working electrode and the medicine-containing portion, wherein said ion-exchange membrane has both the anion-exchange groups and the cation-exchange groups, and between these anion-exchange groups of the one side are contained in an excess amount compared to the other ion-exchange groups. The working electrode assembly effectively prevents the contact between the medicine and the working electrode and, at the same time, accomplishes a high efficiency for administering the medicine.

  一种用于离子透入疗法的工作电极组件，具有一个工作电极、一个含有离子药物的含药部分，以及一个布置在工作电极和含药部分之间的离子交换膜，其中所述离子交换膜同时具有阴离子交换基团和阳离子交换基团，在这些阴离子交换基团之间，一侧的阴离子交换基团与其他离子交换基团相比含量过多。该工作电极组件可有效防止药物与工作电极之间的接触，同时实现高效的给药效果。
• PROCESS FOR PRODUCING ION EXCHANGE MEMBRANE FOR IONTOPHORESIS
  申请人：TOKUYAMA CORPORATION

  公开号：EP1752487A1

  公开（公告）日：2007-02-14

  A method of producing an ion-exchange membrane for iontophoresis by preparing a polymerizable composition containing monomer components and non-polymerizable components which are compatible with the monomer components but do not copolymerize therewith; forming the polymerizable composition into a membrane form; polymerizing the polymerizable composition in the obtained membrane form to thereby form a membrane of a structure in which the non-polymerizable components are dispersed in the polymer having a crosslinked structure; removing the non-polymerizable components from the obtained membrane; and, as required, introducing ion-exchange groups into the polymer. The ion-exchange membrane obtained by the above method is applied to an iontophoresis device. When an ionic medicine contained in a medicine-containing portion of the device is permeated into a living body by the electrophoresis through the ion-exchange membrane, not only ionic medicines having small formula weights but also medicinal ions of formula weights of about 500 to about 1,000 can be efficiently administered into the living body.

  一种生产离子透析用离子交换膜的方法，通过制备一种可聚合组合物，该组合物含有单体成分和与单体成分相容但不共聚的不可聚合成分；将可聚合组合物制成膜状；在获得的膜状中聚合可聚合组合物，从而形成一种膜结构，其中不可聚合成分分散在具有交联结构的聚合物中；从获得的膜中去除不可聚合成分；以及根据需要在聚合物中引入离子交换基团。通过上述方法获得的离子交换膜可用于离子透析装置。当该装置的含药部分所含的离子药物通过离子交换膜的电泳渗透到活体内时，不仅可将配方重量较小的离子药物，而且可将配方重量约为 500 至约 1 000 的药用离子有效地注入活体内。
• ION-EXCHANGE MEMBRANE
  申请人：Astom Corporation

  公开号：EP2692782A1

  公开（公告）日：2014-02-05

  An ion-exchange membrane including a porous unstretched polyethylene sheet in which fine pores are piercing, the pores being filled with an ion-exchange resin. The ion-exchange membrane exhibits excellent concentration property.

  一种离子交换膜，包括多孔的未拉伸聚乙烯片材，片材上有细孔，孔内填充有离子交换树脂。 这种离子交换膜具有优异的浓缩性能。